LEADER 04988nam 22006855 450 001 9910298463503321 005 20200702164754.0 010 $a3-319-08632-4 024 7 $a10.1007/978-3-319-08632-3 035 $a(CKB)3710000000227313 035 $a(SSID)ssj0001338404 035 $a(PQKBManifestationID)11898425 035 $a(PQKBTitleCode)TC0001338404 035 $a(PQKBWorkID)11337617 035 $a(PQKB)10904834 035 $a(DE-He213)978-3-319-08632-3 035 $a(MiAaPQ)EBC6312912 035 $a(MiAaPQ)EBC5588212 035 $a(Au-PeEL)EBL5588212 035 $a(OCoLC)890464437 035 $a(PPN)180627589 035 $a(EXLCZ)993710000000227313 100 $a20140827d2014 u| 0 101 0 $aeng 135 $aurnn#008mamaa 181 $ctxt 182 $cc 183 $acr 200 10$aAdvanced Separation Techniques for Polyolefins /$fby Harald Pasch, Muhammad Imran Malik 205 $a1st ed. 2014. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2014. 215 $a1 online resource (XII, 179 p. 121 illus., 44 illus. in color.) 225 1 $aSpringer Laboratory, Manuals in Polymer Science,$x0945-6074 300 $aBibliographic Level Mode of Issuance: Monograph 311 $a3-319-08631-6 327 $aPart A Introduction -- Molecular Heterogeneity of Polyolefins -- Analytical Methods for Polyolefins -- Part B Crystallization-Based Fractionation Techniques -- Temperature Rising Elution Fractionation -- Crystallization Analysis Fractionation -- Crystallization Elution Fractionation -- Part C Column-Based Chromatographic Techniques -- Multidetector Size Exclusion Chromatography -- Solvent Gradient Interaction Chromatography -- Temperature Gradient Interaction Chromatography -- Two-Dimensional Liquid Chromatography -- Part D Field-Flow Fractionation -- Fundamentals -- Application of Field-Flow Fractionation of Polyolefins -- Analysis of Polyolefins by Asymmetric Flow FFF -- Conclusions and Future Trends. 330 $aThis Springer Laboratory volume introduces the reader to advanced techniques for the separation and fractionation of polyolefins. It includes detailed information on experimental protocols and procedures, addressing the experimental background of different polyolefin fractionation techniques in great detail. The book summarizes important applications in all major fractionation methods with emphasis on multidimensional analytical approaches. It comprises the most powerful modern techniques, such as high temperature size exclusion chromatography (HT-SEC) for molar mass analysis, temperature rising elution fractionation (TREF) and crystallization analysis fractionation (CRYSTAF) for the analysis of chemical composition and branching, high temperature two-dimensional liquid chromatography (HT-2D-LC), solvent and temperature gradient interaction chromatography (SGIC and TGIC) and crystallization elution fractionation (CEF).Beginners as well as experienced chromatographers will benefit from this concise introduction to a great variety in instrumentation, separation procedures and applications. With detailed descriptions of experimental approaches for the analysis of complex polyolefins, the readers are offered a toolbox to solve simple as well as sophisticated separation tasks. The book starts with an introduction into the molecular complexity of polyolefins - the most widely used synthetic polymers with rapidly growing production capacities. It systematically discusses crystallization based fractionation techniques including TREF, CRYSTAF and CEF, and column chromatographic techniques for molar mass, chemical composition and microstructure, as well as the combination of different fractionations in multidimensional experimental setups. This book also includes basic information on the application of high-temperature field-flow fractionation. 410 0$aSpringer Laboratory, Manuals in Polymer Science,$x0945-6074 606 $aPolymers   606 $aChromatography 606 $aOrganic chemistry 606 $aPolymer Sciences$3https://scigraph.springernature.com/ontologies/product-market-codes/C22008 606 $aChromatography$3https://scigraph.springernature.com/ontologies/product-market-codes/C11030 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 615 0$aPolymers  . 615 0$aChromatography. 615 0$aOrganic chemistry. 615 14$aPolymer Sciences. 615 24$aChromatography. 615 24$aOrganic Chemistry. 676 $a540 700 $aPasch$b Harald$4aut$4http://id.loc.gov/vocabulary/relators/aut$0769892 702 $aMalik$b Muhammad Imran$4aut$4http://id.loc.gov/vocabulary/relators/aut 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910298463503321 996 $aAdvanced Separation Techniques for Polyolefins$92525185 997 $aUNINA