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010   $a3-319-77914-1
024 7 $a10.1007/978-3-319-77914-0
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035   $a(MiAaPQ)EBC5356226
035   $a(DE-He213)978-3-319-77914-0
035   $a(PPN)226693511
035   $a(EXLCZ)994100000003359563
100   $a20180419d2018      u|         0
101 0 $aeng
135   $aurcnu||||||||
181   $ctxt$2rdacontent
182   $cc$2rdamedia
183   $acr$2rdacarrier
200 10$aAssemblies of Gold Nanoparticles at Liquid-Liquid Interfaces $eFrom Liquid Optics to Electrocatalysis /$fby Evgeny Smirnov
205   $a1st ed. 2018.
210  1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2018.
215   $a1 online resource (270 pages)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
311   $a3-319-77913-3 
327   $aIntroduction -- Experimental and Instrumentation -- Self-assembly of Nanoparticles into Gold Metal Liquid-Like Droplets (MeLLDs) -- Optical properties of self-healing gold nanoparticle mirrors and filters at Liquid-Liquid interfaces -- Self-assembly of gold nanoparticles: low interfacial tensions -- Electrochemical investigation of nanofilms at liquid-liquid interface -- Electron transfer reactions and redox catalysis on gold nanofilms at soft interfaces -- Gold nanofilm redox electrocatalysis for oxygen reduction at soft interfaces -- Perspectives: from Colloidosomes through SERS to electrically driven Marangoni Shutters -- General conclusions.
330   $aThis book is devoted to various aspects of self-assembly of gold nanoparticles at liquid-liquid interfaces and investigation of their properties. It covers primarily two large fields: (i) self-assembly of nanoparticles and optical properties of these assemblies; and (ii) the role of nanoparticles in redox electrocatalysis at liquid-liquid interfaces. The first part aroused from a long-lasting idea to manipulate adsorption of nanoparticles at liquid-liquid with an external electric field to form 'smart' mirrors and/or filters. Therefore, Chapters 3 to 5 are dedicated to explore fundamental aspects of charged nanoparticles self-assembly and to investigate optical properties (extinction and reflectance) in a through manner. Novel tetrathiafulvalene (TTF)-assisted method leads to self-assembly of nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs) with remarkable optical properties. The second part (Chapters 6 to 8) clarifies the role of nanoparticles in interfacial electron transfer reactions. They demonstrate how nanoparticles are charged and discharged upon equilibration of Fermi levels with redox couples in solution and how it can be used to perform HER and ORR. Finally, chapter 9 gives a perspective outlook, including applications of suggested methods in fast, one-step preparation of colloidosomes, SERS substrates as well as pioneer studies on so-called Marangony-type shutters drive by the electric field. .
410  0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
606   $aNanotechnology
606   $aMaterials science
606   $aElectrochemistry
606   $aCatalysis
606   $aNanotechnology$3https://scigraph.springernature.com/ontologies/product-market-codes/Z14000
606   $aCharacterization and Evaluation of Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z17000
606   $aElectrochemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21010
606   $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000
615  0$aNanotechnology.
615  0$aMaterials science.
615  0$aElectrochemistry.
615  0$aCatalysis.
615 14$aNanotechnology.
615 24$aCharacterization and Evaluation of Materials.
615 24$aElectrochemistry.
615 24$aCatalysis.
676   $a547.28
700   $aSmirnov$b Evgeny$4aut$4http://id.loc.gov/vocabulary/relators/aut$0769149
906   $aBOOK
912   $a9910298592303321
996   $aAssemblies of Gold Nanoparticles at Liquid-Liquid Interfaces$91567661
997   $aUNINA