LEADER 05276nam 2200673Ia 450 001 9910144319803321 005 20170822135102.0 010 $a1-280-72285-1 010 $a9786610722853 010 $a3-527-60935-0 010 $a3-527-60937-7 035 $a(CKB)1000000000376262 035 $a(EBL)482339 035 $a(OCoLC)77601568 035 $a(SSID)ssj0000096889 035 $a(PQKBManifestationID)11121969 035 $a(PQKBTitleCode)TC0000096889 035 $a(PQKBWorkID)10112652 035 $a(PQKB)10307487 035 $a(MiAaPQ)EBC482339 035 $a(EXLCZ)991000000000376262 100 $a20061017d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aActivation of small molecules$b[electronic resource] $eorganometallic and bioinorganic perspectives /$fedited by William B. Tolman 210 $aWeinheim $cWiley-VCH$dc2006 215 $a1 online resource (383 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31312-5 320 $aIncludes bibliographical references and index. 327 $aActivation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts 327 $a1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 327 $a2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (?(1)-?(2)-) Complexes; 2.2.1.3 ?(1)-?(3)-NO Bridging Complexes; 2.2.1.4 ?(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on ?(2)-NO Complexes; 2.2.1.6 Side-on ?(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 327 $a2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 327 $a2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 327 $a3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten 330 $aThe first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field. 606 $aMolecules 606 $aIons 606 $aInorganic compounds 606 $aInorganic compounds$xSynthesis 608 $aElectronic books. 615 0$aMolecules. 615 0$aIons. 615 0$aInorganic compounds. 615 0$aInorganic compounds$xSynthesis. 676 $a541.22 686 $a35.60$2bcl 701 $aTolman$b William B$0911720 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144319803321 996 $aActivation of small molecules$92041682 997 $aUNINA