LEADER 03045nam 2200565Ia 450 001 9910144298203321 005 20170816123146.0 010 $a1-280-52080-9 010 $a9786610520800 010 $a3-527-60377-8 010 $a3-527-60592-4 035 $a(CKB)1000000000376380 035 $a(EBL)482353 035 $a(OCoLC)69157038 035 $a(SSID)ssj0000246017 035 $a(PQKBManifestationID)11174066 035 $a(PQKBTitleCode)TC0000246017 035 $a(PQKBWorkID)10189190 035 $a(PQKB)10840205 035 $a(MiAaPQ)EBC482353 035 $a(EXLCZ)991000000000376380 100 $a20041110d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSilicon-mediated transformations of functional groups$b[electronic resource] /$fHelmut Vorbru?ggen 210 $aWeinheim $cWiley-VCH$dc2004 215 $a1 online resource (378 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30668-4 320 $aIncludes bibliographical references and indexes. 327 $aSilicon-mediated Transformations of Functional Groups; Contents; Preface; 1 Introduction; 2 Techniques for Preparative Silylations-Desilylations; 3 Preparation and Properties of Silyloxy Leaving Groups; 4 Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide; 5 Reactions of Aldehydes and Ketones; 6 Reactions of Alcohols, Esters, Silyl Ethers, Epoxides, and Haloalkanes; 7 Reactions of N-O Systems; 8 Reactions of S-O and Se-O Systems; 9 Cyclizations and Ring Enlargements; 10 Base-catalyzed, Acid-catalyzed and Thermal Eliminations of Trimethylsilanol. Peterson Reactions 327 $a11 Formation of Carbon-Phosphorus Double Bonds12 Reductions and Oxidations; 13 Dehydration-Halogenation-Activation and Silylation of Inorganic and Organic Salts and Metallorganic Compounds; 14 Formation of Organic and Inorganic Polymers; Appendix; Subject Index; Author Index 330 $aIn the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbr?ggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathwayswhile effecting the elimination of water in it 606 $aFunctional groups 606 $aSilicon 608 $aElectronic books. 615 0$aFunctional groups. 615 0$aSilicon. 676 $a547.2 700 $aVorbru?ggen$b Helmut$0497308 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144298203321 996 $aSilicon-mediated transformations of functional groups$92181938 997 $aUNINA