LEADER 05131nam 2200625Ia 450 001 9910144712903321 005 20170816122514.0 010 $a1-280-85460-X 010 $a9786610854608 010 $a3-527-61020-0 010 $a3-527-61019-7 035 $a(CKB)1000000000377547 035 $a(EBL)482316 035 $a(OCoLC)123503997 035 $a(SSID)ssj0000145077 035 $a(PQKBManifestationID)11163574 035 $a(PQKBTitleCode)TC0000145077 035 $a(PQKBWorkID)10167991 035 $a(PQKB)10472186 035 $a(MiAaPQ)EBC482316 035 $a(PPN)124442625 035 $a(EXLCZ)991000000000377547 100 $a20060529d2007 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aElectrocrystallization in nanotechnology$b[electronic resource] /$fedited by Georgi Staikov 210 $aWeinheim $cWiley-VCH$dc2007 215 $a1 online resource (281 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31515-2 320 $aIncludes bibliographical references and index. 327 $aElectrocrystallization in Nanotechnology; Contents; Preface; List of Contributors; I Fundamentals; 1 The Impact of Electrocrystallization on Nanotechnology; 1.1 Introduction; 1.2 Thermodynamic Properties of Large and Small Phases; 1.2.1 The State of Thermodynamic Equilibrium; 1.2.2 Electrochemical Supersaturation and Undersaturation; 1.2.3 The Thermodynamic Work for Nucleus Formation; 1.2.3.1 Classical Nucleation Theory; 1.2.3.2 Atomistic Nucleation Theory; 1.3 Kinetics of Nucleus Formation in Electrocrystallization 327 $a1.4 Energy State of the Electrode Surface and Spatial Distribution of Nanoclusters1.5 Electrochemical Growth of Nanoparticles and Ultrathin Films; 1.5.1 Growth of 3D Nanoclusters; 1.5.2 Growth of 2D Nanoclusters and Formation of UPD Monolayers; 1.6 Localization of Electrocrystallization Processes and Nanostructuring; 1.7 Conclusion; Acknowledgments; References; 2 Computer Simulations of Electrochemical Low-dimensional Metal Phase Formation; 2.1 Introduction; 2.2 Molecular Dynamics Simulations; 2.2.1 Generalities; 2.2.2 Nanostructuring of Metallic Surfaces; 2.3 Monte Carlo Method 327 $a2.3.1 Generalities2.3.2 Off-lattice Models; 2.3.2.1 Stability of Metallic Nanostructures; 2.3.3 Lattice Models; 2.3.3.1 Introduction; 2.3.3.2 Electrocrystallization; 2.3.3.3 Dynamics of Crystal Growth; 2.3.3.4 Simulation of a Complex Underpotential Deposition System; 2.4 Brownian and Langevin Dynamics Simulations; 2.4.1 Generalities; 2.4.2 Applications in Electrochemical Nanostructuring and Crystal Growth; 2.5 Conclusions and Outlook; Acknowledgments; References; 3 Electrodeposition of Metals in Templates and STM Tip-generated 0D Nanocavities; 3.1 Introduction; 3.2 Bottom-up Template Approach 327 $a3.3 Top-down SPM Approach3.4 Thermodynamics of Low-dimensional Phases; 3.5 Experiments on the Electrodeposition in STM-tip-generated Nanocavities; 3.6 Underpotential Behavior of Bismuth on Gold; 3.7 Zero-dimensional Bi Deposition; 3.8 Conclusions; Acknowledgment; References; 4 Nanoscale Electrocrystallization of Metals and Semiconductors from Ionic Liquids; 4.1 Introduction; 4.2 Some Electrochemical and Interfacial Characteristics of Ionic Liquids (ILs); 4.3 Variable Temperature Electrochemical SPM Technique for Studies with Ionic Liquids 327 $a4.4 Underpotential Deposition of Metals: Phase Formation and Transitions4.4.1 Ag on Au(111): Aqueous versus Ionic Liquid Electrolytes; 4.4.2 Zn on Au(111): Spinodal Decomposition and Surface Alloying; 4.5 Overpotential Deposition of Metals, Alloys and Semiconductors; 4.5.1 Co-Al, Ni-Al and Ti-Al Alloy Deposition; 4.5.2 Nanoscale Growth of Al-Sb Compound Semiconductors; 4.6 Concluding Remarks; Acknowledgment; References; 5 Superconformal Film Growth; 5.1 Introduction; 5.2 Competitive Adsorption: Inhibition versus Acceleration 327 $a5.3 Quantifying the Impact of Competitive Adsorption on Metal Deposition Kinetics 330 $aHere, the well-known editor in the field of electrocrystallization and his team of excellent international authors guarantee the high quality of the contributions.Clearly structured in two main parts, this book reviews the fundamentals and applications of electrocrystallization processes in nanotechnology. The first part, ""Fundamentals"" covers the basic concepts of electrocrystallization, computer simulations of low-dimensional metal phase formation, electrodeposition in templates and nanocavities, nanoscale electrocrystallization from ionic liquids, and superconformal electrodeposition 606 $aElectrocrystallization 606 $aNanotechnology 615 0$aElectrocrystallization. 615 0$aNanotechnology. 676 $a548.5 676 $a621.381 701 $aStaikov$b Georgi$0866153 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144712903321 996 $aElectrocrystallization in nanotechnology$91933190 997 $aUNINA