LEADER 05189nam 2200613 a 450 001 9910144297003321 005 20170814190235.0 010 $a1-280-51992-4 010 $a9786610519927 010 $a3-527-60396-4 010 $a3-527-60463-4 035 $a(CKB)1000000000376384 035 $a(EBL)481653 035 $a(OCoLC)68660227 035 $a(SSID)ssj0000204298 035 $a(PQKBManifestationID)11168567 035 $a(PQKBTitleCode)TC0000204298 035 $a(PQKBWorkID)10187899 035 $a(PQKB)10362694 035 $a(MiAaPQ)EBC481653 035 $a(EXLCZ)991000000000376384 100 $a20041022d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aModern cyclophane chemistry$b[electronic resource] /$fRolf Gleiter, Henning Hopf, eds 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley]$dc2004 215 $a1 online resource (588 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30713-3 320 $aIncludes bibliographical references and index. 327 $aModern Cyclophane Chemistry; Contents; Preface; List of Contributors; 1 Cyclophynes; 1.1 Introduction; 1.2 Orthocyclophynes and Related Systems; 1.2.1 Planar Dehydrobenzoannulenes; 1.2.2 Nonplanar Orthocyclophynes; 1.3 Metacyclophynes and Related Systems; 1.4 Paracyclophynes and 1,3,5-Bridged Cyclophynes; 1.5 Concluding Remarks; 1.6 Acknowledgement; 1.7 References; 2 Hetera (Cyclo-)phanes; 2.1 Introduction; 2.1.1 Selection of Topics Presented; 2.1.2 Definitions; 2.1.3 Why Conduct a Survey on Heteraphanes?; 2.2 Heteraphanes; 2.2.1 Planar Chiral and Helical Chiral Phanes 327 $a2.2.1.1 Design of Phanes with Planar and Helical Chirality2.2.1.2 Hetera [2.2]Metacyclophanes; 2.2.1.3 Planar Chiral [2.2]Metacyclophanes; 2.2.1.4 Planar Chiral Hetera [n]Para- and Hetera [n]Metacyclophanes; 2.2.1.5 Dioxa [2.2]Phanes and Oxaza [2.2]Phanes; 2.2.1.6 Enantiomer Separations; 2.2.1.7 Strongly Helical Heteraphanes; 2.2.2 Catenanes, Rotaxanes, and Knotanes of the Heteraphane Type; 2.2.2.1 Template Synthesis of Rotaxanes Using Cyclophane Wheels; 2.2.2.2 Higher Order [n]Rotaxanes via Non-ionic Template Effect; 2.2.2.3 Combination of Anionic and Non-ionic Template 327 $a2.2.2.4 Molecular Knots and Similar Macrocycles of the Heteraphane Type2.2.3 Further Heteraphanes, Metallaphanes and Supramolecular Phanes; 2.3 Conclusions; 2.4 Acknowledgement; 2.5 References; 3 Highly Strained Cyclophanes; 3.1 Introduction; 3.2 [n]Metacyclophanes; 3.2.1 Synthesis; 3.2.2 Structures and Physical Properties; 3.2.3 Reactions of Strained [n]Metacyclophanes; 3.2.3.1 Thermal and Photochemical Reactions; 3.2.3.2 Addition Reactions; 3.2.3.3 Reactions with Electrophiles; 3.2.3.4 Reactions with Nucleophiles; 3.3 [n]Paracyclophanes; 3.3.1 Synthesis 327 $a3.3.2 Structures and Physical Properties3.3.3 Reactions of Strained [n]Paracyclophanes; 3.3.3.1 Thermal and Photochemical Reactions; 3.3.3.2 Reactions with Electrophiles; 3.3.3.3 Diels-Alder and Other Reactions; 3.3.3.4 Kinetic Stabilization of [4]Paracyclophane Systems; 3.4 Aromaticity of Bent Benzene Rings; 3.5 Cyclophanes containing Polycyclic Aromatic Rings: (2,7)Pyrenophanes; 3.6 [1.1]Paracyclophanes; 3.6.1 Synthesis; 3.6.2 Kinetic Stabilization of [1.1]Paracyclophane Systems; 3.6.3 Structures and Physical Properties; 3.7 References and Notes; 4 Superphanes; 4.1 Introduction 327 $a4.2 [n(2)]Cyclopropenonophanes4.2.1 Synthesis; 4.3 Superbridged Cyclopropenyliophanes; 4.4 C(4)-Superphanes; 4.4.1 Properties of Cyclobutadieno Superphanes; 4.4.2 Oxidative Demetallations; 4.5 C(5)-Superphanes; 4.6 Superbridged Benzene Rings; 4.7 Concluding Remarks; 4.8 Acknowledgement; 4.9 References; 5 Carbon-Bridged Ferrocenophanes; 5.1 Introduction; 5.2 Nomenclature; 5.3 Mononuclear Carbon-Bridged Ferrocenophanes; 5.3.1 [1]Ferrocenophanes; 5.3.2 [2]Ferrocenophanes; 5.3.3 [3]Ferrocenophanes; 5.3.4 [4]Ferrocenophanes; 5.3.5 [5]Ferrocenophanes; 5.3.6 [m]Ferrocenophanes (m>5) 327 $a5.3.7 Multiply-Bridged Mononuclear Ferrocenophanes ([m](n)Ferrocenophanes) 330 $aHere, the editors Rolf Gleiter and Henning Hopf present an excellent overview of all the important aspects and latest results in cyclophane chemistry. Clearly structured and covering the entire range, the book introduces readers to the most recent research in the field. Twenty chapters, written by well-known scientists, cover in particular:- synthesis of carbo- and heterocyclic cyclophanes and metallocenophanes,- structural and spectroscopic properties of cyclophanes,- current and future applications in synthesis and material science,- novel reactions of cyclophanes,- use o 606 $aCyclophanes 608 $aElectronic books. 615 0$aCyclophanes. 676 $a547.59 676 $a547/.59 701 $aGleiter$b Rolf$f1936-$0924945 701 $aHopf$b Henning$f1940-$0924946 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144297003321 996 $aModern cyclophane chemistry$92075992 997 $aUNINA