LEADER 05329nam 2200649 450 001 9910146238003321 005 20170809173151.0 010 $a1-280-56087-8 010 $a9786610560875 010 $a3-527-61437-0 010 $a3-527-60244-5 035 $a(CKB)1000000000019366 035 $a(EBL)481731 035 $a(OCoLC)310353439 035 $a(SSID)ssj0000204826 035 $a(PQKBManifestationID)11199490 035 $a(PQKBTitleCode)TC0000204826 035 $a(PQKBWorkID)10189362 035 $a(PQKB)10560183 035 $a(MiAaPQ)EBC481731 035 $a(EXLCZ)991000000000019366 100 $a20160816h20042004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMolecular clusters of the main group elements /$fMatthias Driess, Heinrich No?th, (eds.) 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2004. 210 4$dİ2004 215 $a1 online resource (462 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30654-4 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aMolecular Clusters of the Main Group Elements; Contents; Preface; List of Contributors; 1 Theory and Concepts in Main-Group Cluster Chemistry; 1.1 Introduction; 1.1.1 Three-center Bonding in Boranes: Lipscomb's Equations of Balance; 1.1.2 Polyhedral Skeletal Electron Pair Theory: The Wade-Mingos Rules; 1.1.3 Aromaticity in Three-dimensional Clusters; 1.1.3.1 From Polygonal Aromatics to Deltahedral Boranes; 1.1.3.2 Interstitial Polygonal Aromatic-Deltahedral Borane Relationships; 1.1.3.3 Aromaticity Evaluations of Three-dimensional Structures: Nucleus-Independent Chemical Shift (NICS) 327 $a1.1.3.4 Spherical Aromaticity1.1.4 Bare Ionic Post-transition Metal Clusters: The Zintl Phases; 1.1.5 Clusters of the Heavier Group 13 Metals; 1.1.5.1 Apparently Hypoelectronic Deltahedra in Bare Clusters of Indium and Thallium: Polyhedra with Flattened Vertices; 1.1.5.2 Organometallic Deltahedral Clusters of the Heavier Group 13 Metals and More Complicated Structures Derived from Deltahedra; 1.1.5.3 Giant Aluminum Clusters with Shell Structures Consisting of Nested Polyhedra: Pieces of Icosahedral Quasicrystals; 1.1.6 Conclusion and Outlook; References; 2.1 Homonuclear Boron Clusters 327 $a2.1.1 Introduction2.1.2 General Principles and Systematic Naming; 2.1.2.1 Structures and Bonding; 2.1.3 Synthetic Methods; 2.1.3.1 Diborane Pyrolysis; 2.1.3.2 The Anionic Route; 2.1.3.3 Platinum-catalyzed Dehydrocoupling; 2.1.3.4 Cluster Expansion and Cluster Contraction Reactions; 2.1.4 Chemistry of Selected Polyboranes; 2.1.4.1 Chemistry of Triborane B(3)H(7); 2.1.4.2 Chemistry of Tetraboranes; 2.1.4.2.1 arachno-Tetraborane(10); 2.1.4.2.2 Derivatives of nido-Tetraborane(8), B(4)H(8), and closo-Tetraborane(6), B(4)H(6); 2.1.4.3 Chemistry of Pentaborane(9); 2.1.4.4 Chemistry of Decaborane(14) 327 $a2.1.5 Chemistry of Selected nido- and closo-Polyborane Anions2.1.5.1 Chemistry of closo-B(6)H(6)(2-); 2.1.5.2 Chemistry of the Nonahydro-closo-nonaborate(2-); 2.1.5.3 Reaction of Decahydro-closo-decaborate(2-); 2.1.5.4 Chemistry of the nido-Decaborate B(10)H(13)(-); 2.1.5.5 Chemistry of Undecahydro-closo-undecaborate B(11)H(11)(2-); 2.1.5.6 Chemistry of the Dodecahydro-closo-dodecaborate; 2.1.5.6.1 Protonation and Alkylation of B(12)H(12)(2-); 2.1.5.6.2 Halogeno-, Hydroxo-, Alkoxo- and Amine closo-dodecaborates; 2.1.5.7 Chemistry of B(20)H(18)(2-) Anions 327 $a2.1.6 Substituted Neutral Polyboranes of Type B(y)X(y)2.1.6.1 Overview; 2.1.6.2 Structures; 2.1.6.3 Synthesis; 2.1.6.4 Reactions; References; 2.2 Boron Clusters in Medical Applications; 2.2.1 Introduction; 2.2.2 Dicarba-closo-dodecaborane, C(2)B(10)H(12), and Derivatives; 2.2.2.1 Preparation and Reactions of C(2)B(10) Cage Compounds; 2.2.2.2 Design and Classification of BNCT Reagents Containing C(2)B(10) Cages; 2.2.2.3 Amino Acids; 2.2.2.4 Nucleic Acid Precursors; 2.2.2.5 DNA Binders; 2.2.2.6 Porphyrins; 2.2.2.7 Combination of C(2)B(10) and Gadolinium-containing Species 327 $a2.2.3 Derivatives of the nido-carborane C(2)B(9)H(12)(2-) 330 $aWith more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including:the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters* and numerous other compound classes. The whole is illustrated by examples of the great potential for technical appli 606 $aMicroclusters 606 $aChemical elements 608 $aElectronic books. 615 0$aMicroclusters. 615 0$aChemical elements. 676 $a539.6 676 $a541 702 $aDriess$b Matthias$f1961- 702 $aNo?th$b Heinrich$f928- 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146238003321 996 $aMolecular clusters of the main group elements$92221369 997 $aUNINA