LEADER 03751nam 22005415 450 001 9910337931403321 005 20200705065833.0 010 $a3-030-06004-7 024 7 $a10.1007/978-3-030-06004-6 035 $a(CKB)4100000007881305 035 $a(MiAaPQ)EBC5747387 035 $a(DE-He213)978-3-030-06004-6 035 $a(PPN)235669547 035 $a(EXLCZ)994100000007881305 100 $a20190405d2019 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 14$aThe Structure Dependent Energy of Organic Compounds /$fby Árpád Furka 205 $a1st ed. 2019. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2019. 215 $a1 online resource (133 pages) 225 1 $aSpringerBriefs in Molecular Science,$x2191-5407 311 $a3-030-06003-9 327 $aAn alternative thermochemical reference system -- Hydrocarbons -- The oxygen derivatives of hydrocarbons -- Organic compounds containing nitrogen -- Organosulfur compounds -- Organohalides -- Radicals, cations, and anions -- Inorganic compounds -- Components of the heats of reactions. 330 $aThis brief introduces readers to an alternative thermochemical reference system that makes it possible to use the heats of formation of organic compounds to deduce the energies that depend entirely on their structures, and which provides calculated values for most of the characteristic structures appearing in organic molecules. These structure-dependent energies are provided e.g. for selected compounds of normal and cyclic alkanes, open chain and cyclic olefins (including conjugated polyenes), alkynes, aromatic hydrocarbons and their substituted derivatives. The oxygen, sulfur and nitrogen derivatives of the above-mentioned compounds are also represented with calculated structure-dependent energies including alcohols, ethers, aldehydes and ketones, carboxylic acids, thiols, sulfides, amines, amides, heterocyclic compounds and others. Most organic reactions can be interpreted as the disappearance of certain structures and formation of others. If the structure-dependent energies are known, it can be shown how the disappearing and the newly formed structures contribute to the heat of reactions and to the driving forces. As experienced by the author, who pioneered the concept, structure dependent energies can help teachers to make organic chemistry more accessible for their students. Accordingly, the brief offers a valuable resource for all those who teach organic chemistry at universities, and for those who are learning it. 410 0$aSpringerBriefs in Molecular Science,$x2191-5407 606 $aChemistry, Organic 606 $aChemistry, Physical and theoretical 606 $aChemistry, Physical and theoretical 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aTheoretical and Computational Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C25007 615 0$aChemistry, Organic. 615 0$aChemistry, Physical and theoretical. 615 0$aChemistry, Physical and theoretical. 615 14$aOrganic Chemistry. 615 24$aPhysical Chemistry. 615 24$aTheoretical and Computational Chemistry. 676 $a547.122 676 $a547 700 $aFurka$b Árpád$4aut$4http://id.loc.gov/vocabulary/relators/aut$0770187 906 $aBOOK 912 $a9910337931403321 996 $aStructure Dependent Energy of Organic Compounds$91570930 997 $aUNINA