LEADER 05370nam 2200685 a 450 001 9910144299903321 005 20170810192827.0 010 $a1-280-27141-8 010 $a9786610271412 010 $a0-470-34184-X 010 $a0-470-86201-7 010 $a0-470-86200-9 035 $a(CKB)1000000000376375 035 $a(EBL)470087 035 $a(SSID)ssj0000201628 035 $a(PQKBManifestationID)11182306 035 $a(PQKBTitleCode)TC0000201628 035 $a(PQKBWorkID)10245674 035 $a(PQKB)10405943 035 $a(MiAaPQ)EBC470087 035 $a(OCoLC)85820699 035 $a(EXLCZ)991000000000376375 100 $a20050413d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMetal catalysed carbon-carbon bond-forming reactions$b[electronic resource] /$fedited by Stanley M. Roberts ... [et al.] 210 $aChichester, West Sussex, England ;$aHoboken, N.J. $cJohn Wiley$dc2004 215 $a1 online resource (282 p.) 225 1 $aCatalysts for fine chemical synthesis ;$vv. 3 300 $aDescription based upon print version of record. 311 $a0-470-86199-1 320 $aIncludes bibliographical references and index. 327 $aCatalysts for Fine Chemical Synthesis Volume 3; Contents; Series Preface; Preface to Volume 3; Abbreviations; List of Chemical Names Used; 1 Considerations of Industrial Fine Chemical Synthesis; 1.1 Introduction; 1.2 Types of processes - flow charts; 1.2.1 Classical process; 1.2.2 General catalytic process; 1.3 Costs associated with use of catalysts; 1.3.1 Catalyst fabrication costs; 1.3.2 Intellectual property right (IPR) issues; 1.3.3 Separation costs; 1.3.4 Pre-reaction/immobilisation; 1.3.5 Post reaction - separation; 1.3.6 Industrial examples; References 327 $a2 Alkylation and Allylation Adjacent to a Carbonyl Group2.1 The RuH(2)(CO)(PPh(3))(3)-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage; 2.1.1 Preparation of carbonyldihydrotris(triphenylphosphine) ruthenium; 2.1.2 Synthesis of 8-(2-triethoxysilanylethyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.3 Synthesis of 8-(1-methyl-2-trimethylsilanylvinyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.4 Synthesis of 1-biphenyl-2-yl-2,2-dimethylpropan-1-one; 2.1.5 Conclusion; References 327 $a2.2 Catalytic, asymmetric synthesis of a,a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst2.2.1 Synthesis of (chsalen); 2.2.2 Synthesis of copper(II) (chsalen); 2.2.3 Alkylation of alanine methyl ester Schiff base by chiral salen-metal catalysts, a-benzyl-alanine methyl ester; 2.2.4 Conclusion; References; 2.3 Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts 327 $a2.3.1 Synthesis of (1S,2S,4S,5R,1 ?R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide2.3.2 Synthesis of (1S,2S,4S,5R,1 ?R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[benzyloxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide; 2.3.3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate; 2.3.4 Conclusion; References; 3 Asymmetric Alkylation or Amination of Allylic Esters; 3.1 Synthesis and application in palladium-catalysed asymmetric allylic substitution of enantiopure cyclic b-iminophosphine ligands 327 $a3.1.1 Synthesis of (2,6-dimethyl-phenyl)-(1-phenyl-2,3,3a,8a-tetrahydro-1H-1-phospha-cyclopenta[a]inden-8-ylidene)-amines 1R(p)3.1.2 Synthesis of (E)-Methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate; 3.1.3 Synthesis of benzyl(1,3-diphenylprop-2-enyl)amine; 3.1.4 Conclusion; References; 3.2 (9H,9 ?H,10H,10 ?H,11H,11H ?,13H,13 ?H,14H,14 ?H,15H,15 ?H-perfluorotricosane-12,12 ?-diyl)bis[(4S)-4-phenyl-2-oxazoline as a ligand for asymmetric palladium-catalysed alkylation of allylic acetates in fluorous media; 3.2.1 Synthesis of 2-iodo-1-(1H,1 ?H,2H,2 ?H,3H,3 ?H-perfluorooctyl)-3-propanol 327 $a3.2.2 Synthesis of 3-(1H,1 ?H,2H,2 ?H,3H,3 ?H-perfluorooctyl)-1-propanol 330 $aThe chemist has a vast range of high-tech catalysts to use when working in fine chemical synthesis but the catalysts are generally hard to use and require both time, skill and experience to handle properly. The Catalysts for Fine Chemical Synthesis series contains tested and validated procedures which provide a unique range resources for chemists who work in organic chemistry. ""... of great value to synthetic organic chemists..."" (The Chemists, Summer 2003) Volume 3 in the series focuses on catalysts for carbon-carbon bond formation and presents practical and detailed prot 410 0$aCatalysts for fine chemical synthesis ;$vv. 3. 606 $aOrganic compounds$xSynthesis 606 $aMetal catalysts 606 $aChemical bonds 615 0$aOrganic compounds$xSynthesis. 615 0$aMetal catalysts. 615 0$aChemical bonds. 676 $a660 676 $a660.28443 676 $a660.2995 701 $aRoberts$b Stanley M$0754844 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144299903321 996 $aMetal catalysed carbon-carbon bond-forming reactions$92248136 997 $aUNINA