LEADER 05336nam 2200649Ia 450 001 9910144327303321 005 20170816123325.0 010 $a1-280-51994-0 010 $a9786610519941 010 $a3-527-60548-7 010 $a3-527-60470-7 035 $a(CKB)1000000000376391 035 $a(EBL)481516 035 $a(OCoLC)85820648 035 $a(SSID)ssj0000096628 035 $a(PQKBManifestationID)11515923 035 $a(PQKBTitleCode)TC0000096628 035 $a(PQKBWorkID)10081890 035 $a(PQKB)10249626 035 $a(MiAaPQ)EBC481516 035 $a(EXLCZ)991000000000376391 100 $a20040624d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAcetylene chemistry$b[electronic resource] $echemistry, biology, and material science /$fedited by F. Diederich, P.J. Stang, R.R. Tykwinski 210 $aWeinheim $cWiley-VCH$dc2005 215 $a1 online resource (530 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30781-8 320 $aIncludes bibliographical references and index. 327 $aAcetylene Chemistry; Preface; Contents; Symbols and Abbreviations; List of Contributors; 1 Theoretical Studies on Acetylenic Scaffolds; 1.1 Introduction; 1.2 Linear Acetylenic Scaffolds; 1.2.1 The Dicarbon Molecule and Acetylene; 1.2.2 Uncapped Pure sp Carbon Chains; 1.2.3 Capped All-sp Oligoacetylenic Chains; 1.2.4 Hybrid sp-sp(2) Oligoacetylenic Molecules; 1.2.5 Hybrid sp-sp(3) Oligoacetylenic Molecules; 1.3 Cyclic Acetylenic Scaffolds; 1.3.1 Hybrid sp-sp(3) Rings; 1.3.2 Hybrid sp-sp(2) Rings (Dehydroannulenes); 1.3.3 carbo-Heteroannulenes; 1.4 Star-Shaped Acetylenic Scaffolds 327 $a1.4.1 Atomic Cores1.4.2 Rod Cores; 1.4.3 Cyclic Cores; 1.5 Cage Acetylenic Scaffolds; 1.6 Conclusion; Acknowledgements; 2 Synthesis of Heterocycles and Carbocycles by Electrophilic Cyclization of Alkynes; 2.1 Introduction; 2.2 Cyclization of Oxygen Compounds; 2.2.1 Cyclization of Acetylenic Alcohols; 2.2.2 Cyclization of Acetylenic Phenols; 2.2.3 Cyclization of Acetylenic Ethers; 2.2.4 Cyclization of Acetylenic Acids and Derivatives; 2.2.5 Cyclization of Acetylenic Aldehydes and Ketones; 2.3 Cyclization of Sulfur and Selenium Compounds; 2.4 Cyclization of Nitrogen Compounds 327 $a2.4.1 Cyclization of Acetylenic Amines2.4.2 Cyclization of Acetylenic Amides; 2.4.3 Cyclization of Acetylenic Carbamates; 2.4.4 Cyclization of Acetylenic Sulfonamides; 2.4.5 Cyclization of Acetylenic Enamines and Imines; 2.4.6 Cyclization of Other Acetylenic Nitrogen Functional Groups; 2.5 Cyclization of Carbon onto Acetylenes; 2.5.1 Cyclization of Acetylenic Carbonyl Compounds and Derivatives; 2.5.2 Cyclization of Diacetylenes; 2.5.3 Cyclization of Aryl Acetylenes; 2.5.4 Cyclization of Acetylenic Organometallics; 2.6 Conclusions; 2.7 Representative Experimental Procedures 327 $a2.7.1 Synthesis of ?-Methylene-?-butyrolactones by Carbonylation of 1-Alkyn-4-ols2.7.2 Synthesis of 1-Alkoxyisochromenes by Cyclization of 2-(1-Alkynyl)benzaldehydes; 2.7.3 Synthesis of 3-Aryl(vinylic)indoles by Palladium-catalyzed Cross-coupling of Aryl Halides or Vinylic Triflates and 2-(1-Alkynyl)trifluoroacetanilides; 2.7.4 Synthesis of Pyridines by the Gold-catalyzed Cross-coupling of Ketones and Propargyl Amine; 2.7.5 Synthesis of 4-Iodoisoquinolines by the Cyclization of Iminoalkynes; 2.7.6 Synthesis of Cyclic Amines by Acetylene-Iminium Ion Cyclizations; Acknowledgements 327 $a3 Addition of Terminal Acetylides to CO and CN Electrophiles3.1 Introduction; 3.2 Background; 3.3 Additions with Stoichiometric Amounts of Metal Acetylides; 3.4 Nucleophilic CO Additions involving the Use of Zn(II) Salts; 3.5 Acetylene Additions to CN Electrophiles; 3.6 Conclusion; 3.7 Experimental Procedures; 3.7.1 General Procedure for the Enantioselective Alkynylation of Aldehydes by the Use of Stoichiometric Amounts of Zn(OTf)(2); 3.7.2 General Procedure for the Zn(OTf)(2)-Catalyzed Enantioselective Alkynylation of Aldehydes 327 $a3.7.3 General Procedure for the Enantioselective Alkynylation of Ketones Catalyzed by Zn(salen) Complexes 330 $aAcetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental proced 606 $aAcetylene 606 $aAlkynes 608 $aElectronic books. 615 0$aAcetylene. 615 0$aAlkynes. 676 $a547.413 686 $a35.68$2bcl 701 $aDiederich$b Franc?ois$0543126 701 $aStang$b Peter J$0978681 701 $aTykwinski$b R. R$g(Rik R.)$0951563 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144327303321 996 $aAcetylene chemistry$92230627 997 $aUNINA