LEADER 05427nam 2200661Ia 450 001 9910144282503321 005 20170810191449.0 010 $a1-281-76423-X 010 $a9786611764234 010 $a3-527-61368-4 010 $a3-527-61369-2 035 $a(CKB)1000000000376613 035 $a(EBL)481702 035 $a(OCoLC)261224407 035 $a(SSID)ssj0000120477 035 $a(PQKBManifestationID)11130256 035 $a(PQKBTitleCode)TC0000120477 035 $a(PQKBWorkID)10081533 035 $a(PQKB)10312838 035 $a(MiAaPQ)EBC481702 035 $a(EXLCZ)991000000000376613 100 $a20020620d1999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aChemical synthesis using supercritical fluids$b[electronic resource] /$fedited by Philip G. Jessop and Walter Leitner 210 $aWeinheim ;$aNew York $cWiley-VCH$dc1999 215 $a1 online resource (503 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29605-0 320 $aIncludes bibliographical references and index. 327 $aChemical Synthesis Using Supercritical Fluids; Preface; Contents; Contents; List of Contributors; 1 Introduction; 1.1 Supercritical Fluids as Media for Chemical Reactions; 1.1.1 What is a Supercritical Fluid (SCF)?; 1.1.2 Practical Aspects of Reactions in Supercritical Fluids (SFRs); 1.1.3 Motivation for Use of SCFs in Modern Chemical Synthesis; 1.1.4 A Brief History of Chemical Synthesis in SCFs; 1.1.4.1 Discovery of SCFs and their Use as Solvents; 1.1.4.2 Early Examples of Chemical Reactions in SCFs; 1.1.4.3 Industrial Use of SCFs as Reaction Media; References 327 $a1.2 Phase Behavior and Solubility1.2.1 Basic Physical Properties of Supercritical Fluids; 1.2.2 Phase Behavior in High Pressure Systems; 1.2.2.1 Types of Binary Phase Diagrams; 1.2.2.2 Asymmetric Binary Mixtures; 1.2.3 Factors Affecting Solubility in Supercritical Fluids; 1.2.3.1 SCF Solvent; 1.2.3.2 Chemical Functionality of the Solute; 1.2.3.3 Temperature and Pressure Effects; References; 1.3 Physical Properties as Related to Chemical Reactions; 1.3.1 Behavior of Diffusion Coefficients; 1.3.2 Diffusional Effects on Reactions; 1.3.3 Transition-state Theory Applied to SCFs 327 $a1.3.4 Density Dependence of Two Competing Reactions1.3.5 Solvation Effects on Reactions; 1.3.6 Conclusions; References; 2 Experimental Techniques; 2.1 High-pressure Reaction Equipment Design; 2.1.1 Introduction; 2.1.2 Basic Equipment and Components; 2.1.2.1 Design of Thick-Walled Vessels; 2.1.2.2 Closures and Connectors; 2.1.2.3 Tubing and Fittings; 2.1.2.4 Valves; 2.1.2.5 Compressors and Pumps; 2.1.2.6 Stirring and Mixing; 2.1.2.7 Optical Windows; 2.1.3 High Pressure Systems; 2.1.3.1 Single-batch High-pressure Reactors; 2.1.3.2 View Cells; 2.1.3.3 Systems for Continuous Processing 327 $a2.1.4 SummaryReferences; 2.2 Extraction and Related Separation Techniques; 2.2.1 General Aspects of Supercritical Fluids as Mass Separating Agents; 2.2.2 Extraction from Solids; 2.2.2.1 Basic Process Design; 2.2.2.2 Process Parameters; 2.2.2.3 Modeling the Extraction; 2.2.2.4 Solids in Multiple Stages and Countercurrent Operation in SFE; 2.2.2.5 Continuous Extraction of Contaminated Soil with Supercritical Water; 2.2.3 Countercurrent Multistage Extraction; 2.2.3.1 Basic Process Design; 2.2.3.2 Phase Equilibria; 2.2.3.3 Separation Analysis with Respect to Theoretical Stages 327 $a2.2.3.4 Multicomponent Process Simulation2.2.3.5 Determination of the Height (Length) of a Theoretical Stage; 2.2.3.6 Determination of Column Diameter; 2.2.4 Chromatographic Separation with Supercritical Fluids; 2.2.4.1 Design of SFC Apparatus; 2.2.4.2 Methods for Scale-up of Chromatography; 2.2.5 Conclusion; References; 2.3 Precipitation and Crystallization Techniques; 2.3.1 Introduction; 2.3.2 Thermodynamics and Phase Equilibria; 2.3.2.1 CSS, PGSS and RESS; 2.3.2.2 GASP; 2.3.3 Process Basics and Reference Schemes; 2.3.3.1 Crystallization from a Supercritical Solution (CSS) 327 $a2.3.3.2 Formation of Particles from Gas Saturated Solution (PGSS) 330 $aFor 'better solutions' - this practical guide describes how to take advantage of supercritical fluids in chemical synthesis. Well-established in extractions and materials processing, supercritical fluids are becoming increasingly popular as media for modern chemical syntheses. Historically, the application of compressed gases has been restricted mainly to the production of bulk chemicals. In the last decade, however, research has turned to exploiting the unique properties of supercritical fluids for the synthesis of fine chemicals and specialized materials. Now that the necessary equipment is 606 $aHigh pressure chemistry 606 $aOrganic compounds$xSynthesis 606 $aSupercritical fluids 608 $aElectronic books. 615 0$aHigh pressure chemistry. 615 0$aOrganic compounds$xSynthesis. 615 0$aSupercritical fluids. 676 $a541.3 676 $a541.39 701 $aJessop$b Philip G$0968944 701 $aLeitner$b Walter$0968945 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144282503321 996 $aChemical synthesis using supercritical fluids$92201341 997 $aUNINA LEADER 02163nam 2200493 450 001 9910780584003321 005 20230627032539.0 010 $a9781628944846$b(electronic bk.) 010 $z9781628944822 035 $a(MiAaPQ)EBC30296639 035 $a(Au-PeEL)EBL30296639 035 $a(CKB)25791622800041 035 $a(EXLCZ)9925791622800041 100 $a20230627d2022 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aDemian $ethe story of Emil Sinclair's youth /$fHermann Hesse ; translated by Thomas Wayne 205 $a1st ed. 210 1$aNew York, NY :$cAlgora Publishing,$d[2022] 210 4$dİ2022 215 $a1 online resource (142 pages) 311 08$aPrint version: Wayne, Thomas Demian New York : Algora Publishing,c2022 9781628944822 327 $aIntro -- Blank Page -- Blank Page. 330 $aThe accepted chronology of ancient Egypt, Persia and Babylonia is wrong to a dramatic degree, with some major historical events mis-dated by several centuries. Modern Egyptologists tell us that Seti I and Ramses II reigned 700 years before the rise of the Medes and Persians, but Emmet Sweeney marshals archeological and linguistic evidence to show that Ramses II's dynasty was terminated by the Persian Conquest of Egypt (525 BC). Matching events, matching biographies, and matching cultural artifacts identify Seti II, hailed by the Egyptians as a warrior and hero, with Inaros, the Egyptian patriot who waged war against Xerxes and was eventually impaled on the orders of Artaxerxes I. 606 $aSocial history 606 $aYoung men 606 $aSelf-consciousness (Awareness) 608 $aBildungsromans.$2lcgft 608 $aNovels.$2lcgft 615 0$aSocial history. 615 0$aYoung men. 615 0$aSelf-consciousness (Awareness) 676 $a833.912 700 $aHesse$b Hermann$f1877-1962,$0131876 702 $aWayne$b Thomas 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 912 $a9910780584003321 996 $aDemian$978449 997 $aUNINA