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200 10$aNew Synthetic Routes to Polyoxometalate Containing Ionic Liquids $eAn Investigation of their Properties /$fby Sven Herrmann
205   $a1st ed. 2015.
210  1$aWiesbaden :$cSpringer Fachmedien Wiesbaden :$cImprint: Springer Spektrum,$d2015.
215   $a1 online resource (138 p.)
225 1 $aBestMasters,$x2625-3577
300   $aDescription based upon print version of record.
311   $a3-658-08795-1 
320   $aIncludes bibliographical references.
327   $aPolyoxometlates and Ionic Liquids in General -- POM-Ils as New Class of Compounds -- Synthesis and Characterization of POM-ILs -- Reactivity Towards Azide and Carbonmonoxide.
330   $aIn his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.  Contents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide  Target Groups Researchers and students in the field of chemistry Practitioners in this area  The Author Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).
410  0$aBestMasters,$x2625-3577
606   $aChemistry, Inorganic
606   $aCatalysis
606   $aChemical engineering
606   $aInorganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C16008
606   $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000
606   $aIndustrial Chemistry/Chemical Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/C27000
615  0$aChemistry, Inorganic.
615  0$aCatalysis.
615  0$aChemical engineering.
615 14$aInorganic Chemistry.
615 24$aCatalysis.
615 24$aIndustrial Chemistry/Chemical Engineering.
676   $a54
676   $a541395
676   $a546
676   $a660
700   $aHerrmann$b Sven$4aut$4http://id.loc.gov/vocabulary/relators/aut$0893254
906   $aBOOK
912   $a9910304140503321
996   $aNew Synthetic Routes to Polyoxometalate Containing Ionic Liquids$91995418
997   $aUNINA