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010   $a3-658-08793-5
024 7 $a10.1007/978-3-658-08793-7
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035   $a(DE-He213)978-3-658-08793-7
035   $a(MiAaPQ)EBC2096174
035   $a(PPN)184894611
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100   $a20150317d2015      u|         0
101 0 $aeng
135   $aur|n|---|||||
181   $ctxt
182   $cc
183   $acr
200 10$aElectron Microscopical Investigation of Interdiffusion and Phase Formation at Gd2O3/CeO2- and Sm2O3/CeO2-Interfaces /$fby Christian Rockenhäuser
205   $a1st ed. 2015.
210  1$aWiesbaden :$cSpringer Fachmedien Wiesbaden :$cImprint: Springer,$d2015.
215   $a1 online resource (117 p.)
225 1 $aMatWerk,$x2522-0756
300   $a"Research"--Cover.
311 08$a3-658-08792-7 
320   $aIncludes bibliographical references.
327   $aIntroduction -- Fundamentals -- Experimental Techniques and Instrumentation -- The Gd(x)Ce(1-x)O(2-x/2) System: Phase Formation and Cation Interdiffusion -- The Sm(x)Ce(1-x)O(2-x/2) System: Phase Formation and Cation Interdiffusion -- Summary.  .
330   $aChristian Rockenhäuser adresses phase formation and cation interdiffusion of the GdxCe1-xO2-x/2-and SmxCe1-xO2-x/2-material systems at temperatures ranging from 970 to 1270°C. Diffusion couples with CeO2/Sm2O3 and CeO2/Gd2O3 interfaces were fabricated for the investigations. The resulting reaction phases were investigated utilizing transmission electron microscopy (TEM) and allow conclusions regarding the phase diagrams in the examined temperature range. A miscibility gap can be ruled out for GdxCe1-xO2-x/2 across the whole composition range. Cation interdiffusion coefficients were determined for both material systems by measuring and evaluating concentration profiles at the material interfaces. The activation enthalpies for interdiffusion were calculated using the temperature dependence of the interdiffusion coefficients. The study for the first time compiles comprehensively the previous results regarding the phase diagrams of the two material systems since 1923.
410  0$aMatWerk,$x2522-0756
606   $aChemistry, Physical and theoretical
606   $aThermodynamics
606   $aHeat engineering
606   $aHeat$xTransmission
606   $aMass transfer
606   $aMaterials science
606   $aEnergy systems
606   $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001
606   $aEngineering Thermodynamics, Heat and Mass Transfer$3https://scigraph.springernature.com/ontologies/product-market-codes/T14000
606   $aMaterials Science, general$3https://scigraph.springernature.com/ontologies/product-market-codes/Z00000
606   $aEnergy Systems$3https://scigraph.springernature.com/ontologies/product-market-codes/115000
615  0$aChemistry, Physical and theoretical.
615  0$aThermodynamics.
615  0$aHeat engineering.
615  0$aHeat$xTransmission.
615  0$aMass transfer.
615  0$aMaterials science.
615  0$aEnergy systems.
615 14$aPhysical Chemistry.
615 24$aEngineering Thermodynamics, Heat and Mass Transfer.
615 24$aMaterials Science, general.
615 24$aEnergy Systems.
676   $a54
676   $a541
676   $a620.11
676   $a621.042
676   $a621.4021
700   $aRockenhäuser$b Christian$4aut$4http://id.loc.gov/vocabulary/relators/aut$0994062
906   $aBOOK
912   $a9910298617203321
996   $aElectron Microscopical Investigation of Interdiffusion and Phase Formation at Gd2O3$92276636
997   $aUNINA