LEADER 02272nam 2200481 450 001 9910164997503321 005 20200520144314.0 010 $a1-5231-1494-0 010 $a1-119-18898-9 010 $a1-119-18900-4 035 $a(CKB)4330000000009209 035 $a(MiAaPQ)EBC4815052 035 $a(DLC) 2017005375 035 $a(Au-PeEL)EBL4815052 035 $a(CaPaEBR)ebr11354731 035 $a(CaONFJC)MIL994743 035 $a(OCoLC)975224226 035 $a(EXLCZ)994330000000009209 100 $a20170127d2017 uy| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aLimits of detection in chemical analysis /$fEdward Voigtman 210 1$aHoboken, New Jersey :$cJohn Wiley & Sons,$d2017. 215 $a1 online resource (409 pages) $cillustrations (some color) 225 0 $aChemical analysis series 311 $a1-119-18899-7 311 $a1-119-18897-0 320 $aIncludes bibliographical references and index. 327 $aBackground -- Chemical measurement systems and their errors -- The response, net response and content domains -- Traditional limits of detection -- Modern limits of detection -- Receiver operating characteristics -- Statistics of an ideal model CMS -- If only the true intercept is unknown -- If only the true slope is unknown -- If the true intercept and true slope are both unknown -- If only the population standard deviation is unknown -- If only the true slope is known -- If only the true intercept is known -- If all three parameters are unknown -- Bootstrapped detection limits in a real CMS -- Four relevant considerations -- Neyman-Pearson hypothesis testing -- Heteroscedastic noises -- Limits of quantitation -- The sampled step function -- The sampled rectangular pulse -- The sampled triangular pulse -- The sampled Gaussian pulse -- Parting considerations. 606 $aChemistry, Analytic 615 0$aChemistry, Analytic. 676 $a543/.19 700 $aVoigtman$b Edward$f1949-$0916297 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910164997503321 996 $aLimits of detection in chemical analysis$92054196 997 $aUNINA