LEADER 04459nam 22006375 450 001 9910298606603321 005 20200629193436.0 010 $a981-10-8932-9 024 7 $a10.1007/978-981-10-8932-9 035 $a(CKB)4100000003359791 035 $a(MiAaPQ)EBC5343209 035 $a(DE-He213)978-981-10-8932-9 035 $a(PPN)22669352X 035 $a(EXLCZ)994100000003359791 100 $a20180407d2018 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aAssembled Lanthanide Complexes with Advanced Photophysical Properties$b[electronic resource] /$fby Yuichi Hirai 205 $a1st ed. 2018. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2018. 215 $a1 online resource (115 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $a"Doctoral thesis accepted by the Hokkaido University, Hokkaido, Japan." 311 $a981-10-8931-0 327 $aGeneral introduction -- Luminescent lanthanide coordination polymers with densely-packed structures for high energy transfer efficiency -- Luminescent lanthanide-mixed coordination polymers for tunable temperature-sensitivity -- Construction of luminescent lanthanide coordination glass -- Amorphous formability and temperature-sensitive luminescence of lanthanide coordination glasses.-Triboluminescence of lanthanide coordination polymers -- Summary. 330 $aThis thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers? fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f?4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aOrganometallic chemistry  606 $aInorganic chemistry 606 $aTribology 606 $aCorrosion and anti-corrosives 606 $aCoatings 606 $aPolymers   606 $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020 606 $aInorganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C16008 606 $aTribology, Corrosion and Coatings$3https://scigraph.springernature.com/ontologies/product-market-codes/Z15000 606 $aPolymer Sciences$3https://scigraph.springernature.com/ontologies/product-market-codes/C22008 615 0$aOrganometallic chemistry . 615 0$aInorganic chemistry. 615 0$aTribology. 615 0$aCorrosion and anti-corrosives. 615 0$aCoatings. 615 0$aPolymers  . 615 14$aOrganometallic Chemistry. 615 24$aInorganic Chemistry. 615 24$aTribology, Corrosion and Coatings. 615 24$aPolymer Sciences. 676 $a546.41 700 $aHirai$b Yuichi$4aut$4http://id.loc.gov/vocabulary/relators/aut$0769141 906 $aBOOK 912 $a9910298606603321 996 $aAssembled Lanthanide Complexes with Advanced Photophysical Properties$91567649 997 $aUNINA