LEADER 02850nam 2200445 450 001 9910483028303321 005 20211020071116.0 010 $a981-16-1163-7 035 $a(CKB)4100000011867244 035 $a(MiAaPQ)EBC6533406 035 $a(Au-PeEL)EBL6533406 035 $a(OCoLC)1245674790 035 $a(PPN)255291078 035 $a(EXLCZ)994100000011867244 100 $a20211020d2021 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aKinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex /$fKenichi Endo 210 1$aSingapore :$cSpringer,$d[2021] 210 4$d©2021 215 $a1 online resource (xv, 80 pages) 225 1 $aSpringer theses 311 $a981-16-1162-9 320 $aIncludes bibliographical references. 327 $aIntro -- Supervisor's Foreword -- Acknowledgments -- Contents -- Abbreviations -- 1 General Introduction -- 1.1 Selective Synthesis of Metal Complexes -- 1.2 Target Scope of Kinetically Controlled Stepwise Synthesis -- 1.3 Overview of This Study -- References -- 2 Heterometallic CoIINi3II Complex -- 2.1 Introduction -- 2.2 Step 1: Complexation with a Redox-Active Metal -- 2.3 Step 2: Site-Selective Oxidation -- 2.4 Step 3: Site-Selective Transmetalation -- 2.5 Step 4: Reduction -- 2.6 Comparison with Other Strategies -- 2.7 Conclusions -- 2.8 Experimental Section -- 2.8.1 Materials and Methods -- 2.8.2 Synthesis of Compounds -- 2.8.3 Miscellaneous Experiments -- 2.8.4 Single-Crystal XRD Analyses -- References -- 3 Tetrahedral Chiral-at-Metal ZnII Complex -- 3.1 Introduction -- 3.2 Molecular Design -- 3.3 Strategy for Enantioselective Synthesis -- 3.4 Step 1: Racemic Complexation -- 3.5 Step 2: Asymmetric Induction with a Chiral Ligand -- 3.6 Step 3: Replacement of the Chiral Ligand -- 3.7 Configurational Stability -- 3.8 Enantioselective Catalysis -- 3.9 Conclusions -- 3.10 Experimental Section -- 3.10.1 Materials and Methods -- 3.10.2 Synthesis of the Ligand -- 3.10.3 Syntheses of the Metal Complexes -- 3.10.4 Single-Crystal X-Ray Diffraction Analyses -- 3.10.5 Miscellaneous Experiments -- References -- 4 Conclusions -- 4.1 Conclusions -- Curriculum Vitae -- Education -- Appointment -- Research Interest -- Major Awards -- Fellowship. 410 0$aSpringer theses. 606 $aMetal complexes 615 0$aMetal complexes. 676 $a541.2242 700 $aEndo?$b Ken'ichi$f1961-$01228304 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910483028303321 996 $aKinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex$92851588 997 $aUNINA LEADER 03508nam 2200709 450 001 9910160769103321 005 20190331122325.0 010 $a1-78536-449-9 035 $a(CKB)3710000000602088 035 $a(EBL)4443179 035 $a(SSID)ssj0001690695 035 $a(PQKBManifestationID)16540050 035 $a(PQKBTitleCode)TC0001690695 035 $a(PQKBWorkID)15064532 035 $a(PQKB)25079666 035 $a(DLC)9781785364495 035 $a(MiAaPQ)EBC4443179 035 $a(DLC)eep9781785364495 035 $a(oapen)https://directory.doabooks.org/handle/20.500.12854/50282 035 $a(EXLCZ)993710000000602088 100 $a20150825h20162016 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aInnovation networks and the new Asian regionalism $ea knowledge platform on economic productivity /$fHans-Peter Brunner, Asian Development Bank, the Philippines 210 1$aNorthampton, Mass. :$cEdward Elgar Pub.,$d2016. 215 $a1 online resource (204 p.) 300 $a"Co-publication of the Asian Development Bank and Edward Elgar Publishing"--Cover. 311 $a1-78536-448-0 320 $aIncludes bibliographical references and index. 327 $aFront matter; Copyright page; Contents; Figures; Tables and boxes; Acknowledgments; Abbreviations; Introduction; 1. The impact of regional cooperation and integration drivers on economic productivity and welfare; 2. The view from the Baltic Sea Region; 3. The view from the Greater Mekong Subregion; 4. Roadmap to innovation and skill-based cluster ecology development initiatives; Appendix 1 Detailed description of computable general equilibrium model exercises and data matrices; Appendix 2 Mapping of Baltic Sea Region tools 327 $aAppendix 3 Usage case for the design of an Asian Regional Economic Integration ObservatoryAppendix 4 Details and data related to Asian Regional Integration Observatory ; References; Index 330 $aThe rise of Asia, as well as the future of regional cooperation and integration (RCI) the world over, will be profoundly influenced by the challenges of slowing productivity growth, increasing economic inequalities and systemic vulnerabilities. Such structural reform issues will require RCI policies that complement domestic policy reform. This unique book explains what drives the regional economic integration of nations and their contribution to national knowledge capital. It also lays out how such beneficial integration can generate broad-based, equitable wealth in Europe and Asia. 606 $aEconomic development$zAsia 606 $aRegionalism$zAsia 607 $aAsia$xEconomic integration 607 $aAsia$xEconomic conditions 607 $aAsia$2fast 607 $aAsien$2gnd 610 $aEconomics 610 $aDevelopment Studies 610 $aRegional Economics 610 $aAsian Geography 610 $aAsian Economics 610 $aDevelopment Economics 610 $aEconomic Geography 610 $aAsian Innovation 610 $aAsian Development 615 0$aEconomic development 615 0$aRegionalism 676 $a337.1/5 700 $aBrunner$b Hans-Peter$0231429 712 02$aEdward Elgar Publishing. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910160769103321 996 $aInnovation networks and the new Asian regionalism$92105574 997 $aUNINA