LEADER 05237nam 2200685Ia 450 001 9910146399403321 005 20170809164105.0 010 $a1-282-13738-7 010 $a9786612137389 010 $a0-470-45183-1 010 $a0-470-45182-3 035 $a(CKB)1000000000748564 035 $a(EBL)433790 035 $a(OCoLC)609835788 035 $a(SSID)ssj0000354766 035 $a(PQKBManifestationID)11233483 035 $a(PQKBTitleCode)TC0000354766 035 $a(PQKBWorkID)10316211 035 $a(PQKB)11770862 035 $a(MiAaPQ)EBC433790 035 $a(PPN)140100040 035 $a(EXLCZ)991000000000748564 100 $a20081126d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSolid state polymerization$b[electronic resource] /$fConstantine D. Papaspyrides, Stamatina N. Vouyiouka 210 $aHoboken, NJ $cWiley$dc2009 215 $a1 online resource (314 p.) 300 $aIncludes index. 311 $a0-470-08418-9 327 $aSOLID STATE POLYMERIZATION; CONTENTS; Contributors; Preface; 1 Fundamentals of Solid State Polymerization; 1.1 Introduction; 1.1.1 Polymers and Plastics; 1.1.2 Polymerization Processes; 1.1.3 Introduction to Solid State Polymerization; 1.2 Solid State Polymerization of Chain-Growth Polymers (Solid State Polyaddition); 1.3 Solid State Polymerization of Step-Growth Polymers (Solid State Polycondensation); 1.3.1 Monomer Solid State Polymerization (Direct SSP); 1.3.2 Prepolymer Solid State Polymerization (Post-SSP, Solid State Finishing); 1.4 Solid State Polymerization Apparatus and Assemblies 327 $a1.5 Solid State Applications in the Polymer Industry1.5.1 Solid State Polymerization Advantages; 1.5.2 Post-Solid State Polymerization Application in Polyamides; 1.6 Conclusions; 2 Solid State Polymerization Chemistry and Mechanisms: Unequal Reactivity of End Groups; 2.1 Introduction; 2.2 Special Characteristics of Solid State Polymerization; 2.3 Classical Kinetic Equations in Solid State Polymerization; 2.4 Model of Molecular Morphology and Chain-End Movement; 2.4.1 Definition of Chain-End Length in the Amorphous Phase; 2.4.2 How End Groups Move During Solid State Polymerization 327 $a2.4.3 How Chain-End Length Affects the Movement of End Groups2.5 Reactivity of End Groups; 2.5.1 Principles of Equal Reactivity of End Groups in Melt Polymerization; 2.5.2 Principles of Unequal Reactivity of End Groups in Solid State Polymerization; 2.5.3 Sources of Low Reactivity of End Groups; 2.6 Why Intrinsic Viscosity Levels Off During Solid State Polymerization; 2.6.1 Definition of Residual Average Radius and Residual End-Group Concentration; 2.6.2 Relationship Between (r) and; 2.6.3 Relationship Between C(r), (r), and Ultimate IV 327 $a2.6.4 Explanation of Temperature Effect on Solid State Polymerization2.6.5 Explanation of Initial IV Effect on Solid State Polymerization; 2.7 Solid State Polymerization Kinetics; 2.7.1 Kinetic Equation of Ideal Solid State Polymerization; 2.7.2 Empirical Kinetic Equation of Real Solid State Polymerization; 2.8 Conclusions; 3 Kinetic Aspects of Polyester Solid State Polymerization; 3.1 Introduction; 3.2 Phenomena Involved in Solid State Polymerization of Polyesters; 3.2.1 Possible Reactions in Solid State Polymerization of Polyesters 327 $a3.2.2 Chain Mobility and Diffusion of Low-Molecular-Weight By-Products3.2.3 Kinetic and Diffusion Equations; 3.3 Modeling Solid State Polymerization of Polyesters; 3.3.1 Effects of Variables and Predictions Based on Kinetic Models; 3.4 Solid State Polymerization of Typical Polyesters; 3.4.1 Poly(ethylene terephthalate); 3.4.2 Poly(butylene terephthalate); 3.4.3 Poly(ethylene naphthalate); 3.4.4 Poly(trimethylene terephthalate); 3.4.5 Poly(L-lactic acid); 3.5 Conclusions; 4 Kinetic Aspects of Polyamide Solid State Polymerization; 4.1 Introduction 327 $a4.2 Simple Kinetic Models of Solid State Polyamidation 330 $aThe most current guide to solid state polymerization Solid State Polymerization (SSP)is an indispensable tool in the design, manufacture, and study of polymers, plastics, and fibers. SSP presents significant advantages over other polymerization techniques due to low operating temperatures, inexpensive equipment, and simple and environmentally sound procedures. Combining fundamentals of polymer science, chemistry, physical chemistry, and engineering, SSP also offers many research applications for a wide range of students and investigators. Gathering and filtering the latest literature on SS 606 $aPolymerization 606 $aSolid state chemistry 615 0$aPolymerization. 615 0$aSolid state chemistry. 676 $a660 676 $a668.9/2 676 $a668.92 686 $aUV 2100$2rvk 686 $aVE 8000$2rvk 686 $aVK 8000$2rvk 686 $aVN 5900$2rvk 700 $aPapaspyrides$b Constantine D$0953851 701 $aVouyiouka$b Stamatina N$0953852 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146399403321 996 $aSolid state polymerization$92156802 997 $aUNINA