LEADER 05284nam 2200649 a 450 001 9910145584603321 005 20200520144314.0 010 $a1-281-30914-1 010 $a9786611309145 010 $a0-470-69213-8 010 $a0-470-69142-5 035 $a(CKB)1000000000408964 035 $a(EBL)351351 035 $a(OCoLC)476171837 035 $a(SSID)ssj0000224298 035 $a(PQKBManifestationID)11187353 035 $a(PQKBTitleCode)TC0000224298 035 $a(PQKBWorkID)10205573 035 $a(PQKB)10704457 035 $a(MiAaPQ)EBC351351 035 $a(Au-PeEL)EBL351351 035 $a(CaPaEBR)ebr10232920 035 $a(CaONFJC)MIL130914 035 $a(PPN)140406654 035 $a(EXLCZ)991000000000408964 100 $a20070404d2007 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aPolymer reaction engineering$b[electronic resource] /$fedited by Jose? M. Asua 210 $aOxford ;$aAmes, Iowa $cBlackwell Pub.$d2007 215 $a1 online resource (394 p.) 300 $aDescription based upon print version of record. 311 $a1-4051-4442-4 320 $aIncludes bibliographical references and index. 327 $aPolymer Reaction Engineering; Contents; Contributors; Preface; Notation; Acronyms; 1 Introduction to Polymerization Processes; 1.1 Microstructural features of polymers and their effect on properties; 1.1.1 Chemical composition and monomer sequence distribution; 1.1.2 Molecular weight distribution; 1.1.3 Polymer architecture; 1.1.4 Chain configuration; 1.1.5 Morphology; 1.1.6 Effect of processing and compounding on the microstructure of the polymeric materials; 1.2 Classes of polymerizations; 1.2.1 Chain-growth polymerization; 1.2.2 Step-growth polymerization; 1.3 Polymerization techniques 327 $a1.4 Main commercial polymers 1.4.1 Polyolefins; 1.4.2 Styrenic polymers; 1.4.3 Poly(vinyl chloride); 1.4.4 Waterborne dispersed polymers; 1.4.5 Polyesters and polyamides; 1.4.6 Thermosets; 1.5 Polymerization reactors; References; 2 Coordination Polymerization; 2.1 Polyolefin types: microstructural classification and analytical techniques; 2.1.1 Polyethylene types; 2.1.2 Polypropylene types; 2.1.3 Polyolefin microstructural characterization techniques; 2.2 Catalysts for olefin polymerization; 2.2.1 Coordination catalyst types; 2.2.2 Polymerization mechanism 327 $a2.3 Polymerization kinetics for single- and multiple-site catalysts 2.3.1 Homopolymerization; 2.3.2 Copolymerization; 2.3.3 Long-chain branch formation; 2.4 Inter- and intraparticle mass and heat transfer resistances; 2.4.1 Particle fragmentation and morphology control; 2.4.2 Single particle models: inter- and intraparticle mass and heat transfer; 2.5 Industrial olefin polymerization reactors; 2.5.1 Reactor configurations and designs; 2.5.2 Polyethylene manufacturing processes; 2.5.3 Polypropylene manufacturing processes; 2.5.4Mathematical models for industrial reactors; Acknowledgments 327 $aReferences 3 Free-Radical Polymerization: Homogeneous Systems; 3.1 Free-radical polymers: properties and applications; 3.2 FRP mechanisms and kinetics; 3.2.1 Homopolymerization; 3.2.2 Copolymerization; 3.2.3 Diffusion-controlled reactions; 3.2.4 Kinetic balances for modeling polymer MWs; 3.3 Controlled radical polymerization; 3.3.1 Stable free-radical polymerization; 3.3.2 Atom transfer radical polymerization; 3.3.3 Reverse addition-fragmentation chain transferpolymerization; 3.4 Polymer reaction engineering aspects; 3.4.1 Heat removal and temperature programming; 3.4.2 Batch reactors 327 $a3.4.3 Semibatch (semicontinuous) reactors 3.4.4 Continuous stirred-tank reactors; 3.4.5 Tubular reactors; 3.5 A ""roadmap"" for mathematical modeling; References; 4 Free-Radical Polymerization: Heterogeneous Systems; 4.1 Introduction; 4.2 High-impact polystyrene; 4.2.1 Interrelationship between microstructure and application properties; 4.2.2 Modeling HIPS polymerization; 4.2.3 Optimizing final properties: melt flow index in a continuous HIPS process; 4.2.4 Final remarks for HIPS; 4.3 Vinyl chloride monomer bulk polymerization; 4.3.1 Kinetic mechanism; 4.3.2 PVC morphology; Acknowledgments 327 $aReferences 330 $aPolymers are an example of ""products-by-process"", where the final product properties are mostly determined during manufacture, in the reactor. An understanding of processes occurring in the polymerization reactor is therefore crucial to achieving efficient, consistent, safe and environmentally friendly production of polymeric materials.Polymer Reaction Engineering provides the link between the fundamentals of polymerization kinetics and polymer microstructure achieved in the reactor. Organized according to the type of polymerization, each chapter starts with a description of the main 606 $aPolymerization 606 $aPolymer engineering 615 0$aPolymerization. 615 0$aPolymer engineering. 676 $a668.9/2 701 $aAsua$b Jose? M$0962718 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910145584603321 996 $aPolymer reaction engineering$92182933 997 $aUNINA