LEADER 01578nlm0 2200325 450 001 000029711 005 20141030114518.0 100 $a20131202d2011----km-y0itay50------ba 101 0 $aita 102 $aIT 105 $ay---m---001yy 200 1 $a<>federalismo fiscale ex lege n.42/09$eil caso della spesa sanitaria$brisorsa elettronica$ftesi di dottorato di: Nicola Chiacchio$gtutor: Raffaele Fiume 210 $aNapoli$d2011 215 $a1 disco ottico (CD-ROM)$d12 cm 230 $aDati testuali (1 file: 2,8 Mb) 304 $aTit. dell'etichetta 314 $aCoordinatore: Mariano D\2019Amore 328 $aTesi di Dottorato di ricerca in Economia e Regolazione delle Aziende e delle Amministrazioni Pubbliche, 2009-2010 (23. ciclo) : Università degli studi di Napoli "Parthenope". 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Italia 700 1$aChiacchio,$bNicola$0634318 712 02$aUniversità degli Studi di Napoli "Parthenope" 801 0$aIT$bUNIPARTHENOPE$c20131202$gRICA$2UNIMARC 912 $a000029711 951 $aTESI Dottorato CD-ROM/71$bs.i.$cNAVA1$d2013 996 $aFederalismo fiscale ex lege n.42$940395 997 $aUNIPARTHENOPE LEADER 05190nam 2200613Ia 450 001 9910144322703321 005 20180504131653.0 010 $a1-280-72273-8 010 $a9786610722730 010 $a3-527-60786-2 010 $a3-527-60748-X 035 $a(CKB)1000000000376402 035 $a(EBL)482387 035 $a(OCoLC)77602103 035 $a(SSID)ssj0000108286 035 $a(PQKBManifestationID)11745619 035 $a(PQKBTitleCode)TC0000108286 035 $a(PQKBWorkID)10016656 035 $a(PQKB)11566892 035 $a(MiAaPQ)EBC482387 035 $a(EXLCZ)991000000000376402 100 $a20050523d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAziridines and epoxides in organic synthesis$b[electronic resource] /$fedited by Andrei K. Yudin 210 $aWeinheim ;$aChichester $cWiley$d2006 215 $a1 online resource (516 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31213-7 320 $aIncludes bibliographical references and index. 327 $aAziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation 327 $a1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 327 $a1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of ?,?-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 327 $a2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 327 $a3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of ?-Halo- and ?-Sulfonyloxy-?-amino Esters and Amides; 3.2.1.4 Aziridination of ?,?-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 327 $a3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates 330 $aAziridines and epoxides are among the most widely used intermediates in organic synthesis, acting as precursors to complex molecules due to the strains incorporated in their skeletons. Besides their importance as reactive intermediates, many biologically active compounds also contain these three-membered rings.Filling a gap in the literature, this clearly structured book presents the much needed information in a compact and concise way. The renowned editor has succeeded in gathering together excellent authors to cover synthesis, applications, and the biological aspects in equal depth.D 606 $aEpoxy compounds 606 $aOrganic compounds$xSynthesis 608 $aElectronic books. 615 0$aEpoxy compounds. 615 0$aOrganic compounds$xSynthesis. 676 $a547.2 701 $aYudin$b Andrei K$0888198 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144322703321 996 $aAziridines and epoxides in organic synthesis$91984064 997 $aUNINA