LEADER 06192nam 22007215 450 001 9910155325603321 005 20200706010755.0 010 $a9783319464015 024 7 $a10.1007/978-3-319-46401-5 035 $a(CKB)3710000000964800 035 $a(DE-He213)978-3-319-46401-5 035 $a(MiAaPQ)EBC4749238 035 $a(PPN)197141110 035 $a(EXLCZ)993710000000964800 100 $a20161128d2017 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 14$aThe Notion of Activity in Chemistry /$fby Jean-Louis Burgot 205 $a1st ed. 2017. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2017. 215 $a1 online resource (XLI, 608 p. 51 illus.) 311 $a3-319-46399-3 311 $a3-319-46401-9 320 $aIncludes bibliographical references. 327 $a1st part: The Activity in Classical Thermodynamics -- Thermodynamic systems -- Gibbs and Helmhotz energies -- Escaping tendency and molar Gibbs energy -- Partial molar properties -- Chemical potential or partial molar Gibbs energy -- An overview of the notion of activity -- The concept of fugacity -- Ideal solutions -- Definitions of the activity -- Activity of a gaz -- Activities of non- electrolytes in solutions -- Activities of electrolytes: definitions -- Determination of the activity of non-electrolytes -- Determination of the activity of electrolytes -- Debye and Hückel ?s relations -- Excess Gibbs energies and activities -- Chemical equilibrium constants : activities and Gibbs energies of reactions -- Derivation of thermodynamic equilibrium constants- pH and its measure -- General principles of calculations of ionic species concentrations in solutions involving activities -- 2nd part: The Activity in Statistical Thermodynamics -- Statistical thermodynamics in brief -- Concept of ensembles and postulates -- The canonical ensemble: notion of distribution -- Thermodynamic quantities in the framework of the canonical ensemble -- Other ensembles -- Systems of molecules and subsystems independent distinguishable and ?indistinguishable? -- Perfect gases -- Classical statistical mechanics- Notion of configuration ? Classical canonical partition function -- The configurational partition function ? Molecular distribution functions -- The radial distribution function -- Radial distribution function and thermodynamic quantities- calculations of the internal energy and of the pressure of a system -- Radial distribution function and calculation of the isothermal compressibility coefficient of a system -- The chemical potential and the radial distribution function: General formal introduction of the activity and of the activity coefficient -- Imperfect gases ? The virial coefficients in terms of interaction potential energies -- A statistical expression of the activity: A relation between it and the concentration in the case of an imperfect gaz -- Activities of gases in a mixture of imperfect gases -- Chemical equilibria between gases and statistical thermodynamics -- Activity coefficients of gases -- Activities and concentrations of non-electrolytes in dilute liquid solutions ? McMillan- Mayer?s theory of their osmotic pressure -- A study of dilute solutions of non-electrolytes at constant pressure and temperature -- The activity coefficients of solutes in binary non-electrolyte solutions -- Molecular distribution functions in binary mixtures -- The Kirkwood-Buff?s theory- Changes of chemical potentials of solutes with their concentrations at constant pressure and temperature -- Expressions of the chemical potentials of the components of ideal solutions of non-electrolytes. 330 $aThis book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment has been streamlined by placing some background material in appendices. Chemical Activity is of interest not only to those in chemical thermodynamics, but also to chemical engineers working with mass transfer and its applications - for example, separation methods. 606 $aChemistry, Physical and theoretical 606 $aThermodynamics 606 $aHeat engineering 606 $aHeat$xTransmission 606 $aMass transfer 606 $aChemical engineering 606 $aAnalytical chemistry 606 $aChemistry, Physical and theoretical 606 $aTheoretical and Computational Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C25007 606 $aEngineering Thermodynamics, Heat and Mass Transfer$3https://scigraph.springernature.com/ontologies/product-market-codes/T14000 606 $aThermodynamics$3https://scigraph.springernature.com/ontologies/product-market-codes/P21050 606 $aIndustrial Chemistry/Chemical Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/C27000 606 $aAnalytical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C11006 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 615 0$aChemistry, Physical and theoretical. 615 0$aThermodynamics. 615 0$aHeat engineering. 615 0$aHeat$xTransmission. 615 0$aMass transfer. 615 0$aChemical engineering. 615 0$aAnalytical chemistry. 615 0$aChemistry, Physical and theoretical. 615 14$aTheoretical and Computational Chemistry. 615 24$aEngineering Thermodynamics, Heat and Mass Transfer. 615 24$aThermodynamics. 615 24$aIndustrial Chemistry/Chemical Engineering. 615 24$aAnalytical Chemistry. 615 24$aPhysical Chemistry. 676 $a541.2 700 $aBurgot$b Jean-Louis$4aut$4http://id.loc.gov/vocabulary/relators/aut$0767666 906 $aBOOK 912 $a9910155325603321 996 $aNotion of Activity in Chemistry$91563144 997 $aUNINA