LEADER 01214nam0-2200277 --450 001 9910293846203321 005 20181207082455.0 020 $aIT$b619583 100 $a20181207d1961----kmuy0itay5050 ba 101 0 $aita 102 $aIT 105 $a 001yy 200 1 $aCriteri e direttive per la redazione dei piani regolatori territoriali delle aree di sviluppo industriale e dei nuclei di industrializzazione 210 $aRoma$cIstituto poligrafico dello Stato$d1961 215 $a14 p.$d25 cm 300 $aPrima del titolo: Circolare del 9 marzo 1961 destinata ai Consorzi per le aree di sviluppo industriale, ai Consorzi per i nuclei di industrializzazione ed alle prefetture del Mezzogiorno, Prot. n. 2356 610 0 $aItalia meridionale$aZone industriali$aPiani regolatori 676 $a711$v16 710 02$aItalia.$bComitato dei ministri per il Mezzogiorno$0331910 801 0$aIT$bUNINA$gREICAT$2UNIMARC 901 $aBK 912 $a9910293846203321 952 $aINU B 1337$b2245$fFARBC 959 $aFARBC 996 $aCriteri e direttive per la redazione dei piani regolatori territoriali delle aree di sviluppo industriale e dei nuclei di industrializzazione$91539712 997 $aUNINA LEADER 05557nam 2200661 450 001 9910830798503321 005 20200520144314.0 010 $a3-527-69848-5 010 $a3-527-69846-9 010 $a3-527-69847-7 024 7 $a10.1002/9783527698479 035 $a(CKB)4330000000010717 035 $a(EBL)4538963 035 $a(OCoLC)951434460 035 $a(MiAaPQ)EBC4538963 035 $a(Au-PeEL)EBL4538963 035 $a(CaPaEBR)ebr11218602 035 $a(CaONFJC)MIL928259 035 $a(NjHacI)994330000000010717 035 $a(BIP)054999322 035 $a(EXLCZ)994330000000010717 100 $a20160623h20162016 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 00$aAsymmetric dearomatization reactions /$fedited by Shu-Li You 210 1$aWeinheim, Germany :$cWiley-VCH,$d2016. 210 4$d2016 215 $a1 online resource (422 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33851-9 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aCover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Introduction; 1.1 Why Asymmetric Dearomatization Reactions?; 1.2 Discovery of Aromatic Compounds and Dearomatization Reactions; 1.3 Development of Dearomatization Reactions; 1.4 Asymmetric Dearomatization Reactions; References; Chapter 2 Asymmetric Dearomatization with Chiral Auxiliaries and Reagents; 2.1 Introduction; 2.2 Chiral -Bound Auxiliaries; 2.2.1 Oxazolines; 2.2.2 Imines, Oxazolidines, and Hydrazones; 2.2.3 Chiral Ethers and Amines; 2.3 Diastereospecific Anionic Cyclizations; 2.4 Use of Chiral Reagents 327 $a2.4.1 Chiral Bases in Dearomatizing Cyclizations2.4.2 Chiral Nucleophiles; 2.4.3 Chiral Ligands in Enantioselective Nucleophilic Additions; 2.5 Chiral -Complexes; 2.5.1 Planar Chiral 6-Arene Complexes; 2.5.2 6-Arene Complexes with a Chiral Ligand; 2.5.3 Complexes with Stereogenic Metal Centers; 2.6 Conclusion; References; Chapter 3 Organocatalytic Asymmetric Transfer Hydrogenation of (Hetero)Arenes; 3.1 Introduction; 3.2 Organocatalytic Asymmetric Transfer Hydrogenation of Heteroaromatics; 3.2.1 Quinolines; 3.2.1.1 Proof-of-Concept; 3.2.1.2 2-Substituted Quinolines 327 $a3.2.1.3 4-Substituted Quinolines3.2.1.4 3-Substituted Quinolines; 3.2.1.5 2,3-Disubstituted Quinolines; 3.2.1.6 Spiro-Tetrahydroquinolines; 3.2.2 Benzoxazines, Benzothiazines, and Benzoxazinones; 3.2.3 Benzodiazepines and Benzodiazepinones; 3.2.4 Pyridines; 3.2.5 3H-Indoles; 3.2.6 Quinoxalines and Quinoxalinones; 3.3 Organocatalytic Asymmetric Transfer Hydrogenation in Aqueous Solution; 3.4 Cascade Reactions; 3.4.1 Introduction; 3.4.2 In situ Generation of the Heteroarene; 3.4.3 Dearomatization of Pyridine/Asymmetric aza-Friedel-Crafts Alkylation Cascade 327 $a3.4.4 Combining Photochemistry and Brønsted Acid Catalysis3.4.4.1 Quinolines; 3.4.4.2 Pyrylium ions; 3.5 Cooperative and Relay Catalysis: Combining Brønsted Acid- and Metal-Catalysis; 3.5.1 Introduction; 3.5.2 Improvements in Transfer Hydrogenation; 3.5.2.1 Regenerable Hydrogen Sources; 3.5.2.2 Asymmetric Relay Catalysis (ARC); 3.5.3 Cooperative Metal-Brønsted Acid Catalysis; 3.6 Summary and Conclusion; References; Chapter 4 Transition-Metal-Catalyzed Asymmetric Hydrogenation of Aromatics; 4.1 Introduction; 4.2 Catalytic Asymmetric Hydrogenation of Five-Membered Heteroarenes 327 $a4.2.1 Catalytic Asymmetric Hydrogenation of Azoles and Indoles4.2.1.1 Rhodium-Catalyzed Asymmetric Hydrogenation of Indoles; 4.2.1.2 Ruthenium-Catalyzed Asymmetric Hydrogenation of Azoles; 4.2.1.3 Palladium-Catalyzed Asymmetric Hydrogenation of Azoles; 4.2.1.4 Iridium-Catalyzed Asymmetric Hydrogenation of Indoles; 4.2.2 Catalytic Asymmetric Hydrogenation of Oxygen-Containing Heteroarenes; 4.2.3 Catalytic Asymmetric Hydrogenation of Sulfur-Containing Heteroarenes; 4.3 Catalytic Asymmetric Hydrogenation of Six-Membered Heteroarenes; 4.3.1 Catalytic Asymmetric Hydrogenation of Azines 327 $a4.3.1.1 Iridium-Catalyzed Asymmetric Hydrogenation of Pyridines 330 $aAnnotation The first comprehensive account of the rapidly growing field of asymmetric dearomatization reactions with a focus on catalytic methods. It introduces the concept of dearomatization and describes recent progress in asymmetric reaction procedures with different catalyst systems, such as organocatalysts, transition metal catalysts, and enzymes. Chapters on dearomatizations of electron-deficient aromatic rings, dearomatization reactions via transition metal-catalyzed cross-couplings as well as dearomatization strategies in the synthesis of complex natural products are also included. Written by pioneers in the field, this is a highly valuable source of information not only for professional synthetic chemists in academia and industry but also for all those are interested in asymmetric methodologies and organic synthesis in general. 606 $aCatalysis 606 $aChemistry 610 $aChemical Reactions 610 $aChemistry 610 $aAromatic Compounds 610 $aScience 615 0$aCatalysis. 615 0$aChemistry. 676 $a541.395 702 $aYou$b Shu-Li 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830798503321 996 $aAsymmetric dearomatization reactions$94087019 997 $aUNINA