LEADER 02412oam 2200469 450 001 9910298658903321 005 20190911103512.0 010 $a1-4614-8268-2 024 7 $a10.1007/978-1-4614-8268-0 035 $a(OCoLC)875638485 035 $a(MiFhGG)GVRL6VJV 035 $a(EXLCZ)993710000000083330 100 $a20131112d2014 uy 0 101 0 $aeng 135 $aurun|---uuuua 181 $ctxt 182 $cc 183 $acr 200 10$aElectrostatic and stereoelectronic effects in carbohydrate chemistry /$fMomcilo Miljkovic 205 $a1st ed. 2014. 210 1$aNew York :$cSpringer,$d2014. 215 $a1 online resource (xii, 304 pages) $cillustrations 225 0 $aGale eBooks 300 $aDescription based upon print version of record. 311 $a1-4614-8267-4 320 $aIncludes bibliographical references at the end of each chapter and indexes. 327 $aIntramolecular Electrostatic Interacations -- Anomeric Effects -- Acid Catalyzed Hydrolysis of Glycosides -- Conformation and Chemistry of Oxocarbenium Ion -- Glycosylation -- Stereoelectronic Effects in Nucleosides and Nucleotides -- Free Radical Cyclizations -- Sulfones, Olefins, Nitrones, Glycosidic Bond, and Norrish-Young Photocyclization. 330 $aThe book deals with polar effects in carbohydrates and how these effects control the stereochemistry of carbohydrate reactions. This is important for understanding the mechanisms of certain carbohydrate reactions, including enzymatic reactions such as glycosidases, a very important group of enzymes in living matter. It is also very useful for synthetic carbohydrate chemists who would like to synthesize stereoselectively certain classes of carbohydrates. This book will be a very important source of information for practicing synthetic carbohydrate chemists. The book will also be helpful for organic chemists, or for those studying glycobiology. 606 $aCarbohydrates 606 $aElectrostatics 615 0$aCarbohydrates. 615 0$aElectrostatics. 676 $a54 676 $a547 676 $a547.78 700 $aMiljkovic$b Momcilo$4aut$4http://id.loc.gov/vocabulary/relators/aut$01063349 801 0$bMiFhGG 801 1$bMiFhGG 906 $aBOOK 912 $a9910298658903321 996 $aElectrostatic and Stereoelectronic Effects in Carbohydrate Chemistry$92531903 997 $aUNINA