LEADER 05342nam 2200661Ia 450 001 9910144830003321 005 20240227221527.0 010 $a1-282-37217-3 010 $a9786612372179 010 $a3-527-61901-1 010 $a3-527-61902-X 035 $a(CKB)1000000000687746 035 $a(EBL)481700 035 $a(OCoLC)609855419 035 $a(SSID)ssj0000301778 035 $a(PQKBManifestationID)11261536 035 $a(PQKBTitleCode)TC0000301778 035 $a(PQKBWorkID)10263322 035 $a(PQKB)11543325 035 $a(MiAaPQ)EBC481700 035 $a(PPN)242616933 035 $a(EXLCZ)991000000000687746 100 $a20060322d2007 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aLight-matter interaction$b[electronic resource] $eatoms and molecules in external fields and nonlinear optics /$fWendell T. Hill and Chi H. Lee 210 $aWeinheim $cWiley-VCH ;$aChichester $cJohn Wiley [distributor]$d2007 215 $a1 online resource (328 p.) 300 $aDescription based upon print version of record. 311 $a3-527-40661-1 320 $aIncludes bibliographical references and index. 327 $aLight-Matter Interaction; Contents; Preface; Part 1 Light-Matter Interaction: Atoms, Molecules and External Fields; 1 Hydrogen-Like Ion: An Atom (Ion) With One Electron; 1.1 Bohr Model of the Atom; 1.2 Hydrogen-Like Ions, Quantum Approach: Bound States; 1.2.1 Angular Wavefunctions; 1.2.2 Radial Wavefunction and Energy States; 1.2.3 Exact Radial Solution, Hydrogen-Like Ions; 1.2.4 Energy Units and Atomic States; 1.3 Classification of Nonrelativistic States; 1.3.1 Parity; 1.3.2 Degeneracy; 1.4 Corrections to the Energy Levels; 1.4.1 Relativistic Motion 327 $a1.4.1.1 Electron Spin and the Dirac Equation1.4.1.2 Classification of Relativistic Hydrogen States; 1.4.1.3 Hydrogen-Like Ion Wavefunction Including Spin; 1.4.2 Fine Structure and Spin-Orbit Interaction; 1.4.3 Rydberg Series; 1.5 Continuum States; Further Reading; Problems; 2 The Structure of the Multielectron Atom; 2.1 Overview; 2.2 Angular Momentum Coupling Schemes; 2.2.1 LS or Russell-Saunders Coupling; 2.2.2 jj Coupling; 2.2.3 Intermediate or Pair Coupling; 2.2.4 Recoupling Between Coupling Schemes; 2.3 Fine Structure; Further Reading; Problems; 3 Atoms in Static Fields 327 $a3.1 External Electric and Magnetic Fields3.1.1 Stark Effect; 3.1.1.1 Linear Stark Effect; 3.1.1.2 Quadratic Stark Effect; 3.1.2 Zeeman Effect; 3.2 Hyperfine Structure; 3.2.1 Magnetic Interaction; 3.2.2 Explicit Expression for A(l); 3.2.3 Hyperfine Zeeman Effect; 3.2.4 Electric Quadrupole Correction; Further Reading; Problems; 4 Atoms in AC Fields; 4.1 Applied EM Fields; 4.1.1 Radiation Hamiltonian; 4.1.2 Coulomb or Radiation Gauge; 4.2 Free-Electron Wavefunction; 4.3 Radiative Transitions; 4.3.1 One-Photon Transitions; 4.3.2 Two-Photon Transitions; 4.3.3 Transition Rate: Fermi's Golden Rule 327 $a4.3.3.1 Degeneracy4.3.3.2 Narrow and Broad Sources; 4.3.4 Transition Strength: Absorption; 4.3.4.1 Line Strength; 4.3.4.2 Cross Section; 4.3.4.3 Oscillator Strength; 4.3.5 Transition Strength: Emission; 4.4 Selection Rules for Atomic Transitions; 4.4.1 Electric Dipole (E1) Transitions; 4.4.2 Magnetic Dipole (M1) Transitions; 4.4.3 Electric Quadrupole (E2) Transitions; 4.5 Atomic Spectra; 4.5.1 Rydberg Series; 4.5.2 Autoionization; 4.5.3 Photoionization with Intense Lasers; Further Reading; Problems; 5 Diatomic Molecules; 5.1 The Hamiltonian; 5.2 Born-Oppenheimer Approximation 327 $a5.3 Nuclear Equation5.3.1 Harmonic Approximation of U(R); 5.3.2 Beyond the Harmonic Approximation of U(R); 5.3.3 Vibrating Rotator; 5.3.4 Analytic Expression for U(R); 5.3.5 More Accurate Techniques; 5.4 Electronic States; 5.4.1 Angular Momenta in Cylindrically Symmetric Fields; 5.4.1.1 Orbital Angular Momentum; 5.4.1.2 Spin Angular Momentum; 5.4.1.3 Multiplet Splitting; 5.4.1.4 Total Angular Momentum; 5.4.1.5 Labeling Nomenclature; 5.4.2 Angular Momenta Coupling: Hund's Cases; 5.4.2.1 Hund's Case (a); 5.4.2.2 Hund's Case (b); 5.4.2.3 Hund's Case (c); 5.4.2.4 Hund's Case (d) 327 $a5.4.3 Molecular Symmetries: Electronic Motion 330 $aThis book draws together the principal ideas that form the basis of atomic, molecular, and optical science and engineering. It covers the basics of atoms, diatomic molecules, atoms and molecules in static and electromagnetic fields and nonlinear optics. Exercises and bibliographies supplement each chapter, while several appendices present such important background information as physics and math definitions, atomic and molecular data, and tensor algebra.Accessible to advanced undergraduates, graduate students, or researchers who have been trained in one of the conventional curricula of phy 606 $aAtoms 606 $aNonlinear optics 606 $aMolecules 615 0$aAtoms. 615 0$aNonlinear optics. 615 0$aMolecules. 676 $a535.2 676 $a539 700 $aHill$b Wendell T$0522070 701 $aLee$b Chi H$0522071 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144830003321 996 $aLight-matter interaction$9835071 997 $aUNINA