LEADER 04022nam 22006495 450 001 9910300542203321 005 20200704041904.0 010 $a3-030-02366-4 024 7 $a10.1007/978-3-030-02366-9 035 $a(CKB)4100000007177261 035 $a(MiAaPQ)EBC5606211 035 $a(DE-He213)978-3-030-02366-9 035 $a(PPN)232468907 035 $a(EXLCZ)994100000007177261 100 $a20181127d2018 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aLithium Intercalation in Bilayer Graphene Devices /$fby Matthias Kühne 205 $a1st ed. 2018. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2018. 215 $a1 online resource (128 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a3-030-02365-6 327 $aIntroduction -- Electronic Properties -- Electrochemical Device Setup and Fabrication -- Lithiation Studies -- Conductivity Corrections from Quantum Interferences -- Intercalate Diffusion Pathways -- Intercalate Diffusion Kinetics -- Summary. 330 $aThis book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aSolid state physics 606 $aMaterials science 606 $aForce and energy 606 $aElectrochemistry 606 $aSurfaces (Physics) 606 $aInterfaces (Physical sciences) 606 $aThin films 606 $aSolid State Physics$3https://scigraph.springernature.com/ontologies/product-market-codes/P25013 606 $aEnergy Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z21000 606 $aElectrochemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21010 606 $aSurface and Interface Science, Thin Films$3https://scigraph.springernature.com/ontologies/product-market-codes/P25160 615 0$aSolid state physics. 615 0$aMaterials science. 615 0$aForce and energy. 615 0$aElectrochemistry. 615 0$aSurfaces (Physics). 615 0$aInterfaces (Physical sciences). 615 0$aThin films. 615 14$aSolid State Physics. 615 24$aEnergy Materials. 615 24$aElectrochemistry. 615 24$aSurface and Interface Science, Thin Films. 676 $a620.115 700 $aKühne$b Matthias$4aut$4http://id.loc.gov/vocabulary/relators/aut$0835361 906 $aBOOK 912 $a9910300542203321 996 $aLithium Intercalation in Bilayer Graphene Devices$91866872 997 $aUNINA