LEADER 05114nam 2200625 a 450 001 9910146030103321 005 20170815110150.0 010 $a3-527-62041-9 010 $a1-283-83495-2 010 $a3-527-62077-X 010 $a3-527-61993-3 035 $a(CKB)1000000000417221 035 $a(EBL)819499 035 $a(OCoLC)815648594 035 $a(SSID)ssj0000354581 035 $a(PQKBManifestationID)11267483 035 $a(PQKBTitleCode)TC0000354581 035 $a(PQKBWorkID)10314678 035 $a(PQKB)11401904 035 $a(MiAaPQ)EBC819499 035 $a(EXLCZ)991000000000417221 100 $a19931102d1994 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aOrganosilicon chemistry$b[electronic resource] $efrom molecules to materials /$fedited by Norbert Auner, Johann Weis 210 $aWeinheim ;$aNew York $cVCH$dc1994 215 $a1 online resource (374 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29061-3 320 $aIncludes bibliographical references and indexes. 327 $aOrganosilicon Chemistry From Molecules to Materials; Contents; Tetravalent Organosilicon Compounds: Chemistry and Structure; Introduction; Structures of Small Silicon Containing Compounds - Why and How?; Sterically Overcrowded Organosilicon Compounds and their Properties; Synthesis of Functionally Substituted Oligosilanes Based on Silyltriflate Derivatives; Electroreductive Formation of Di- and Polysilanes; Linear Tetrasilanes with Internal Substituents: Oligosilanes with Optical Activity; A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes 327 $a29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H6-n and XnSi3H8-n (X = Br, I)Calculation of the 29 Si NMR Chemical Shifts in Molecules with SIN, SiCl, and SiSi Bonds; Reactivity of Very Electron-Rich Organosilyl Amines; Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes; Fluorofunctional Silylamines and -Hydrazines Precursors for (Si-N) Ring Systems; New Approaches to (Fluoromethyl)silanes; Homo- and heterocyclic Si-O-Systems . Rings and Cages 327 $aSilaheterocycles from Intramolecular Reactions of Silicon-functionalized Diazoacetic EstersSynthesis and Reaction Behavior of Organoalkoxysilylphenols; N-Silylation: New Possibilities for Long-known Amines; On the Acid-catalyzed Reaction of Siloxanes with Alcohols; On the Reactivity of Chlorosiloxanes; Chlorosilanols - more stable than you think - shown with 29Si NMR; Diorganosilyl-bis(O-alkylphosphonates); Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity; Introduction; Basic Principles of the Theory of Bonding in Silicon Compounds 327 $aExpectations from an Unusual Compound: The Chemistry of DecamethylsilicoceneCp*2Si(CO) and CP*2Si(N2): Complexes of Decamethylsilicocene; Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry; Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?; Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines; Reactions of Silaethenes in the Gas Phase and in Solution; The Reaction of Vinylsilanes with Lithium Metal; Small Silicon Ring Compounds: Formation and Reactions 327 $aMatrix Photolysis of Simple AzidosilanesLow-coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes; Unusual Coordination in Phosphorus-Silicon Compounds; Unsaturated Silicon Compounds: Matrix IR Investigations and Quantum Chemical Calculations; Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry; Introduction; Reactivity of Penta- and Hexacoordinated Silicon Species; Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon Centers 327 $aOrganosilicon Metal Compounds: Coordination Chemistry and Catalysis 330 $aDo you need to know what's new in organosilicon chemistry? This book provides in-depth coverage of the latest developments in this interdisciplinary and fast-evolving field:- selectivity and reactivity of organosilicon compounds - new synthetic applications- structure and bonding- applications in materials and polymer scienceWritten by leading experts, this book is a well-referenced and critical overview of modern silicon chemistry.'I recommend this book to the student and the practitioner in this new, very different, and very exciting field'. Eugene G. 606 $aOrganosilicon compounds 608 $aElectronic books. 615 0$aOrganosilicon compounds. 676 $a547 676 $a547.08 676 $a547/.08 701 $aAuner$b Norbert$0906518 701 $aWeis$b Johann$0963192 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146030103321 996 $aOrganosilicon chemistry$92183916 997 $aUNINA