LEADER 04561nam 2200613 450 001 9910146268103321 005 20180612234033.0 010 $a1-282-78442-0 010 $a9786612784422 010 $a3-527-62178-4 010 $a3-527-62179-2 035 $a(CKB)1000000000441546 035 $a(EBL)482346 035 $a(OCoLC)609855595 035 $a(SSID)ssj0000354797 035 $a(PQKBManifestationID)11249101 035 $a(PQKBTitleCode)TC0000354797 035 $a(PQKBWorkID)10313405 035 $a(PQKB)11185212 035 $a(MiAaPQ)EBC482346 035 $a(PPN)150635621 035 $a(EXLCZ)991000000000441546 100 $a20160819h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSupramolecular catalysis /$fedited by Piet W. N. M. van Leeuwen 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (321 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32191-8 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aSupramolecular Catalysis; Contents; List of Authors; 1 Introduction to Supramolecular Catalysis; 1.1 Introduction; 1.2 Design Approaches to Supramolecular Catalysis; 1.2.1 Molecular Receptors that Place a Binding Site Close to a Catalytic Center; 1.2.2 Molecular Receptors that Promote the Reaction of two Simultaneously Complexed Reactants; 1.2.3 Preparation of the Catalyst Backbone via Supramolecular Interactions; 1.3 Artificial Biomacromolecules for Asymmetric Catalysis; 1.4 Summary and Outlook; References 327 $a2 Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis2.1 Introduction; 2.2 Emulation of Chelation through Self-Assembly of Monodentate Ligands; 2.3 Tautomeric Self-Complementary Interligand Hydrogen Bonding; 2.3.1 Hydroformylation; 2.3.2 Room Temperature/Ambient Pressure Hydroformylation; 2.3.3 Asymmetric Hydrogenation; 2.4 A-T Base Pair Analogous Complementary Hydrogen Bonding for the Construction of Heterodimeric Self-Assembling Ligands; 2.4.1 Aminopyridine/Isoquinolone Platform 327 $a3.3.2 X-Ray and other Techniques for Structural Characterization in the Solid State3.3.3 Structural Characterization in Solution by NMR; 3.3.4 Anion Exchange in the Solid State; 3.4 Preparation of Coordination Polymers with 2,3-Pyrazolylquinoxalines or 2,3-Pyrazolylpyrazines and Cu(I) or Ag(I); 3.4.1 Preparation and Characterization of Dinuclear Building Blocks and Coordination Polymers; 3.4.2 X-Ray and other Techniques for Structural Characterization; 3.5 Preparation of Supramolecular Structures with 2,4-Diamino-6-R-1,3,5-triazines and Ag(I); 3.5.1 Synthesis 327 $a3.5.2 X-Ray Structure Determination3.5.3 Structural Characterization in Solution by NMR; 3.6 Conclusions; References; 4 Chiral Metallocycles for Asymmetric Catalysis; 4.1 Introduction; 4.2 Thermodynamically-Controlled Metallocycles; 4.3 Kinetically-Controlled Metallocycles; 4.4 General Synthetic Strategies for Chiral Metallocycles; 4.5 Self- and Directed-Assembly of Chiral Pt-Alkynyl Metallocycles; 4.6 Chiral Pt-Alkynyl Metallocycles for Asymmetric Catalysis; 4.7 Concluding Remarks; References; 5 Catalysis of Acyl Transfer Processes by Crown-Ether Supported Alkaline-Earth Metal Ions 327 $a5.1 Introduction 330 $aIn the past few years, supramolecular chemistry has led to new approaches in homogeneous catalysis. While host-guest chemistry had already found applications in catalysis as a result of the pioneering work carried out by Professor Ronald Breslow and Nobel prizewinner Professor Jean-Marie Lehn that began some 40 years ago, the construction of catalysts by supramolecular forces has only recently become a powerful tool. This development paves the way for large numbers of new potential catalysts that can be varied in an expedient way by changing the constituting building blocks.Written by some 606 $aCatalysis 606 $aSupramolecular chemistry 615 0$aCatalysis. 615 0$aSupramolecular chemistry. 676 $a541.395 702 $aLeeuwen$b P. W. N. M. van$g(Piet W. N. M.), 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146268103321 996 $aSupramolecular Catalysis$92819151 997 $aUNINA