LEADER 03506nam 22006015 450 001 9910298590603321 005 20200702175822.0 010 $a981-10-8327-4 024 7 $a10.1007/978-981-10-8327-3 035 $a(CKB)4100000004244301 035 $a(MiAaPQ)EBC5398099 035 $a(DE-He213)978-981-10-8327-3 035 $a(PPN)227399293 035 $a(EXLCZ)994100000004244301 100 $a20180516d2018 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aFire Retardancy Behavior of Polymer/Clay Nanocomposites /$fby Indraneel Suhas Zope 205 $a1st ed. 2018. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2018. 215 $a1 online resource (190 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a981-10-8326-6 327 $aIntroduction -- Literature Review -- Experimental Methodology -- Decomposition Behavior of Metal-ion Exchanged Clay -- Thermo-oxidative Decomposition Behavior of Polyamide 6 Nanocomposites with Metal-ion Exchanged Clays -- Thermo-oxidative Decomposition Behavior of Polyamide 6 Nanocomposites with Structurally Different Clays -- Controlling the Interfacial Interactions Between Clay and Host Polyamide 6 Matrix -- Clay Catalysis and Fire Retardancy of Polymer/Clay Nanocomposites: A Complete Overview. 330 $aThis thesis investigates the early ignition behavior of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition.  Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer?clay interfacial interaction. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aCeramics 606 $aGlass 606 $aComposites (Materials) 606 $aComposite materials 606 $aEngineering?Materials 606 $aPolymers   606 $aCeramics, Glass, Composites, Natural Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z18000 606 $aMaterials Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/T28000 606 $aPolymer Sciences$3https://scigraph.springernature.com/ontologies/product-market-codes/C22008 615 0$aCeramics. 615 0$aGlass. 615 0$aComposites (Materials). 615 0$aComposite materials. 615 0$aEngineering?Materials. 615 0$aPolymers  . 615 14$aCeramics, Glass, Composites, Natural Materials. 615 24$aMaterials Engineering. 615 24$aPolymer Sciences. 676 $a628.9223 700 $aZope$b Indraneel Suhas$4aut$4http://id.loc.gov/vocabulary/relators/aut$01062859 906 $aBOOK 912 $a9910298590603321 996 $aFire Retardancy Behavior of Polymer$92528770 997 $aUNINA