LEADER 05045nam 2201237z- 450 001 9910346672303321 005 20231214133529.0 035 $a(CKB)4920000000094944 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/44062 035 $a(EXLCZ)994920000000094944 100 $a20202102d2019 |y 0 101 0 $aeng 135 $aurmn|---annan 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aCoordination Chemistry of Silicon 210 $cMDPI - Multidisciplinary Digital Publishing Institute$d2019 215 $a1 electronic resource (225 p.) 311 $a3-03897-638-5 330 $aThe chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds. 610 $acluster 610 $amolecular orbital analysis 610 $abond activation 610 $aX-ray diffraction 610 $asilsesquioxanes 610 $adigermacyclobutadiene 610 $aintermetallic bond 610 $agermanium 610 $acomputational chemistry 610 $a?-electron systems 610 $aisocyanide 610 $aX-ray crystallography 610 $acyclic organopolysilane 610 $adisilene 610 $aruthenium 610 $aplatinum 610 $aDFT 610 $aPhotostability 610 $asilicon surfaces 610 $astereochemistry 610 $apalladium 610 $adistorted coordination 610 $a29Si NMR spectroscopy 610 $aorganosilicon 610 $adisilanylene polymer 610 $aSi?Cl activation 610 $aadsorption 610 $aAIM 610 $asiliconoid 610 $ananoparticle 610 $adisiloxane tetrols 610 $agermylene 610 $ahydrogen bonding 610 $aTiO2 610 $adehydrogenative alkoxylation 610 $asiloxanes 610 $a2-silylpyrrolidines 610 $abonding analysis 610 $a?-chloro-?-hydrooligosilane 610 $ahydrido complex 610 $aoxidative addition 610 $aphotoreaction 610 $atemplate 610 $asurface modification 610 $atitanium 610 $abromosilylenes 610 $ahost-guest chemistry 610 $ahydrogen bonds 610 $asalt-free 610 $aN-heterocyclic carbines 610 $asilicon cluster 610 $acondensation 610 $asilyliumylidenes 610 $aBaird?s rule 610 $aN-heterocyclic carbenes 610 $areductant 610 $amain group coordination chemistry 610 $amolecular cage 610 $asubvalent compounds 610 $aisomerization 610 $asilanetriols 610 $agermathioacid chloride 610 $adehydrobromination 610 $aN-heterocyclic carbene 610 $amechanistic insights 610 $aligand-exchange reaction 610 $abridging silylene ligand 610 $adye-sensitized solar cell 610 $asilylene 610 $acomputation 610 $afunctionalization 610 $asilicon 610 $adigermene 610 $aN-Heterocyclic tetrylene 610 $adensity functional theory 610 $aprimary silane 610 $asmall molecule activation 610 $aexcited state aromaticity 610 $agermanethione 610 $asupramolecular chemistry 700 $aInoue$b Shigeyoshi$4auth$01331071 906 $aBOOK 912 $a9910346672303321 996 $aCoordination Chemistry of Silicon$93040099 997 $aUNINA