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100   $a20150613d2015      u|             0
101 0 $aeng
135   $aur|n|---|||||
181   $ctxt
182   $cc
183   $acr
200 10$aSynthesis and Original Reactivity of Copper and Gold Complexes$b[electronic resource] $e?-Bond Coordination, Oxidative Addition, Migratory Insertion /$fby Maximilian Joost
205   $a1st ed. 2015.
210  1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2015.
215   $a1 online resource (244 p.)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
300   $aDescription based upon print version of record.
311   $a3-319-18689-2 
320   $aIncludes bibliographical references.
327   $aGeneral Introduction -- Copper: ?-SiH Coordination to Cu(I) -- Fundamental Elementary Steps in Gold Chemistry -- Gold: Migratory Insertion at Au(I) -- Gold: Oxidative Addition to Au(I) -- General Conclusion and Perspective -- Appendix: Crystallographic Data.
330   $aThis thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of ?-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first ?-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into ?-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of ?-SiSi, ?-CC and ?-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of ?-CC and ?-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
606   $aOrganometallic chemistry 
606   $aPhysical chemistry
606   $aChemoinformatics
606   $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020
606   $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001
606   $aComputer Applications in Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C13009
615  0$aOrganometallic chemistry .
615  0$aPhysical chemistry.
615  0$aChemoinformatics.
615 14$aOrganometallic Chemistry.
615 24$aPhysical Chemistry.
615 24$aComputer Applications in Chemistry.
676   $a54
676   $a541
676   $a541.0285
676   $a547.05
700   $aJoost$b Maximilian$4aut$4http://id.loc.gov/vocabulary/relators/aut$0974047
906   $aBOOK
912   $a9910298634203321
996   $aSynthesis and Original Reactivity of Copper and Gold Complexes$92217269
997   $aUNINA