LEADER 05371nam 22006854a 450 001 9910144328203321 005 20220609160359.0 010 $a1-280-51956-8 010 $a9786610519569 010 $a3-527-60469-3 010 $a3-527-60409-X 035 $a(CKB)1000000000376387 035 $a(EBL)481834 035 $a(OCoLC)68623514 035 $a(SSID)ssj0000204507 035 $a(PQKBManifestationID)11174231 035 $a(PQKBTitleCode)TC0000204507 035 $a(PQKBWorkID)10188125 035 $a(PQKB)11435697 035 $a(MiAaPQ)EBC481834 035 $a(EXLCZ)991000000000376387 100 $a20070725d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern rhodium-catalyzed organic reactions$b[electronic resource] /$fedited by P. Andrew Evans 210 $aWeinheim $cWiley-VCH$dc2005 215 $a1 online resource (499 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30683-8 320 $aIncludes bibliographical references and index. 327 $aModern Rhodium-Catalyzed Organic Reactions; Foreword; Preface; Contents; List of Contributors; 1 Rhodium-Catalyzed Asymmetric Hydrogenation; 1.1 Introduction; 1.2 Chiral Phosphorous Ligands; 1.2.1 Atropisomeric Biaryl Bisphosphine Ligands; 1.2.2 Chiral Bisphosphane Ligands Based on the Modification of DuPhos and BPE; 1.2.3 Chiral Bisphosphane Ligands Based on the Modification of DIOP; 1.2.4 Chiral Ferrocene-Based Bisphosphane Ligands; 1.2.5 P-Chiral Bisphosphane Ligands; 1.2.6 Other Bisphosphane Ligands; 1.2.7 Bisphosphinite, Bisphosphonite, and Bisphosphite Ligands 327 $a1.2.8 Chelating Aminophosphine- and Amidophosphine-phosphoramidites1.2.9 Chiral Monophosphorous Ligands; 1.3 Applications of Chiral Phosphorous Ligands in Rhodium-Catalyzed Asymmetric Hydrogenation; 1.3.1 Hydrogenation of Olefins; 1.3.1.1 Hydrogenation of Dehydroamino Acid Derivatives; 1.3.1.2 Hydrogenation of Enamides; 1.3.1.3 Asymmetric Hydrogenation of ß-(Acylamino)acrylates; 1.3.1.4 Asymmetric Hydrogenation of Enol Esters; 1.3.1.5 Asymmetric Hydrogenation of Unsaturated Acids and Esters; 1.3.2 Hydrogenation of Ketones; 1.3.2.1 Hydrogenation of Functionalized Ketones 327 $a1.3.2.2 Hydrogenation of Unfunctionalized Ketones1.3.3 Asymmetric Hydrogenation of Imines; 1.3.3.1 Acyclic N-Alkylimines; 1.3.3.2 C=N-X Substrates; 1.4 Conclusion; 1.5 References; 2 Rhodium-Catalyzed Hydroborations and Related Reactions; 2.1 Introduction; 2.2 General Advances in Catalytic Hydroboration; 2.3 Advances in Asymmetric Hydroboration; 2.3.1 Diphosphine Ligands; 2.3.2 Phosphinamine and Related Ligands; 2.3.3 Transformations of the Initial Boronate Ester; 2.4 Catalytic Diboration of Alkenes; 2.5 Summary and Conclusions; 2.6 References 327 $a3 Rhodium(I)-Catalyzed Asymmetric Addition of Organometallic Reagents to Electron-Deficient Olefins3.1 Introduction; 3.2 Addition of Organoboron Reagents to ?,?-Unsaturated Ketones; 3.3 Mechanism; 3.4 Addition of Organoboron Reagents to Other Electron-Deficient Olefins; 3.5 Addition of Organotin and -silicon Reagents; 3.6 New Aspects of Addition of Organoboron and -titanium Reagents; 3.7 Outlook; 3.8 References; 4 Recent Advances in Rhodium(I)-Catalyzed Asymmetric Olefin Isomerization and Hydroacylation Reactions; 4.1 Rhodium(I)-Catalyzed Asymmetric Isomerization of Olefins 327 $a4.1.1 Allylic Amines4.1.2 Allylic Ethers; 4.1.3 Allylic Alcohols; 4.1.4 Summary; 4.2 Rhodium(I)-Catalyzed Asymmetric Hydroacylation of Olefins and Alkynes with Aldehydes; 4.2.1 Cyclopentanones; 4.2.2 Cyclopentenones; 4.2.3 Summary; 4.3 References; 5 Stereoselective Rhodium(I)-Catalyzed Hydroformylation and Silylformylation Reactions and their Application to Organic Synthesis; 5.1 Introduction; 5.2 Hydroformylation; 5.2.1 Diastereoselective Hydroformylation of Chiral Alkene Substrates; 5.2.2 Hydroformylation of Organomercurials; 5.2.3 Directed Diastereo- and Regioselective Hydroformylation 327 $a5.2.4 Applications in Natural Product Synthesis 330 $aRhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for the dramatic increase in the number of articles that have recently emerged on the topic. P. Andrew Evans, the editor of this much-needed book, has assembled an internationally renowned team to present the first comprehensive coverage of this important area. The book features contributions 606 $aRhodium catalysts 606 $aOrganic compounds$xSynthesis 606 $aChemistry, Organic 606 $aKatalyse$2gtt 606 $aRhodium$2gtt 608 $aElectronic books. 615 0$aRhodium catalysts. 615 0$aOrganic compounds$xSynthesis. 615 0$aChemistry, Organic. 615 17$aKatalyse. 615 17$aRhodium. 676 $a547.215 701 $aEvans$b Andrew P$0319044 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144328203321 996 $aModern rhodium-catalyzed organic reactions$91935372 997 $aUNINA