LEADER 04136nam 22005895 450 001 9910155302703321 005 20200702222039.0 010 $a9783319483504 024 7 $a10.1007/978-3-319-48350-4 035 $a(CKB)3710000000964730 035 $a(DE-He213)978-3-319-48350-4 035 $a(MiAaPQ)EBC4748999 035 $a(PPN)197138616 035 $a(EXLCZ)993710000000964730 100 $a20161126d2017 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aVisible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks /$fby Basudev Sahoo 205 $a1st ed. 2017. 210 1$aCham :$cSpringer International Publishing :$cImprint: Springer,$d2017. 215 $a1 online resource (XXIII, 258 p. 113 illus., 37 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a3-319-48349-8 311 $a3-319-48350-1 320 $aIncludes bibliographical references at the end of each chapters. 327 $aAbstract -- Introduction to Photocatalysis -- Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-Activated Alkenes -- Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement -- Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines -- Synthesis and Characterizations of Novel Metal-Organic Frameworks (MOFs) -- Experimental Section. 330 $aThis unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aChemistry, Organic 606 $aCatalysis 606 $aChemical engineering 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 606 $aIndustrial Chemistry/Chemical Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/C27000 615 0$aChemistry, Organic. 615 0$aCatalysis. 615 0$aChemical engineering. 615 14$aOrganic Chemistry. 615 24$aCatalysis. 615 24$aIndustrial Chemistry/Chemical Engineering. 676 $a541.395 700 $aSahoo$b Basudev$4aut$4http://id.loc.gov/vocabulary/relators/aut$0767520 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910155302703321 996 $aVisible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks$91562570 997 $aUNINA