LEADER 05257nam 2200613 a 450 001 9910145283203321 005 20230721030525.0 010 $a1-281-23728-0 010 $a9786611237288 010 $a0-470-22675-7 010 $a0-470-22674-9 035 $a(CKB)1000000000400033 035 $a(EBL)333746 035 $a(OCoLC)437202669 035 $a(SSID)ssj0000139273 035 $a(PQKBManifestationID)11146838 035 $a(PQKBTitleCode)TC0000139273 035 $a(PQKBWorkID)10011244 035 $a(PQKB)10747163 035 $a(MiAaPQ)EBC333746 035 $a(Au-PeEL)EBL333746 035 $a(CaPaEBR)ebr10226716 035 $a(CaONFJC)MIL123728 035 $a(EXLCZ)991000000000400033 100 $a20070612d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aDihydrogen bonds$b[electronic resource] $eprinciples, experiments, and applications /$fVladimir I. Bakhmutov 210 $aHoboken, N.J. $cWiley-Interscience$dc2008 215 $a1 online resource (257 p.) 300 $aDescription based upon print version of record. 311 $a0-470-18096-X 320 $aIncludes bibliographical references and index. 327 $aDIHYDROGEN BONDS; CONTENTS; Preface; 1 Introduction: Weak Noncovalent Interactions; References; 2 Brief Summary of Hydrogen-Bonded Systems: Definitions and General View; 2.1 Conventional Hydrogen Bonds: Theoretical and Experimental Criteria of Hydrogen Bond Formation; 2.1.1 Energy and Geometry of Conventional Hydrogen Bonds; 2.1.2 Cooperative and Anticooperative Energy Effects in Systems with Classical Hydrogen Bonds; 2.1.3 Dynamics of Classical Hydrogen Bonds; 2.2 Nonconventional Hydrogen Bonds as a Part of Hydrogen-Bonded Systems: Definition and Classification 327 $a2.3 Difference Between Hydrogen and Chemical Bonds2.4 Concluding Remarks; References; 3 Concept of Dihydrogen Bonding; 3.1 General View: From an H(2) Molecule to a Dihydrogen Bond via a Dihydrogen Ligand; 3.2 The Nature of Dihydrogen Bonding: The Topology of Electron Density and Contributions to Total Bonding Energy; 3.3. Scalar Spin-Spin Coupling Through Dihydrogen Bonds as Evidence of Their Partly Covalent Character; 3.4 Field Effects on Dihydrogen Bonding; 3.5 Pressure Effects on Dihydrogen Bonding; 3.6 Difference Between Hydrogen and Dihydrogen Bonds; 3.7 Concluding Remarks; References 327 $a4 How to Find a Dihydrogen Bond: Experimental Criteria of Dihydrogen Bond Formation4.1 Dihydrogen-Bonded Complexes in the Solid State: X-Ray and Neutron Diffraction Evidence; 4.1.1 Topology of Electron Density in Dihydrogen-Bonded Systems from Diffraction Data; 4.2 Gas-Phase Experiments with Dihydrogen-Bonded Complexes; 4.3 Experiments with Dihydrogen-Bonded Complexes in Solutions; 4.3.1 IR Spectral Criteria for the Formation of Dihydrogen-Bonded Complexes in Solutions; 4.3.2 How to Determine the Stoichiometry of Dihydrogen-Bonded Complexes in Solution by IR Spectroscopy 327 $a4.3.3 Energy Parameters of Dihydrogen-Bonded Complexes from IR Spectra in Solution4.3.4 (1)H Nuclear Magnetic Resonance Evidence for Dihydrogen Bonding in Solution; 4.3.5 Energy Parameters of Dihydrogen Bonds in Solution from (1)H NMR; 4.4 Concluding Remarks; References; 5 Intramolecular Dihydrogen Bonds: Theory and Experiment; 5.1 Weak Intramolecular Bonding: C-H· · ·H-C in Systems with Slightly Polarized Bonds CH; 5.2 Intramolecular Dihydrogen Bonds in Solid Amino Acids: C-H Bonds as Weak Proton Acceptors; 5.3 Intramolecular Dihydrogen Bonds: C-H· · ·H-B 327 $a5.4 Intramolecular Bonds: N-H· · ·H-B and O-H· · ·H-B5.5 Intramolecular Dihydrogen Bonds in Metal Hydride Complexes; 5.5.1 Intramolecular Dihydrogen Bonds in Metal Hydride Clusters; 5.6 Connection Between Intramolecular Dihydrogen Bonding and Dehydrogenation Reactions; 5.7 Concluding Remarks; References; 6 Intermolecular Dihydrogen-Bonded Complexes: From Groups 1A-4A to Xenon Dihydrogen-Bonded Complexes; 6.1 Group 1A: Dihydrogen Bonds X-H· · ·H-Li and X-H· · ·H-Na (X = F, Cl, NH(3), CN, NC, HO, HS, ClCC, FCC, HCC) 327 $a6.2 Group 2A: Dihydrogen Bonds X-H· · ·H-Mg and X-H· · ·H-Be (X = F, Cl, Br, NH(3), NNN, CN, NC, ClCC, FCC, HCC, CH(3)CC, F(2)Be, FKr, FAr) 330 $aThis definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions and molecular aggregations. After an overview, it analyzes the differences between dihydrogen bonds, classical hydrogen bonds, and covalent bonds. It describes dihydrogen bonds as intermediates in intramolecular and intermolecular proton transfer reactions. It describes dihydrogen bonding in the solid-state, the gas phase, and in solution. This is the premier reference for physical chemists, biochemists, biophysicists, and chemical engi 606 $aDihydrogen bonding 615 0$aDihydrogen bonding. 676 $a541/.226 700 $aBakhmutov$b Vladimir I$0288384 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910145283203321 996 $aDihydrogen bonds$92273195 997 $aUNINA LEADER 02505nam 2200685 a 450 001 9910959039603321 005 20251117080919.0 010 $a1-280-49093-4 010 $a9786613586162 010 $a0-8203-4367-6 035 $a(CKB)2670000000176111 035 $a(EBL)3039102 035 $a(OCoLC)784959323 035 $a(SSID)ssj0000644998 035 $a(PQKBManifestationID)11403258 035 $a(PQKBTitleCode)TC0000644998 035 $a(PQKBWorkID)10680401 035 $a(PQKB)11212405 035 $a(MdBmJHUP)muse17748 035 $a(Au-PeEL)EBL3039102 035 $a(CaPaEBR)ebr10555746 035 $a(CaONFJC)MIL358616 035 $a(Perlego)839530 035 $a(MiAaPQ)EBC3039102 035 $a(EXLCZ)992670000000176111 100 $a20110927d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 04$aThe bioregional imagination $eliterature, ecology, and place /$fedited by Tom Lynch, Cheryll Glotfelty, and Karla Armbruster ; maps by Ezra Zeitler 205 $a1st ed. 210 $aAthens $cUniversity of Georgia Press$d2012 215 $a1 online resource (xiv, 438 pages) $cillustrations, maps 300 $aIncludes index. 311 08$a0-8203-4171-1 320 $aIncludes bibliographical references and index. 327 $apt. 1. Reinhabiting -- pt. 2. Rereading -- pt. 3. Reimaging -- pt. 4. Renewal. 330 $aBioregionalism is an innovative way of thinking about place and planet from an ecological perspective. Although bioregional ideas occur regularly in ecocritical writing, until now no systematic effort has been made to outline the principles of bioregional literary criticism and to use it as a way to read, write, understand, and teach literature. 606 $aBioregionalism in literature 606 $aEcology in literature 606 $aPlace (Philosophy) in literature 606 $aEcocriticism 615 0$aBioregionalism in literature. 615 0$aEcology in literature. 615 0$aPlace (Philosophy) in literature. 615 0$aEcocriticism. 676 $a809/.9336 701 $aLynch$b Tom$f1955-$01805115 701 $aGlotfelty$b Cheryll$01892856 701 $aArmbruster$b Karla$0526604 701 $aZeitler$b Ezra J$01892857 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910959039603321 996 $aThe bioregional imagination$94539833 997 $aUNINA