LEADER 05251nam 2200637 a 450 001 9910146075903321 005 20170815122605.0 010 $a1-280-54192-X 010 $a9786610541928 010 $a0-471-62356-3 010 $a0-471-62357-1 035 $a(CKB)1000000000018987 035 $a(EBL)176025 035 $a(OCoLC)56712919 035 $a(SSID)ssj0000306004 035 $a(PQKBManifestationID)11195606 035 $a(PQKBTitleCode)TC0000306004 035 $a(PQKBWorkID)10294499 035 $a(PQKB)10273277 035 $a(MiAaPQ)EBC176025 035 $a(EXLCZ)991000000000018987 100 $a20031022d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aPhysical chemistry of macromolecules$b[electronic resource] $ebasic principles and issues /$fS.F. Sun 205 $a2nd ed. 210 $aHoboken, N.J. $cJohn Wiley & Sons$dc2004 215 $a1 online resource (583 p.) 300 $a"A Wiley-Interscience publication." 311 $a0-471-28138-7 320 $aIncludes bibliographical references and indexes. 327 $aPHYSICAL CHEMISTRY OF MACROMOLECULES Second Edition; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1 Introduction; 1.1 Colloids; 1.2 Macromolecules; 1.2.1 Synthetic Polymers; 1.2.2 Biological Polymers; 1.3 Macromolecular Science; References; 2 Syntheses of Macromolecular Compounds; 2.1 Radical Polymerization; 2.1.1 Complications; 2.1.2 Methods of Free-Radical Polymerization; 2.1.3 Some Well-Known Overall Reactions of Addition Polymers; 2.2 Ionic Polymerization; 2.2.1 Anionic Polymerization; 2.2.2 Cationic Polymerization; 2.2.3 Living Polymers 327 $a2.3 Coordination Polymerization2.4 Stepwise Polymerization; 2.5 Kinetics of the Syntheses of Polymers; 2.5.1 Condensation Reactions; 2.5.2 Chain Reactions; 2.6 Polypeptide Synthesis; 2.6.1 Synthesis of Insulin; 2.6.2 Synthesis of Ribonucleus; 2.7 DNA Synthesis; References; Problems; 3 Distribution of Molecular Weight; 3.1 Review of Mathematical Statistics; 3.1.1 Binomial Distribution; 3.1.2 Poisson Distribution; 3.1.3 Gaussian Distribution; 3.2 One-Parameter Equation; 3.2.1 Condensation Polymers; 3.2.2 Addition Polymers; 3.3 Two-Parameter Equations; 3.3.1 Normal Distribution 327 $a3.3.2 Logarithm Normal Distribution3.4 Types of Molecular Weight; 3.5 Experimental Methods for Determining Molecular Weight and Molecular Weight Distribution; References; Problems; 4 Macromolecular Thermodynamics; 4.1 Review of Thermodynamics; 4.2 DS of Mixing: Flory Theory; 4.3 DH of Mixing; 4.3.1 Cohesive Energy Density; 4.3.2 Contact Energy (First-Neighbor Interaction or Energy Due to Contact); 4.4 DG of Mixing; 4.5 Partial Molar Quantities; 4.5.1 Partial Specific Volume; 4.5.2 Chemical Potential; 4.6 Thermodynamics of Dilute Polymer Solutions; 4.6.1 Vapor Pressure; 4.6.2 Phase Equilibrium 327 $aAppendix: Thermodynamics and Critical PhenomenaReferences; Problems; 5 Chain Configurations; 5.1 Preliminary Descriptions of a Polymer Chain; 5.2 Random Walk and the Markov Process; 5.2.1 Random Walk; 5.2.2 Markov Chain; 5.3 Random-Flight Chains; 5.4 Wormlike Chains; 5.5 Flory's Mean-Field Theory; 5.6 Perturbation Theory; 5.6.1 First-Order Perturbation Theory; 5.6.2 Cluster Expansion Method; 5.7 Chain Crossover and Chain Entanglement; 5.7.1 Concentration Effect; 5.7.2 Temperature Effect; 5.7.3 Tube Theory (Reptation Theory); 5.7.4 Images of Individual Polymer Chains 327 $a5.8 Scaling and UniversalityAppendix A Scaling Concepts; Appendix B Correlation Function; References; Problems; 6 Liquid Crystals; 6.1 Mesogens; 6.2 Polymeric Liquid Crystals; 6.2.1 Low-Molecular Weight Liquid Crystals; 6.2.2 Main-Chain Liquid-Crystalline Polymers; 6.2.3 Side-Chain Liquid-Crystalline Polymers; 6.2.4 Segmented-Chain Liquid-Crystalline Polymers; 6.3 Shapes of Mesogens; 6.4 Liquid-Crystal Phases; 6.4.1 Mesophases in General; 6.4.2 Nematic Phase; 6.4.3 Smectic Phase; 6.4.3.1 Smectic A and C; 6.4.4 Compounds Representing Some Mesophases; 6.4.5 Shape and Phase 327 $a6.4.6 Decreasing Order and DH of Phase Transition 330 $aIntegrating coverage of polymers and biological macromolecules into a single text, Physical Chemistry of Macromolecules is carefully structured to provide a clear and consistent resource for beginners and professionals alike. The basic knowledge of both biophysical and physical polymer chemistry is covered, along with important terms, basic structural properties and relationships. This book includes end of chapter problems and references, and also:Enables users to improve basic knowledge of biophysical chemistry and physical polymer chemistry.Explores fully the principles 606 $aMacromolecules 606 $aPhysical organic chemistry 608 $aElectronic books. 615 0$aMacromolecules. 615 0$aPhysical organic chemistry. 676 $a547.7 676 $a547.7045 700 $aSun$b S. 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