LEADER 01707aam 2200433I 450 001 9910710775603321 005 20160421112332.0 024 8 $aGOVPUB-C13-c474835bf829b11d278f3afd847bf0f2 035 $a(CKB)5470000002478549 035 $a(OCoLC)947047572 035 $a(EXLCZ)995470000002478549 100 $a20160421d2004 ua 0 101 0 $aeng 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aSatellite instrument calibration for measuring global climate change $ereport of a workshop at the University of Maryland Inn and Conference Center, College Park, MD, November 12-14, 2002 /$fGeorge Ohring; Bruce Wielicki; Roy Spencer; Bill Emery; Raju Datla 210 1$aGaithersburg, MD :$cU.S. Dept. of Commerce, National Institute of Standards and Technology,$d2004. 215 $a1 online resource 225 1 $aNISTIR ;$v7047 300 $a2004. 300 $aContributed record: Metadata reviewed, not verified. Some fields updated by batch processes. 300 $aTitle from PDF title page. 320 $aIncludes bibliographical references. 517 $aSatellite instrument calibration for measuring global climate change 700 $aOhring$b George$01504 701 $aDatla$b Raju$01410275 701 $aEmery$b Bill$01410276 701 $aOhring$b George$01504 701 $aSpencer$b Roy$0571141 701 $aWielicki$b Bruce$01410277 712 02$aNational Institute of Standards and Technology (U.S.) 801 0$bNBS 801 1$bNBS 801 2$bGPO 906 $aBOOK 912 $a9910710775603321 996 $aSatellite instrument calibration for measuring global climate change$93498608 997 $aUNINA LEADER 04187nam 22006735 450 001 9910298634203321 005 20200704024928.0 010 $a3-319-18690-6 024 7 $a10.1007/978-3-319-18690-0 035 $a(CKB)3710000000434148 035 $a(EBL)2120635 035 $a(OCoLC)916951321 035 $a(SSID)ssj0001525278 035 $a(PQKBManifestationID)11936252 035 $a(PQKBTitleCode)TC0001525278 035 $a(PQKBWorkID)11485264 035 $a(PQKB)11430967 035 $a(DE-He213)978-3-319-18690-0 035 $a(MiAaPQ)EBC2120635 035 $a(PPN)186401388 035 $a(EXLCZ)993710000000434148 100 $a20150613d2015 u| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSynthesis and Original Reactivity of Copper and Gold Complexes $e?-Bond Coordination, Oxidative Addition, Migratory Insertion /$fby Maximilian Joost 205 $a1st ed. 2015. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2015. 215 $a1 online resource (244 p.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $aDescription based upon print version of record. 311 $a3-319-18689-2 320 $aIncludes bibliographical references. 327 $aGeneral Introduction -- Copper: ?-SiH Coordination to Cu(I) -- Fundamental Elementary Steps in Gold Chemistry -- Gold: Migratory Insertion at Au(I) -- Gold: Oxidative Addition to Au(I) -- General Conclusion and Perspective -- Appendix: Crystallographic Data. 330 $aThis thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of ?-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first ?-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into ?-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of ?-SiSi, ?-CC and ?-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of ?-CC and ?-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aOrganometallic chemistry 606 $aChemistry, Physical and theoretical 606 $aCheminformatics 606 $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aComputer Applications in Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C13009 615 0$aOrganometallic chemistry. 615 0$aChemistry, Physical and theoretical. 615 0$aCheminformatics. 615 14$aOrganometallic Chemistry. 615 24$aPhysical Chemistry. 615 24$aComputer Applications in Chemistry. 676 $a54 676 $a541 676 $a541.0285 676 $a547.05 700 $aJoost$b Maximilian$4aut$4http://id.loc.gov/vocabulary/relators/aut$0974047 906 $aBOOK 912 $a9910298634203321 996 $aSynthesis and Original Reactivity of Copper and Gold Complexes$92217269 997 $aUNINA