LEADER 05318nam 2200649Ia 450 001 9910146242203321 005 20170814190147.0 010 $a1-280-52028-0 010 $a9786610520282 010 $a3-527-60519-3 010 $a3-527-60237-2 035 $a(CKB)1000000000019324 035 $a(EBL)481773 035 $a(OCoLC)68941223 035 $a(SSID)ssj0000159701 035 $a(PQKBManifestationID)11137633 035 $a(PQKBTitleCode)TC0000159701 035 $a(PQKBWorkID)10158411 035 $a(PQKB)11018238 035 $a(MiAaPQ)EBC481773 035 $a(EXLCZ)991000000000019324 100 $a20040308d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aFunctional hybrid materials$b[electronic resource] /$fedited by Pedro G?omez-Romero, Cl?ement Sanchez 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley] [distributor]$dc2004 215 $a1 online resource (437 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30484-3 320 $aIncludes bibliographical references and index. 327 $aFunctional Hybrid Materials; Table of Contents; Preface; List of Contributors; 1 Hybrid Materials, Functional Applications. An Introduction; 1.1 From Ancient Tradition to 21st Century Materials; 1.2 Hybrid Materials. Types and Classifications; 1.3 General Strategies for the Design of Functional Hybrids; 1.4 The Road Ahead; 2 Organic-Inorganic Materials: From Intercalation Chemistry to Devices; 2.1 Introduction; 2.2 Types of Hybrid Organic-Inorganic Materials; 2.2.1 Intercalation Compounds; 2.2.1.1 Intercalation of Ionic Species; 2.2.1.2 Intercalation of Neutral Species 327 $a2.2.1.3 Polymer Intercalations: Nanocomposites2.2.2 Organic Derivatives of Inorganic Solids; 2.2.3 Sol-Gel Hybrid Materials; 2.3 Functions & Devices Based on Organic-Inorganic Solids; 2.3.1 Selective Sorbents, Complexing Agents & Membranes; 2.3.2 Heterogeneous Catalysts & Supported Reagents; 2.3.3 Photoactive, Optical and Opto-Electronic Materials & Devices; 2.3.4 Electrical Behaviors: Ionic & Electronic Conductors; 2.3.5 Electroactivity & Electrochemical Devices; 2.4 Conclusions; 3 Bridged Polysilsesquioxanes. Molecular-Engineering Nanostructured Hybrid Organic-Inorganic Materials 327 $a3.1 Introduction3.2 Historical Background; 3.3 Monomer Synthesis; 3.3.1 Metallation; 3.3.2 Hydrosilylation; 3.3.3 Functionalization of an Organotrialkoxysilane; 3.3.4 Other Approaches; 3.4 Sol-Gel Processing of Bridged Polysilsesquioxanes; 3.4.1 Hydrolysis and Condensation; 3.4.2 Gelation; 3.4.3 Aging and Drying; 3.5 Characterization of Bridged Polysilsesquioxanes; 3.5.1 Porosity in Bridged Polysilsesquioxanes; 3.5.2 Pore Size Control; 3.5.3 Pore Templating; 3.6 Influence of Bridging Group on Nanostructures; 3.6.1 Surfactant Templated Mesoporous Materials; 3.6.2 Mesogenic Bridging Groups 327 $a3.6.3 Supramolecular Organization3.6.4 Metal Templating; 3.7 Thermal Stability and Mechanical Properties; 3.8 Chemical Properties; 3.9 Applications; 3.9.1 Optics and Electronics; 3.9.1.1 Dyes; 3.9.1.2 Nano- and Quantum Dots in Bridged Polysilsesquioxanes; 3.9.2 Separations Media; 3.9.3 Catalyst Supports and Catalysts; 3.9.4 Metal and Organic Adsorbents; 3.10 Summary; 4 Porous Inorganic-Organic Hybrid Materials; 4.1 Introduction; 4.2 Inorganic-Network Formation; 4.3 Preparation and Properties; 4.3.1 Aerogels; 4.3.2 M41S materials 327 $a4.4 Methods for Introducing Organic Groups into Inorganic Materials4.5 Porous Inorganic-Organic Hybrid Materials; 4.5.1 Functionalization of Porous Inorganic Materials by Organic Groups; 4.5.1.1 Post-synthesis Modification; 4.5.1.2 Liquid-Phase Modification in the Wet Gel Stage or Prior to Surfactant Removal; 4.5.1.3 Addition of Non-Reactive Compounds to the Precursor Solution; 4.5.1.4 Use of Organically Substituted Co-precursors; 4.5.2 Bridged Silsequioxanes; 4.5.3 Incorporation of Metal Complexes for Catalysis; 4.5.4 Incorporation of Biomolecules; 4.5.5 Incorporation of Polymers 327 $a4.5.6 Creation of Carbon Structures 330 $aFunctional Hybrid Materials consist of both organic and inorganic components, assembled for the purpose of generating desirable properties and functionalities. The aim is twofold: to bring out or enhance advantageous chemical, electrochemical, magnetic or electronic characteristics and at the same time to reduce or wholly suppress undesirable properties or effects. Another target is the creation of entirely new material behavior.The vast number of hybrid material components available has opened up a wide and diversified field of fascinating research. In this book, a team of highly renowned 606 $aComposite materials 606 $aNanostructured materials 608 $aElectronic books. 615 0$aComposite materials. 615 0$aNanostructured materials. 676 $a620.1/18 676 $a620.118 676 $a620.19 701 $aGo?mez-Romero$b Pedro$0975554 701 $aSanchez$b Cle?ment$0802325 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146242203321 996 $aFunctional hybrid materials$92221372 997 $aUNINA