LEADER 04040nam 22006855 450 001 9910298602903321 005 20230810193604.0 010 $a3-319-77574-X 024 7 $a10.1007/978-3-319-77574-6 035 $a(CKB)4100000004835969 035 $a(MiAaPQ)EBC5433810 035 $a(DE-He213)978-3-319-77574-6 035 $a(PPN)229495532 035 $a(EXLCZ)994100000004835969 100 $a20180618d2018 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aNonlinear Dielectric Spectroscopy /$fedited by Ranko Richert 205 $a1st ed. 2018. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2018. 215 $a1 online resource (377 pages) 225 1 $aAdvances in Dielectrics,$x2190-9318 311 $a3-319-77573-1 327 $aIntroduction -- Experiment -- Theory/Modeling. 330 $aThis book introduces the ideas and concepts of nonlinear dielectric spectroscopy, outlines its history, and provides insight into the present state of the art of the experimental technology and understanding of nonlinear dielectric effects. Emphasis is on what can be learned from nonlinear experiments that could not be derived from the linear counterparts. The book explains that nonlinear dielectric spectroscopy can be used as a tool to measure structural recovery or physical aging, as well as connections between dynamics and thermodynamic variables such as enthalpy and entropy. Supercooled liquids in their viscous regime are ideal candidates for investigating nonlinear effects, because they are particularly sensitive to changes in temperature, and thus also to changes in the electric field. Other interesting materials covered are plastic crystals and complex liquids near criticality. The book also points out that, compared with other techniques such as mechanical shear experiments, the nonlinear regime of dielectric spectroscopy is special in the sense that the energies involved always remain small compared with thermal energies. To demonstrate this, nonlinear features of mechanical experiments are discussed. Theoretical approaches to nonlinear effects are particularly complicated because the tools available for the linear regime no longer apply. As a result, there is no single generally accepted theory to nonlinear dielectric responses of real liquids. Various approaches to nonlinear dielectric features have been reported, and the different aspects are communicated in several chapters. The book communicates recent progress most effectively through individual contributions from specialists in their respective fields. Chapter 'Third and Fifth Harmonic Responses in Viscous Liquids' is available open access under a Creative Commons Attribution 4.0 International License via link.springer.com. 410 0$aAdvances in Dielectrics,$x2190-9318 606 $aSpectrum analysis 606 $aAtoms 606 $aMolecules 606 $aMaterials$xAnalysis 606 $aElectrochemistry 606 $aSoft condensed matter 606 $aSpectroscopy 606 $aAtoms and molecules in external fields 606 $aCharacterization and Analytical Technique 606 $aElectrochemistry 606 $aSoft and Granular Matter 615 0$aSpectrum analysis. 615 0$aAtoms. 615 0$aMolecules. 615 0$aMaterials$xAnalysis. 615 0$aElectrochemistry. 615 0$aSoft condensed matter. 615 14$aSpectroscopy. 615 24$aAtoms and molecules in external fields. 615 24$aCharacterization and Analytical Technique. 615 24$aElectrochemistry. 615 24$aSoft and Granular Matter. 676 $a535.84 702 $aRichert$b Ranko$4edt$4http://id.loc.gov/vocabulary/relators/edt 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910298602903321 996 $aNonlinear Dielectric Spectroscopy$91566637 997 $aUNINA