LEADER 04989nam 2200601 450 001 9910146018803321 005 20170814180524.0 010 $a1-282-78432-3 010 $a9786612784323 010 $a3-527-62154-7 010 $a3-527-62155-5 035 $a(CKB)1000000000427794 035 $a(EBL)482121 035 $a(OCoLC)609855540 035 $a(SSID)ssj0000354503 035 $a(PQKBManifestationID)11249038 035 $a(PQKBTitleCode)TC0000354503 035 $a(PQKBWorkID)10302378 035 $a(PQKB)11275905 035 $a(MiAaPQ)EBC482121 035 $a(EXLCZ)991000000000427794 100 $a20160819h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern carbonylation methods /$fedited by La?szlo? Kolla?r 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (385 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31896-8 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aModern Carbonylation Methods; Contents; Preface; List of Contributors; 1 Bite Angle Effects of Diphosphines in Carbonylation Reactions; 1.1 Introduction; 1.2 Rhodium-Catalyzed Hydroformylation; 1.2.1 Introduction; 1.2.2 Steric Bite Angle Effect and Regioselectivity; 1.2.3 Electronic Bite Angle Effect and Activity; 1.2.4 Isotope Effects [24]; 1.3 Platinum-Catalyzed Alkene Hydroformylation; 1.4 Palladium-Catalyzed CO/Ethene Copolymerization; 1.4.1 Polyketone Formation; 1.4.2 Chain Transfer Mechanisms (Initiation-Termination); 1.4.3 Methyl Propanoate Formation; 1.4.4 Theoretical Support 327 $a1.5 Rhodium-Catalyzed Methanol Carbonylation: the Ligand-Modified Monsanto ProcessReferences; 2 Reactivity of Pincer Complexes Toward Carbon Monoxide; 2.1 Reactivity of CO with Pincer Complexes of the Group 10 (Ni, Pd, Pt); 2.1.1 Nickel; 2.1.2 Palladium and Platinum; 2.2 Reactivity of CO with Pincer Complexes of the Group 9 (Rh and Ir); 2.2.1 Rhodium; 2.2.2 Iridium; 2.3 Reactivity of CO with Pincer Complexes of the Group 8 (Fe, Ru, Os); 2.3.1 Iron; 2.3.2 Ruthenium; 2.3.3 Osmium; 2.4 Final Remarks; 2.5 Acknowledgements; References; 3 Enantioselective Carbonylation Reactions; 3.1 Introduction 327 $a3.2 Rhodium-Catalyzed Asymmetric Hydroformylation3.2.1 Introduction; 3.2.2 Catalytic Cycle and Mechanistic Highlights; 3.2.3 Diphosphite Ligands; 3.2.4 Phosphite-Phosphine Ligands; 3.2.5 Other Ligands; 3.3 Pd-catalyzed Asymmetric Hydroxy- and Alkoxycarbonylation Reactions; 3.3.1 Introduction; 3.3.2 Mechanism; 3.3.3 Bidentate Diphosphines; 3.3.4 Ferrocenyldiphosphines; 3.3.5 Hemilabile P-N Ligands; 3.3.6 Monodentate Ligands; 3.3.7 Asymmetric Bis-Alkoxycarbonylation of Alkenes; 3.4 Conclusion; References; 4 Microwave-Promoted Carbonylations; 4.1 Introduction 327 $a4.2 Microwave Heating in Organic Chemistry4.3 Microwave-Promoted Carbonylations; 4.3.1 Microwave-Promoted Carbonylations Using Mo(CO)(6) as a Source of Carbon Monoxide; 4.3.2 Microwave-Promoted Carbonylations Using Co(2)(CO)(8) as a Reaction Mediator; 4.3.3 Microwave-Promoted Carbonylations Using the Solvent as a Source of Carbon Monoxide; 4.3.4 Microwave-Promoted Carbonylations Using Reaction Vessels Prepressurized with Carbon Monoxide; 4.4 Conclusion; References; 5 Recent Advances in Two-Phase Carbonylation; 5.1 Introduction; 5.2 Carbonylation Reactions; 5.2.1 Hydroformylation 327 $a5.2.2 Hydroaminomethylation5.2.3 Hydroesterification (hydroalkoxycarbonylation) and Related Reactions; 5.2.4 Amidocarbonylation and Cyclocarbonylation; 5.3 Methodology and Stability of Catalysts; 5.4 Innovative Concepts for Catalyst Separation in Biphasic Homogeneous Catalysis; References; 6 Catalytic Carbonylations in Ionic Liquids; 6.1 Introduction; 6.2 Brief History; 6.3 Hydroformylation; 6.3.1 Classical Rh and Pt Phosphines Catalyst Precursors; 6.3.2 Ionic Liquids, Catalyst Recycle, Selectivity, and Product Separation; 6.3.3 Pt-Sn and Ru Catalyst Precursors; 6.4 Aryl Halides and Alcohols 327 $a6.5 Carbonylation of Amines 330 $aComprehensively covering modern carbonylation chemistry, this book is an indispensable companion for all synthetic chemists working in industry and academia. This monograph contains everything there is to know from recent advances in the investigation of carbonylation catalysts, via coordination chemistry to the synthetic application of transition metal catalyzed carbonylations. 606 $aCarbonyl compounds$xSynthesis 608 $aElectronic books. 615 0$aCarbonyl compounds$xSynthesis. 676 $a547.036 702 $aKolla?r$b La?szlo? 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910146018803321 996 $aModern carbonylation methods$91230055 997 $aUNINA