LEADER 05251nam 2200649Ia 450 001 9910144710303321 005 20170810194951.0 010 $a1-280-52119-8 010 $a9786610521197 010 $a3-527-60661-0 010 $a3-527-60689-0 035 $a(CKB)1000000000377554 035 $a(EBL)481986 035 $a(OCoLC)70114872 035 $a(SSID)ssj0000167298 035 $a(PQKBManifestationID)11163657 035 $a(PQKBTitleCode)TC0000167298 035 $a(PQKBWorkID)10169082 035 $a(PQKB)11759175 035 $a(MiAaPQ)EBC481986 035 $a(PPN)249486733 035 $a(EXLCZ)991000000000377554 100 $a20040717d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aHandbook of condensation thermoplastic elastomers$b[electronic resource] /$fStokyo Fakirov 210 $aWeinheim ;$a[Great Britain] $cWiley-VCH$d2005 215 $a1 online resource (645 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30976-4 320 $aIncludes bibliographical references and index. 327 $aHandbook of Condensation Thermoplastic Elastomer; Preface; Contents; Contributors; PART I INTRODUCTION; Chapter 1 Creation and Development of Thermoplastic Elastomers, and Their Position Among Organic Materials; 1. Birth and development of TPEs: a brief survey; 2. Main routes to thermoplastic elastomer preparation; 2.1. Living anionic polymerization; 2.2. Living cationic polymerization; 2.3. Controlled radical polymerization; 2.4. Polycondensation and polyaddition; 2.5. Chemical modification and grafting; 2.6. Preparation by blending; 2.7. Preparation by dynamic vulcanization 327 $a3. Techniques used in the characterization of TPEs3.1. Chromatography; 3.2. Spectrometric techniques; 3.3. Scattering techniques; 3.4. Microscopies; 3.5. Controlled degradation; 3.6. Thermal techniques; 4. Properties and processing of TPEs; 4.1. Injection molding; 4.2. Compression molding; 4.3. Extrusion; 4.4. Blow processings; 4.5. Thermoforming; 4.6. Reactive processings; 4.7. Degradation in processing; 5. Position of TPEs among organic materials and their applications; 6. Future trends; References 327 $aChapter 2 Polycondensation Reactions in Thermoplastic Elastomer Chemistry: State of the Art, Trends, and Future Developments1. Introduction; 2. Preparation of block copolymers by polycondensation. A critical review; 2.1. General considerations; 2.2. Direct polycondensation of ?,?-difunctional oligomers; 2.3. Polycondensation of an ?,?-difunctional oligomer with the precursors of another block; 2.4. Oligomer-coupling reactions; 2.5. Characterization techniques. Side reactions; 3. New structures; 3.1. Block copolymers containing liquid crystalline structures 327 $a3.2. Liquid crystalline sequences as part of the backbone3.3. Liquid crystalline sequences as side chains; 3.4. Metallo-supramolecular block copolymers; 3.5. Block copolymers prepared from metal-containing macrocycles; 3.6. The use of microorganisms; 4. Conclusions; References; PART II POLYESTER-BASED THERMOPLASTIC ELASTOMERS; Chapter 3 Polyester Thermoplastic Elastomers: Synthesis, Properties, and Some Applications; 1. Introduction; 2. Chemical structure of polyester elastomers; 3. Poly(alkylene oxide) flexible segment-based polyester elastomers 327 $a4. Modified poly(butylene terephthalate) rigid segment-based polyester elastomers5. Branched polyester elastomers; 6. Synthesis of poly(ether ester) block copolymers; 7. Other multiblock polyester elastomers; 8. Polyester thermoplastic elastomers from blends; 9. A new processing aspect: weldability of polyester elastomers; 10. Polyester elastomers for biomedical application; 11. Conclusions and outlook; References; Chapter 4 Terpoly(Ester-b-Ether-b-Amide) Thermoplastic Elastomers: Synthesis, Structure, and Properties; 1. Introduction; 2. Chemical structure of terpoly(ester-b-ether-b-amide)s 327 $a3. Synthesis of triblock -(GT-b-PO4-b-PA)(n)- polymers 330 $aReporting on the work of an international team of scientists actively involved in the study of thermoplastic elastomers (TPE) based on polyesters, polyamides, and polyurethanes, this book is the first to provide a detailed description of condensation TPE with close attention paid to polyamide-based systems. Reflecting the increasing importance of TPE as engineering plastics, the authors discuss the widened application opportunities by preparing systems with various chemical compositions and molecular structures as (semi-) interpenetrating networks. The contents also cover the chemical aspects, 606 $aElastomers 606 $aThermoplastics 606 $aCondensation products (Chemistry) 615 0$aElastomers. 615 0$aThermoplastics. 615 0$aCondensation products (Chemistry) 676 $a620.194 700 $aFakirov$b Stoyko$0958185 701 $aFakirov$b Stoyko$0958185 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144710303321 996 $aHandbook of condensation thermoplastic elastomers$92230641 997 $aUNINA