LEADER 05369nam 22006494a 450 001 9910146070703321 005 20170815113959.0 010 $a1-280-54201-2 010 $a9786610542017 010 $a0-471-65988-6 010 $a0-471-65989-4 035 $a(CKB)1000000000019002 035 $a(EBL)183682 035 $a(OCoLC)56597370 035 $a(SSID)ssj0000294897 035 $a(PQKBManifestationID)11206520 035 $a(PQKBTitleCode)TC0000294897 035 $a(PQKBWorkID)10312659 035 $a(PQKB)10604115 035 $a(MiAaPQ)EBC183682 035 $a(EXLCZ)991000000000019002 100 $a20031022d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 14$aThe electron capture detector and the study of reactions with thermal electrons$b[electronic resource] /$fE.C.M. Chen, E.S.D. Chen 210 $aHoboken, N.J. $cWiley-Interscience$dc2004 215 $a1 online resource (417 p.) 300 $aDescription based upon print version of record. 311 $a0-471-32622-4 320 $aIncludes bibliographical references and indexes. 327 $aTHE ELECTRON CAPTURE DETECTOR AND THE STUDY OF REACTIONS WITH THERMAL ELECTRONS; CONTENTS; FOREWORD; PREFACE; 1. Scope and History of the Electron; 1.1 General Objectives and Organization; 1.2 General Scope; 1.3 History of the Electron; References; 2. Definitions, Nomenclature, Reactions, and Equations; 2.1 Introduction; 2.2 Definition of Kinetic and Energetic Terms; 2.3 Additional Gas Phase Ionic Reactions; 2.4 Electron Affinities from Solution Data; 2.5 Semi-Empirical Calculations of Energetic Quantities; 2.6 Herschbach Ionic Morse Potential Energy Curves; 2.7 Summary; References 327 $a3. Thermal Electron Reactions at the University of Houston3.1 General Introduction; 3.2 The First Half-Century, 1900 to 1950; 3.3 Fundamental Discovery, 1950 to 1960; 3.4 General Accomplishments, 1960 to 1970; 3.4.1 Introduction; 3.4.2 The Wentworth Group; 3.4.3 Stable Negative-Ion Formation; 3.4.4 Dissociative Thermal Electron Attachment; 3.4.5 Nonlinear Least Squares; 3.5 Milestones in the Wentworth Laboratory and Complementary Methods, 1970 to 1980; 3.6 Negative-Ion Mass Spectrometry and Morse Potential Energy Curves, 1980 to 1990; 3.7 Experimental and Theoretical Milestones, 1990 to 2000 327 $a3.8 Summary of Contributions at the University of HoustonReferences; 4. Theoretical Basis of the Experimental Tools; 4.1 Introduction; 4.2 The Kinetic Model of the ECD and NIMS; 4.3 Nondissociative Electron Capture; 4.4 Dissociative Electron Attachment; 4.5 Electron Affinities and Half-Wave Reduction Potentials; 4.6 Electron Affinities and Ionization Potentials of Aromatic Hydrocarbons; 4.7 Electron Affinities and Charge Transfer Complex Energies; 4.8 Summary; References; 5. Experimental Procedures and Data Reduction; 5.1 Introduction; 5.2 Experimental ECD and NICI Procedures 327 $a5.3 Reduction of ECD Data to Fundamental Properties5.3.1 Introduction; 5.3.2 Acetophenone and Benzaldehyde; 5.3.3 Benzanthracene, Benz[a]pyrene, and 1-Naphthaldehyde; 5.3.4 Carbon Disulfide; 5.3.5 Nitromethane; 5.3.6 Consolidation of Electron Affinities for Molecular Oxygen; 5.4 Reduction of Negative-Ion Mass Spectral Data; 5.5 Precision and Accuracy; 5.6 Evaluation of Experimental Results; 5.7 Summary; References; 6. Complementary Experimental and Theoretical Procedures; 6.1 Introduction; 6.2 Equilibrium Methods for Determining Electron Affinities; 6.3 Photon Techniques 327 $a6.4 Thermal Charge Transfer Methods6.5 Electron and Particle Beam Techniques; 6.6 Condensed Phase Measurements of Electron Affinities; 6.7 Complementary Theoretical Calculations; 6.7.1 Atomic Electron Affinities; 6.7.2 Polyatomic Molecules; 6.8 Rate Constants for Attachment, Detachment, and Recombination; 6.9 Summary; References; 7. Consolidating Experimental, Theoretical, and Empirical Data; 7.1 Introduction; 7.2 Semi-Empirical Quantum Mechanical Calculations; 7.3 Morse Potential Energy Curves; 7.3.1 Classification of Negative-Ion Morse Potentials; 7.3.2 The Negative-Ion States of H(2) 327 $a7.3.3 The Negative-Ion States of I(2) 330 $aBroad in scope, this book describes the general theory and practice of using the Electron Capture Detector (ECD) to study reactions of thermal electrons with molecules. It reviews electron affinities and thermodynamic and kinetic parameters of atoms, small molecules, and large organic molecules obtained by using various methods.* Summarizes other methods for studying reactions of thermal electrons with molecules* Discusses applications in analytical chemistry, physical chemistry, and biochemistry* Provides a data table of electron affinities 606 $aGas chromatography 606 $aElectrons$xCapture 608 $aElectronic books. 615 0$aGas chromatography. 615 0$aElectrons$xCapture. 676 $a541.36 676 $a543.26 676 $a543.85 700 $aChen$b E. C. M$g(Edward C. M.)$0968047 701 $aChen$b E. S. D$0968048 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146070703321 996 $aThe electron capture detector and the study of reactions with thermal electrons$92198562 997 $aUNINA