LEADER 05122nam 2200649Ia 450 001 9910144327603321 005 20201210094149.0 010 $a1-282-30554-9 010 $a9786612305542 010 $a0-470-13258-2 010 $a0-470-13293-0 035 $a(CKB)1000000000376289 035 $a(EBL)469419 035 $a(OCoLC)746577015 035 $a(SSID)ssj0000299768 035 $a(PQKBManifestationID)11248731 035 $a(PQKBTitleCode)TC0000299768 035 $a(PQKBWorkID)10243645 035 $a(PQKB)11755605 035 $a(MiAaPQ)EBC469419 035 $a(PPN)243188765 035 $a(EXLCZ)991000000000376289 100 $a20750907d1990 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aInorganic syntheses$hVolume 27$b[electronic resource] /$feditor-in-chief, Alvin P. Ginsberg 210 $aNew York $cMcGraw Hill$d1990 215 $a1 online resource (463 p.) 225 0 $aInorganic syntheses ;$v27 300 $aDescription based upon print version of record. 311 $a0-471-50976-0 320 $aIncludes bibliographical references and and index. 327 $aINORGANIC SYNTHESES; CONTENTS; Chapter One TRANSITION METAL POLYHYDRIDE COMPLEXES; 1. Molecular Hydrogen Complexes of Mo and W; A. Tricarbonyl(dihydrogen)bis(tricyclohexylphosphine)-molybdenum; B. Tricarbonyl(q6-cycloheptatriene)tungsten; C. Tricarbonyl(dihydrogen)bis-(tricyclohexy1phosphine)tungsten; D. Tricarbonyl(dihydrogen)bis-(triisopropylphosphine)tungsten; 2. Molybdenum and Tungsten Phosphine Polyhydrides; A. Tetrahydridotetrakis(methyldiphenylphosphine)- molybdenum(IV); B. Tetrahydridotetrakis(methyldiphenylphosphine)- tungsten(IV) 327 $aC. Hexahydridotris(dimethylphenylphosphine)tungsten(VI)D. Hexahydridotris(tricyclohexylphosphine)molybdenum(VI); 3. Haptahydridobis(triphenylphosphine)rhenium(VII) and Octahydridotetrakis(triphenylphosphine)dirhenium(IV); A. Heptahydridobis(triphenylphosphine)rhenium(VII); B. Octahydridotetrakis(triphenylphosphine)dirhenium(IV); C. Octahydridotetrakis(triphenylphosphine)dirhenium(IV); 4. Tetrahydrido(n5-pentamethylcyclopentadienyI)iridium 327 $a5. Tris[1,3-bis(diphenylphosphino)propane]- heptahydridotriiridium(2 + ) Bis(tetrafluoroborate) and Bis[ t,3-bis(diphenylphosphino)propane]-pentahydridodiiridium( 1 + ) TetrafluotoborateA. (q-I, 5-cyclooctadiene)[1, 3-Bis(diphenylphosphino)- propane]iridium Tetrafluoroborate; B. [Ir3(dppp)3H7[BF4]2 and [Ir2(dppp)2H5][BF4]; 6. Heterobimetallic Hydride Complexes; A. mer-Trichlorotris(dimethylphenylphosphine)osmium(III); B. Bis[1, 1(q5)-Cyclopentadienyl]-tris(dimethylphenylphosphine-2kP)-tri-u-hydrido1 -hydridoosmiumzirconium 327 $aC. [2(q4)-l, 5-Cyclooctadienel-tris(dimethylphenylphosphine- 1 kP)-tri-u-hydridoosmiumrhodium7. u-Hydrido-tetrakis(tertiary phosphine)diplatinum Cations; A. u-Hydrido-dihydridotetrakis(triethylphosphine)-diplatinum(I1) Tetraphenylborate( 1 -); B. Di-u-hydrido-hydridotetrakis(triethylphosphine)-diplatinum(I1) Tetraphenylborate(1 - ); C. Di-u-hydrido-hydridotetrakis(triphenylphosphine)-diplatinum(I1) Tetraphenylborate( 1 -); Chapter Two TRANSITION METAL CHALCOGENIDE COMPLEXES; 8. Tetraphenylphosphonium Salts of [Mo2(S)n(S2)6-n]2 - Thioanions and Derivatives 327 $aA. Bis(tetraphenylphosphonium) Tetrathiomolybdate(VI), (Ph4P)2[MoS4]B. (Ph4P)2[(Mo2S10)0.72(Mo2S12)0.28]1/2HC0N(CH3)2; C. Bis(tetraphenylphosphonium) Di-u-thio-tetrathiodimolybdate(V), (Ph4P)2[MO2S6]; D. Bis(tetraphenylphosphonium) (q2-Disulfido)- di-u-thio-trithiodimolybdate(IV, VI),; E. Bis(tetraphenylphosphonium) Bis(q2-disulfido)-di-u-thio-dit hiodimoly bdate(V), (Ph4P)2 [ Mo2S8]; 9. Molybdenum-Sulfur Clusters; A. Diammonium Tris(u-disulfido)tris(disulfido)-u3-thio-rtianguto-trimolybdate(IV) Hydrate; B. Diammonium Bis(u-disulfido)tetrakis(disulfido)-dimolybdate(V) Dihydrate 327 $aC. Diammonium Tris(p-disulfido)tris(disulfido)-u3-thio- triangulo-trimolybdate(IV) Hydrate and Diammonium Bis(u-disulfido)-tetrakis(disulfido)dimolybdate(V) Dihydrate 330 $aThe volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested. 410 0$aInorganic Syntheses 606 $aInorganic compounds$xSynthesis 606 $aChemistry, Inorganic 615 0$aInorganic compounds$xSynthesis. 615 0$aChemistry, Inorganic. 676 $a541.3 676 $a541/.39 701 $aGinsberg$b Alvin P$0961463 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144327603321 996 $aInorganic syntheses$92179704 997 $aUNINA