LEADER 04641nam 22007695 450 001 9910300431403321 005 20200707032032.0 010 $a3-319-14809-5 024 7 $a10.1007/978-3-319-14809-0 035 $a(CKB)3710000000434097 035 $a(EBL)2120620 035 $a(OCoLC)911032810 035 $a(SSID)ssj0001525182 035 $a(PQKBManifestationID)11872448 035 $a(PQKBTitleCode)TC0001525182 035 $a(PQKBWorkID)11485299 035 $a(PQKB)11001754 035 $a(DE-He213)978-3-319-14809-0 035 $a(MiAaPQ)EBC2120620 035 $a(PPN)186401361 035 $a(EXLCZ)993710000000434097 100 $a20150611d2015 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aColloidal Crystals of Spheres and Cubes in Real and Reciprocal Space /$fby Janne-Mieke Meijer 205 $a1st ed. 2015. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2015. 215 $a1 online resource (164 p.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $aDescription based upon print version of record. 311 $a3-319-14808-7 320 $aIncludes bibliographical references at the end of each chapters. 327 $aPreparation and Characterization of Colloidal Crystals for Synchrotron and Free Electron Laser X-ray Studies -- Double Hexagonal Close Packed Structure Revealed in a Single Colloidal Crystal Grain by Bragg Rod Analysis -- Inducing Defects in Colloidal Crystals with Thermosensitive PNIPAM Particles -- Preparation and Characterization of Colloidal Cubes -- Self-Assembly of Colloidal Cubes via Vertical Deposition -- Experimental Evidence of Optimal Packings in Convectively Assembled Crystals of Colloidal Cubes -- Self-assembly of Colloidal Cubes Induced by Sedimentation -- Sedimentary Crystals of Magnetic Colloidal Hematite Cubes and the Influence of an External Magnetic Field. 330 $aThis thesis presents an in-depth study on the effect of colloidal particle shape and formation mechanism on self-organization and the final crystal symmetries that can be achieved. It demonstrates how state-of-the-art X-ray diffraction techniques can be used to produce detailed characterizations of colloidal crystal structures prepared using different self-assembly techniques, and how smart systems can be used to investigate defect formation and diffusion in-situ. One of the most remarkable phenomena exhibited by concentrated suspensions of colloidal particles is the spontaneous self-organization into structures with long-range spatial and/or orientational orders. The study also reveals the subtle structural variations that arise by changing the particle shape from spherical to that of a rounded cube. In particular, the roundness of the cube corners, when combined with the self-organization pathway, convective assembly or sedimentation, was shown to influence the final crystal symmetries. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aAmorphous substances 606 $aComplex fluids 606 $aChemistry, Physical and theoretical 606 $aMaterials science 606 $aMaterials?Surfaces 606 $aThin films 606 $aSoft and Granular Matter, Complex Fluids and Microfluidics$3https://scigraph.springernature.com/ontologies/product-market-codes/P25021 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aCharacterization and Evaluation of Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z17000 606 $aSurfaces and Interfaces, Thin Films$3https://scigraph.springernature.com/ontologies/product-market-codes/Z19000 615 0$aAmorphous substances. 615 0$aComplex fluids. 615 0$aChemistry, Physical and theoretical. 615 0$aMaterials science. 615 0$aMaterials?Surfaces. 615 0$aThin films. 615 14$aSoft and Granular Matter, Complex Fluids and Microfluidics. 615 24$aPhysical Chemistry. 615 24$aCharacterization and Evaluation of Materials. 615 24$aSurfaces and Interfaces, Thin Films. 676 $a548.5 700 $aMeijer$b Janne-Mieke$4aut$4http://id.loc.gov/vocabulary/relators/aut$0792255 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910300431403321 996 $aColloidal Crystals of Spheres and Cubes in Real and Reciprocal Space$91771521 997 $aUNINA