LEADER 03309nam 2200601 a 450 001 9910145587403321 005 20170810185740.0 010 $a1-281-23726-4 010 $a9786611237264 010 $a0-470-19905-9 010 $a0-470-19904-0 035 $a(CKB)1000000000408672 035 $a(EBL)333804 035 $a(OCoLC)476138601 035 $a(SSID)ssj0000246517 035 $a(PQKBManifestationID)11188909 035 $a(PQKBTitleCode)TC0000246517 035 $a(PQKBWorkID)10189714 035 $a(PQKB)11083778 035 $a(MiAaPQ)EBC333804 035 $a(EXLCZ)991000000000408672 100 $a20070510d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSix-membered transition states in organic synthesis$b[electronic resource] /$fJaemoon Yang 210 $aHoboken, N.J. $cWiley-Interscience$dc2008 215 $a1 online resource (222 p.) 300 $aDescription based upon print version of record. 311 $a0-470-17883-3 320 $aIncludes bibliographical references and indexes. 327 $aSIX-MEMBERED TRANSITION STATES IN ORGANIC SYNTHESIS; CONTENTS; Preface; Acknowledgments; Introduction; 1 [3,3]-Sigmatropic Rearrangements; General Considerations; Reactions; 1.1 Claisen Rearrangement; 1.2 Johnson-Claisen Rearrangement; 1.3 Ireland-Claisen Rearrangement; 1.4 Cope Rearrangement; 1.5 Anionic Oxy-Cope Rearrangement; 1.6 Aza-Cope-Mannich Reaction; 2 Aldol Reactions; General Considerations; Reactions; 2.1 Asymmetric Syn-Aldol Reaction; 2.2 Asymmetric Anti-Aldol Reaction; 2.3 Proline-Catalyzed Asymmetric Aldol Reaction; 3 Metal Allylation Reactions; General Considerations; Reactions 327 $a3.1 Boron Allylation Reaction3.2 Silicon Allylation Reaction; 4 Stereoselective Reductions; General Considerations; Reactions; 4.1 Diastereoselective Syn-Reduction of ?-Hydroxy Ketones; 4.2 Diastereoselective Anti-Reduction of ?-Hydroxy Ketones; 4.3 Asymmetric Reduction; List of Copyrighted Materials; Abbreviations; Subject Index; Scheme Index of Natural Products 330 $aThis book furthers readers' understanding of the amazing features of six-membered transition states in stereoselective organic reactions. Comprehensive and logically organized, it covers reactions classified in four categories: [3,3]-sigmatropic rearrangements, aldol reactions, metal allylation reactions, and stereoselective reductions. There is a thorough discussion of each reaction category, along with computational studies that support a proposal of a six-membered state. The book assists professors, researchers, and students in proposing reasonable transition states for the description of n 606 $aReaction mechanisms (Chemistry) 606 $aStereochemistry 606 $aOrganic compounds$xSynthesis 608 $aElectronic books. 615 0$aReaction mechanisms (Chemistry) 615 0$aStereochemistry. 615 0$aOrganic compounds$xSynthesis. 676 $a547.2 676 $a547/.2 700 $aYang$b Jaemoon$0921830 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910145587403321 996 $aSix-membered transition states in organic synthesis$92068289 997 $aUNINA