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024 7 $a10.1007/978-3-319-22066-6
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100   $a20150808d2015      u|         0
101 0 $aeng
135   $aur|n|---|||||
181   $ctxt
182   $cc
183   $acr
200 10$aUltrafast Dynamics of Phospholipid-Water Interfaces $eStudied by Nonlinear Time-Resolved Vibrational Spectroscopy /$fby René Costard
205   $a1st ed. 2015.
210  1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2015.
215   $a1 online resource (112 p.)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
300   $a"Doctoral Thesis accepted by Max-Born-Institut, Berlin, Germany."
311   $a3-319-22065-9 
320   $aIncludes bibliographical references at the end of each chapters.
327   $aIntroduction -- Vibrational Spectroscopy -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Sites -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Shells -- Conclusions -- Appendix: Experimental Pulse Parameters.
330   $aThis thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of nonlinear vibrational spectroscopy, including femtosecond two-dimensional infrared spectroscopy. He shows for the first time that the structure of interfacial water undergoes very limited fluctuations on a 300 fs time scale and that the lifetimes of hydrogen bonds with the phospholipid are typically longer than 10 ps. Such properties originate from the steric hindrance of water fluctuations at the interface and the orienting action of strong electric fields from the phospholipid head group dipoles. In an extensive series of additional experiments, the vibrational lifetimes of the different vibrations and the processes of energy dissipation are elucidated in detail.
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
606   $aBiophysics
606   $aBiophysics
606   $aChemistry, Physical and theoretical
606   $aCell membranes
606   $aAtomic structure
606   $aMolecular structure
606   $aSpectrum analysis
606   $aMicroscopy
606   $aBiological and Medical Physics, Biophysics$3https://scigraph.springernature.com/ontologies/product-market-codes/P27008
606   $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001
606   $aMembrane Biology$3https://scigraph.springernature.com/ontologies/product-market-codes/L16050
606   $aAtomic/Molecular Structure and Spectra$3https://scigraph.springernature.com/ontologies/product-market-codes/P24017
606   $aSpectroscopy and Microscopy$3https://scigraph.springernature.com/ontologies/product-market-codes/P31090
615  0$aBiophysics.
615  0$aBiophysics.
615  0$aChemistry, Physical and theoretical.
615  0$aCell membranes.
615  0$aAtomic structure.
615  0$aMolecular structure.
615  0$aSpectrum analysis.
615  0$aMicroscopy.
615 14$aBiological and Medical Physics, Biophysics.
615 24$aPhysical Chemistry.
615 24$aMembrane Biology.
615 24$aAtomic/Molecular Structure and Spectra.
615 24$aSpectroscopy and Microscopy.
676   $a591.19247
700   $aCostard$b René$4aut$4http://id.loc.gov/vocabulary/relators/aut$0792805
801  0$bMiAaPQ
801  1$bMiAaPQ
801  2$bMiAaPQ
906   $aBOOK
912   $a9910300403803321
996   $aUltrafast Dynamics of Phospholipid-Water Interfaces$91780144
997   $aUNINA