LEADER 05399nam 2200649Ia 450 001 9910146268803321 005 20170921223142.0 010 $a1-282-13984-3 010 $a9786612139840 010 $a3-527-61681-0 010 $a3-527-61691-8 035 $a(CKB)1000000000441539 035 $a(EBL)481403 035 $a(OCoLC)814510954 035 $a(SSID)ssj0000138936 035 $a(PQKBManifestationID)11139564 035 $a(PQKBTitleCode)TC0000138936 035 $a(PQKBWorkID)10101709 035 $a(PQKB)10904436 035 $a(MiAaPQ)EBC481403 035 $a(EXLCZ)991000000000441539 100 $a20051214d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aDiffraction and spectroscopic methods in electrochemistry$b[electronic resource] /$fedited by Richard C. Alkire ... [et al.] 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley, distributor]$dc2006 215 $a1 online resource (447 p.) 225 1 $aAdvances in electrochemical science and engineering ;$vv. 9 300 $aDescription based upon print version of record. 311 $a3-527-31317-6 320 $aIncludes bibliographical references and index. 327 $aAdvances in Electrochemical Science and Engineering Volume 9 Diffraction and Spectroscopic Methods in Electrochemistry; Series Preface; Contents; Volume Preface; List of Contributors; 1 In-situ X-ray Diffraction Studies of the Electrode/Solution Interface; 1.1 Introduction; 1.2 Experimental; 1.3 Adsorbate-induced Restructuring of Metal Substrates; 1.3.1 Surface Relaxation; 1.3.1.1 Pt Monometallic and Bimetallic Surfaces; 1.3.1.2 Group IB Metals; 1.3.2 Surface Reconstruction; 1.4 Adlayer Structures; 1.4.1 Anion Structures; 1.4.2 CO Ordering on the Pt(111) Surface 327 $a1.4.3 Underpotential Deposition (UPD)1.5 Reactive Metals and Oxides; 1.6 Conclusions and Future Directions; Acknowledgments; References; 2 UV-visible Reflectance Spectroscopy of Thin Organic Films at Electrode Surfaces; 2.1 Introduction; 2.2 The Basis of UV-visible Reflection Measurement at an Electrode Surface; 2.3 Absolute Reflection Spectrum versus Modulated Reflection Spectrum; 2.4 Wavelength-modulated UV-visible Reflectance Spectroscopy; 2.5 Potential-modulated UV-visible Reflectance Spectroscopy; 2.6 Instrumentation of the Potential-modulated UV-visible Reflection Measurement 327 $a2.7 ER Measurements for Redox-active Thin Organic Films2.8 Interpretation of the Reflection Spectrum; 2.9 Reflection Measurement at Special Electrode Configurations; 2.10 Estimation of the Molecular Orientation on the Electrode Surface; 2.10.1 Estimation of the Molecular Orientation on the Electrode Surface using the Redox ER Signal; 2.10.2 Estimation of the Molecular Orientation on the Electrode Surface using the Stark Effect ER Signal; 2.11 Measurement of Electron Transfer Rate using ER Measurement; 2.11.1 Redox ER Signal in Frequency Domain 327 $a2.11.2 Examples of Electron Transfer Rate Measurement using ER Signal2.11.3 Improvement in Data Analysis; 2.11.4 Combined Analysis of Impedance and Modulation Spectroscopic Signals; 2.11.5 Upper Limit of Measurable Rate Constant; 2.11.6 Rate Constant Measurement using an ER Voltammogram; 2.12 ER Signal Originated from Non-Faradaic Processes - a Quick Overview; 2.13 ER Signal with Harmonics Higher than the Fundamental Modulation Frequency; 2.14 Distinguishing between Two Simultaneously Occurring Electrode Processes 327 $a2.15 Some Recent Examples of the Application of ER Measurement for a Functional Electrode2.16 Scope for Future Development of UV-visible Reflection Measurements; 2.16.1 New Techniques in UV-visible Reflection Measurements; 2.16.2 Remarks on the Scope for Future Development of UV-visible Reflection Measurements; Acknowledgments; References; 3 Epi-fluorescence Microscopy Studies of Potential Controlled Changes in Adsorbed Thin Organic Films at Electrode Surfaces; 3.1 Introduction; 3.2 Fluorescence Microscopy and Fluorescence Probes; 3.3 Fluorescence near Metal Surfaces 327 $a3.4 Description of a Fluorescence Microscope for Electrochemical Studies 330 $aThis ninth volume in the series concentrates on in situ spectroscopic methods and combines a balanced mixture of theory and applications, making it highly readable for chemists and physicists, as well as for materials scientists and engineers. As with the previous volumes, all the chapters continue the high standards of this series, containing numerous references to further reading and the original literature, for easy access to this new field. The editors have succeeded in selecting highly topical areas of research and in presenting authors who are leaders in their fields, covering such diver 410 0$aAdvances in electrochemical science and engineering ;$vv. 9. 606 $aChemical engineering 606 $aElectrochemistry 608 $aElectronic books. 615 0$aChemical engineering. 615 0$aElectrochemistry. 676 $a541.3/7 676 $a660.297 701 $aAlkire$b R. C.$f1941-$0884240 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146268803321 996 $aDiffraction and spectroscopic methods in electrochemistry$92205962 997 $aUNINA