LEADER 01209nam--2200373---450 001 990001516970203316 005 20210304102758.0 035 $a000151697 035 $aUSA01000151697 035 $a(ALEPH)000151697USA01 035 $a000151697 100 $a20040319d1981----km-y0itay0103----ba 101 0 $aita 102 $aVA 105 $a||||||||001yy 200 1 $aScritti di politica internazionale, 1933-1938$fAlcide De Gasperi$gpresentazione di Gabriele De Rosa 210 $aCittą del Vaticano$cLibreria editrice Vaticana$d1981 215 $a2 volumi (750 p. compless.)$d24 cm 225 2 $aStoria e attualitą$v3 410 0$12001$aStoria e attualitą$v3 454 1$12001 461 1$1001-------$12001 606 0 $aPolitica internazionale$xSaggi 676 $a327 700 1$aDE GASPERI,$bAlcide$0172251 702 1$aDE ROSA,$bGabriele$f<1917-2009> 801 0$aIT$bsalbc$gISBD 912 $a990001516970203316 951 $aX.3.A. 949/1(III E Coll 140/3 1)$b115836 L.M.$cIII E Coll 951 $aX.3.A. 949/2(III E Coll 140/3 2)$b115837 L.M.$cIII E Coll 959 $aBK 969 $aUMA 996 $aScritti di politica internazionale, 1933-1938$9935171 997 $aUNISA LEADER 05188nam 22006975 450 001 9910299615803321 005 20200725164815.0 010 $a3-658-10358-2 024 7 $a10.1007/978-3-658-10358-3 035 $a(CKB)3710000000436975 035 $a(EBL)2096064 035 $a(OCoLC)911616879 035 $a(SSID)ssj0001525072 035 $a(PQKBManifestationID)11820630 035 $a(PQKBTitleCode)TC0001525072 035 $a(PQKBWorkID)11496964 035 $a(PQKB)10619066 035 $a(DE-He213)978-3-658-10358-3 035 $a(MiAaPQ)EBC2096064 035 $a(PPN)18639859X 035 $a(EXLCZ)993710000000436975 100 $a20150622d2015 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPyridine-functionalized Polymeric Catalysts for CO2-Reduction$b[electronic resource] /$fby Melanie Weichselbaumer 205 $a1st ed. 2015. 210 1$aWiesbaden :$cSpringer Fachmedien Wiesbaden :$cImprint: Springer Spektrum,$d2015. 215 $a1 online resource (72 p.) 225 1 $aBestMasters,$x2625-3577 300 $aDescription based upon print version of record. 311 $a3-658-10357-4 320 $aIncludes bibliographical references. 327 $a""Foreword""; ""Acknowledgement""; ""Abstract""; ""Zusammenfassung""; ""Contents""; ""List of Figures""; ""1 Introduction""; ""1.1 Background""; ""1.2 Carbon Dioxide: a Greenhouse Gas""; ""1.3 Carbon Capture and Storage (CCS)""; ""1.3.1 Carbon Dioxide Separation""; ""1.3.2 Carbon Dioxide Transport""; ""1.3.3 Carbon Storage""; ""1.4 Carbon Capture and Utilization (CCU) or Carbon Diox-ide Recycling""; ""1.4.1 Biological Conversion""; ""1.4.2 Photochemical Conversion""; ""1.4.3 Electrochemical Reduction""; ""2 Experimental""; ""2.1 Apparatus""; ""2.2 Materials"" 327 $a""2.3 Setup for Electropolymerization""""2.4 Setup for Electrolysis""; ""2.5 Calculation of the halfway-potential""; ""3 Results and Discussion""; ""3.1 Chemical Synthesis""; ""3.1.1 Synthesis of 3-(6-bromohexyl)thiophene""; ""3.1.2 Synthesis of 4-(3-thienylheptyl)pyridine""; ""3.1.3 Synthesis of 4-Methyl-4a???-(3-thienylheptyl)2,2a???-bipyridine""; ""3.1.4 Synthesis of [Re(4-Methyl-4a???-(7-(3-thienyl)heptyl)-2,2a???- bipyridinyl)(CO)3Cl]""; ""3.2 Electropolymerization""; ""3.2.1 Electropolymerization of Pyridine functionalized poly(thiophene) (PP1)"" 327 $a""3.2.2 Electropolymerization of 4-Methyl-4a???-(7-(3-thienyl)heptyl)-2,2a???bipyridine""""3.2.3 Electropolymerization of Rhenium-bipyridine complex function-alized thiophene (RBPP2)""; ""3.3 Characterization of the polymeric films""; ""3.3.1 Characterization of PP1 film in acetonitrile""; ""3.3.2 Characterization of PP1 film in 0.5 M KCl""; ""3.3.3 Characterization of RBPP1 film in propylen carbonate""; ""3.3.4 Characterization of RBPP2 film""; ""3.4 Electrolysis""; ""3.4.1 Electrolysis of PP1 film in acidified 0.1 M TBAPF6 acetonitrile solution"" 327 $a""3.4.2 Electrolysis of PP1 film in 0.5 M water KCl solution""""3.4.3 Electrolysis of RBPP2 film in 0.1 M TBAPF6 in acetonitrile""; ""4 Conclusion""; ""5 Appendix""; ""6 Bibliography ""; ""References"" 330 $aMelanie Weichselbaumer presents the synthesis of the monomers as well as the electropolymerization on Pt-electrodes. The electrolysis experiments were carried out for 40 hours and the products were analysed by gas chromatography and ionic chromatography. Pyridine-functionalized and Rheniumbipyridine-functionalized Polythiophenes can be used as heterogeneous catalysts for CO2 reduction. Contents Carbon Dioxide: A Greenhouse Gas Carbon Capture and Storage Setup for Electropolymerization/Electrolysis Chemical Synthesis of Pyridine-functionalized and Rheniumbipyridine-functionalized Thiophenes Target Groups Researchers and students in the fields of greenhouse gas, global warming, CO2-reduction, electrochemistry and chemical synthesis Practitioners in these areas The Author Melanie Weichselbaumer obtained her Master?s Degree under the supervision of o.Univ. Prof. Mag. Dr. DDr. h.c. N. S. Sariciftci at University of Linz, Austria. 410 0$aBestMasters,$x2625-3577 606 $aRenewable energy resources 606 $aPhysical chemistry 606 $aCatalysis 606 $aRenewable and Green Energy$3https://scigraph.springernature.com/ontologies/product-market-codes/111000 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 615 0$aRenewable energy resources. 615 0$aPhysical chemistry. 615 0$aCatalysis. 615 14$aRenewable and Green Energy. 615 24$aPhysical Chemistry. 615 24$aCatalysis. 676 $a541 676 $a541.395 676 $a621.042 700 $aWeichselbaumer$b Melanie$4aut$4http://id.loc.gov/vocabulary/relators/aut$0956506 906 $aBOOK 912 $a9910299615803321 996 $aPyridine-functionalized Polymeric Catalysts for CO2-Reduction$92165799 997 $aUNINA