LEADER 03519nam 22005895 450 001 9910254057903321 005 20200701032617.0 010 $a981-10-1569-4 024 7 $a10.1007/978-981-10-1569-4 035 $a(CKB)3710000000722401 035 $a(DE-He213)978-981-10-1569-4 035 $a(MiAaPQ)EBC4539646 035 $a(PPN)194379612 035 $a(EXLCZ)993710000000722401 100 $a20160604d2016 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aFunctionalization of Carborane via Carboryne Intermediates /$fby Da Zhao 205 $a1st ed. 2016. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2016. 215 $a1 online resource (XVII, 170 p. 126 illus., 5 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $a"Doctoral Thesis accepted by The Chinese University of Hong Kong, Hong Kong." 311 $a981-10-1568-6 320 $aIncludes bibliographical references at the end of each chapters. 327 $aIntroduction -- Regioselective Insertion of ?-Carborynes into ?-C?H Bond of Tertiary Amines -- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C?H Insertion Reaction -- Reaction of ?-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition -- 1,3-Dehydro-?-Carborane: Generation and Reaction with Arenes -- Ene Reaction of 1,3-Dehydro-?-Carborane -- Cage Boron Arylation of ?-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling -- Conclusion -- Experimental Section. 330 $aThis thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal?organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis. . 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aOrganic chemistry 606 $aPhysical chemistry 606 $aCatalysis 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 615 0$aOrganic chemistry. 615 0$aPhysical chemistry. 615 0$aCatalysis. 615 14$aOrganic Chemistry. 615 24$aPhysical Chemistry. 615 24$aCatalysis. 676 $a547.05671 700 $aZhao$b Da$4aut$4http://id.loc.gov/vocabulary/relators/aut$01059899 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910254057903321 996 $aFunctionalization of Carborane via Carboryne Intermediates$92509401 997 $aUNINA