LEADER 05445nam 2200673Ia 450 001 9910139551803321 005 20200520144314.0 010 $a3-527-65046-6 010 $a1-280-66568-8 010 $a9786613642615 010 $a3-527-65044-X 010 $a3-527-65047-4 035 $a(CKB)2550000000100551 035 $a(EBL)915631 035 $a(OCoLC)798928669 035 $a(SSID)ssj0000654420 035 $a(PQKBManifestationID)11398959 035 $a(PQKBTitleCode)TC0000654420 035 $a(PQKBWorkID)10661888 035 $a(PQKB)10382288 035 $a(MiAaPQ)EBC915631 035 $a(Au-PeEL)EBL915631 035 $a(CaPaEBR)ebr10560661 035 $a(CaONFJC)MIL364261 035 $a(PPN)260291935 035 $a(EXLCZ)992550000000100551 100 $a20120528d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAryl diazonium salts$b[electronic resource] $enew coupling agents in polymer and surface science /$fedited by Mohamed Mehdi Chehimi 210 $aWeinheim, Germany $cWiley-VCH$d2012 215 $a1 online resource (359 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32998-6 320 $aIncludes bibliographical references and index. 327 $aAryl Diazonium Salts: New Coupling Agents in Polymer and Surface Science; Contents; Preface; List of Contributors; 1: Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts; 1.1: A Brief Survey of the Chemistry and Electrochemistry of Diazonium Salts; 1.2: The Different Methods that Permit Grafting of Diazonium Salts; 1.2.1: Electrochemistry; 1.2.2: Reducing Substrate, Homolytic Dediazonation, Reaction with the Substrate; 1.2.3: Reducing Reagent; 1.2.4: Neutral and Basic Media; 1.2.5: Ultrasonication; 1.2.6: Heating and Microwave; 1.2.7: Mechanical Grafting 327 $a1.2.8: Photochemistry1.3: The Different Substrates, Diazonium Salts, and Solvents that Can Be Used; 1.3.1: Substrates; 1.3.2: Diazonium Salts; 1.3.3: Solvents; 1.4: Evidence for the Presence of a Bond between the Substrate and the Organic Layer; 1.4.1: Stability of the Layer; 1.4.2: Spectroscopic Evidence for a Bond; 1.5: From Monolayers to Multilayers; 1.5.1: Monolayers; 1.5.2: Layers of Medium Thickness; 1.5.2.1 Thick Layers; 1.6: Structure and Formation of Multilayers; 1.6.1: Chemical Structure; 1.6.2: The Spatial Structure of the Layers; 1.6.3: Compactness of the Layers 327 $a1.6.4: Swelling of the Layer1.6.5: Electron Transfer through the Layers; 1.6.6: The Formation Mechanism of Multilayers; 1.7: Conclusion; References; 2: Aryl-Surface Bonding: A Density Functional Theory (DFT)Simulation Approach; 2.1: Introduction; 2.2: Density Functional Theory; 2.3: Bonding between Aryl and Various Substrates; 2.3.1: On Graphite/Graphene; 2.3.1.1 On the Basal Plane; 2.3.1.2 On the Edges of Graphene; 2.3.2: On Carbon Nanotubes; 2.3.3: On Metal Surfaces; 2.4: Summary and Outlook; Acknowledgments; References; 3: Patterned Molecular Layers on Surfaces 327 $a3.1: Methods Based on Scanning Probe Lithography3.1.1: AFM; 3.1.2: SECM; 3.1.3: Spotting; 3.2: Methods Based on Soft Lithography; 3.2.1: Printing; 3.2.2: Molds; 3.2.3: Nanosphere Lithography; 3.3: Methods Based on Lithography; 3.4: Methods Based on Surface-Directed Patterning; 3.4.1: Modification of Si Surfaces; 3.4.2: Modified Electrode Arrays; 3.5: Summary and Conclusions; References; 4: Analytical Methods for the Characterization of Aryl Layers; 4.1: Introduction; 4.2: Scanning Probe Microscopies; 4.3: UV-VIS Spectroscopy: Transmission, Reflection, and Ellipsometry; 4.4: IR Spectroscopy 327 $a4.4.1: Transmission Spectroscopy4.4.2: Reflection Spectroscopy; 4.4.3: Infrared Spectroscopic Ellipsometry (IRSE); 4.4.4: IRSE Surface Characterization; 4.4.5: In Situ IR Spectroscopy: ATR and IRSE; 4.5: Raman Spectroscopy and Surface-Enhanced Raman Scattering (SERS); 4.6: X-ray Photoelectron Spectroscopy (XPS); 4.7: X-ray Standing Waves (XSW); 4.8: Rutherford Backscattering; 4.9: Time of Flight Secondary Ion Mass Spectroscopy; 4.10: Electrochemistry; 4.11: Contact Angle Measurements; 4.12: Conclusion; References; 5: Modification of Nano-objects by Aryl Diazonium Salts; 5.1: Introduction 327 $a5.2: Electrochemical Modification of Nano-objects by Reduction of Diazonium Salts 330 $aDiazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and physical properties and find widespread applications. The advantage of aryl diazonium salts compared to other surface modifiers lies in their ease of preparation, rapid (electro)reduction, large choice of reactive functional groups, and strong aryl-surface covalent bonding.This unique book summarizes the current knowledge of the surface and 606 $aDiazo compounds 606 $aPolymers$xSurfaces 615 0$aDiazo compounds. 615 0$aPolymers$xSurfaces. 676 $a541.33 676 $a547.86 701 $aChehimi$b Mohamed Mehdi$0892059 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139551803321 996 $aAryl diazonium salts$91992258 997 $aUNINA LEADER 02801oas 2201105 a 450 001 9910144610403321 005 20251105213014.0 011 $a1432-0592 035 $a(DE-599)ZDB1471201-5 035 $a(DE-599)1471201-5 035 $a(OCoLC)39965859 035 $a(CONSER) 2004233557 035 $a(CKB)954925531966 035 $a(EXLCZ)99954925531966 100 $a19980930a19679999 sy a 101 0 $aeng 135 $aurmnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 14$aThe annals of regional science 210 $aHeidelberg $cSpringer-Verlag Heidelberg 215 $a1 online resource 300 $aRefereed/Peer-reviewed 300 $a"An international journal of urban, regional and environmental research and policy." 311 08$a0570-1864 606 $aRegional planning$vPeriodicals 606 $aCity planning$vPeriodicals 606 $aAme?nagement du territoire$vPe?riodiques 606 $aUrbanisme$vPe?riodiques 606 $aUrban Planning & Development$2ebps 606 $aCity planning$2fast$3(OCoLC)fst00862177 606 $aRegional planning$2fast$3(OCoLC)fst01093120 606 $aRegionale economie$2gtt 606 $aREGIONAL PLANNING$2unbist 606 $aURBAN AREAS$2unbist 608 $aperiodicals.$2aat 608 $aPeriodicals.$2fast 608 $aPeriodicals.$2lcgft 608 $aPe?riodiques.$2rvmgf 615 0$aRegional planning 615 0$aCity planning 615 6$aAme?nagement du territoire 615 6$aUrbanisme 615 7$aUrban Planning & Development. 615 7$aCity planning. 615 7$aRegional planning. 615 17$aRegionale economie. 615 07$aREGIONAL PLANNING. 615 07$aURBAN AREAS. 676 $a309.2505 712 02$aWestern Regional Science Association 801 0$bPIT 801 1$bPIT 801 2$bOCL 801 2$bOCLCQ 801 2$bTWT 801 2$bGUA 801 2$bOCLCQ 801 2$bMUQ 801 2$bOCL 801 2$bCIT 801 2$bOCLCQ 801 2$bUKMGB 801 2$bOCLCQ 801 2$bOCLCF 801 2$bOCLCO 801 2$bOCLCQ 801 2$bOCLCE 801 2$bFJM 801 2$bWT2 801 2$bOCLCQ 801 2$bAU@ 801 2$bVT2 801 2$bDLC 801 2$bU3W 801 2$bNJT 801 2$bOCLCQ 801 2$bLDP 801 2$bNTG 801 2$bCRL 801 2$bOCLCO 801 2$bOCLCQ 801 2$bM6U 801 2$bOSU 801 2$bHUL 801 2$bDHU 801 2$bOCLCL 801 2$bOCLCQ 801 2$bOCLCL 801 2$bOCLCQ 906 $aJOURNAL 912 $a9910144610403321 996 $aAnnals of regional science$9966879 997 $aUNINA