LEADER 05522nam 2200661Ia 450 001 9910144322203321 005 20170815114114.0 010 $a1-282-30808-4 010 $a9786612308086 010 $a0-470-14524-2 010 $a0-470-14545-5 035 $a(CKB)1000000000376304 035 $a(EBL)468908 035 $a(OCoLC)746577094 035 $a(SSID)ssj0000299749 035 $a(PQKBManifestationID)11212862 035 $a(PQKBTitleCode)TC0000299749 035 $a(PQKBWorkID)10243469 035 $a(PQKB)11307601 035 $a(MiAaPQ)EBC468908 035 $a(EXLCZ)991000000000376304 100 $a19880519d1989 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aFormation of bonds to C, Si, Ge, Sn, Pb$hPart 2$b[electronic resource] /$ffounding editor, J.J. Zuckerman ; editor, A.P. Hagen 210 $aNew York, N.Y. $cVCH$dc1989 215 $a1 online resource (541 p.) 225 0 $aInorganic reactions and methods ;$v10/2 300 $aDescription based upon print version of record. 311 $a0-471-18661-9 320 $aIncludes bibliographical references and indexes. 327 $aInorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 10; The Formation of Bonds to the Group-IVB Elements (C, Si, Ge, Sn, Pb) (Part 2); Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group IllB (B, Al, Ga, In, TI); Introduction; Formation of Carbon-Boron Bonds; Industrial Preparation of Boron Carbide.; Industrial Preparation of Boron-Carbide Powders.; Densification of Powders.; Laboratory Preparation of Boron Carbide (from the Elements or Boron Halides) 327 $aby Direct Synthesis.by Reduction of BCI3 by H2 in the Presence of Carbon.; by Chemical Vapor Deposition (CVD).; by Reduction of Boric Anhydride at Low Temperatures.; by Plasma Synthesis.; by Physical Vapor Deposition (PVD).; Crystal Growth.; Boron Carbide Fibers.; from Boron Halides; by Reaction with More Polar Organometallics (Metal-Metal Exchange, Excluding Amino-, Oxo- and Thioboron Halides).; by Reaction with an Organoboron-Active-Metal Reagent.; by Substitution of Hydrocarbons.; by Addition to Olefinic and Acetylenic Linkages (Haloboration).; by Reaction with Diazoalkanes. 327 $aby Redistribution Reactions with Organoboranes.from Boron Alkoxides with More Polar Organometallics; Alkyl- and Arylboronic Acids.; Alkyl- and Arylborinic Acids.; to form Organoboranes with Three B-C Bonds.; from Boron Hyrides; by Addition to Olefins and Acetylenes (Hydroboration).; by Addition to Polar Organometallics to Form Organoborates.; by Redistribution of Organoboron Hydrides.; from Organoboranes; by Redistribution.; by lsomerization and Displacement.; by Pyrolytic Elimination of H2.; by Addition of Olefinic and Acetylenic Linkages (Carboboration).; from Larger Boranes and Carboranes 327 $aby Hydroboration of a Polyborane.by Modified Metal Halide-Catalyzed Alkylations with Organic Halides at a Boron Site.; by B,B Addition of Polyboranes to Alkynes.; by Boron Hydrides with Acetylides, Cyanides, or lsocyanides.; by CO Displacements from Polyboranes.; by Other Reactions Using Polyboranes.; Formation of Carbon-Al Bonds; from the Elements; from Al Metal and Its Alloys; by the Interaction of H2 Olefin and Al Metal.; by the Action of Organic Halides on Al.; by the Reaction of Organomercurials with Al.; from Al Halides or Organoaluminum Halides; by Reaction with Polar Organometallics. 327 $aby Redistribution with Organoaluminums.by the Interaction with an Active-Metal Hydride and Olefin.; by the Dehalogenation of RnAIX3- n with Active Metals.; from Al Hydrides or Complex Al Hydrides; by Addition to Olefins or Acetylenes (Hydroalumination).; by Transfer of Al Hydride from One Olefin to Another-Al Alkyl-Olefin Displacement.; by Redistribution with Organoaluminums.; by Exchange with Other Organometallics.; from Other Organoaluminum Compounds; by Addition of R-AI Bonds to Olefins or Acetylenes (Carbalumination). 327 $aby Substitution of Acidic Carbon-Hydrogen Bonds by Carbon-Al Bonds (Alumination). 330 $aFor the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulne 410 0$aInorganic Reactions and Methods 606 $aChemical kinetics$xEffect of temperature on 606 $aInorganic compounds$xSynthesis 608 $aElectronic books. 615 0$aChemical kinetics$xEffect of temperature on. 615 0$aInorganic compounds$xSynthesis. 676 $a541.3/9 676 $a541.39 701 $aZuckerman$b J. J$g(Jerold J.),$f1936-1987.$0857123 701 $aHagen$b A. P$0857124 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144322203321 996 $aFormation of bonds to C, Si, Ge, Sn, Pb$91913939 997 $aUNINA