LEADER 05451nam 2200709Ia 450 001 9910144282303321 005 20170810191449.0 010 $a1-281-76424-8 010 $a9786611764241 010 $a3-527-61372-2 010 $a3-527-61373-0 035 $a(CKB)1000000000376614 035 $a(EBL)481590 035 $a(OCoLC)261224449 035 $a(SSID)ssj0000204819 035 $a(PQKBManifestationID)11189502 035 $a(PQKBTitleCode)TC0000204819 035 $a(PQKBWorkID)10193271 035 $a(PQKB)10589462 035 $a(MiAaPQ)EBC481590 035 $a(EXLCZ)991000000000376614 100 $a19991124d1999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMolecular catenanes, rotaxanes and knots$b[electronic resource] $ea journey through the world of molecular topology /$fedited by J.-P. Sauvage and C. Dietrich-Buchecker 210 $aWeinheim ;$aNew York $cWiley-VCH$dc1999 215 $a1 online resource (384 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29572-0 320 $aIncludes bibliographical references and index. 327 $aMolecular Catenanes, Rotaxanes and Knots; Contents; 1 Chemical Topology - Statistical Musings; 1.1 Catenanes; 1.2 Olefin Metathesis; 1.3 Knots; References; 2 A Knot Theoretic Approach to Molecular Chirality; 2.1 Topological Chirality of Knots and Links; 2.2 Topological Chirality of Embedded Graphs; 2.3 Topological Chirality of Molecular Knots and Links; 2.4 Topological Chirality of Molecular Cell Complexes; 2.5 Molecular Mo?bius Ladders and Related Molecules; 2.6 Using Automorphisms to Prove Intrinsic Chirality; References 327 $a3 Soft and Hard Molecule-Based Magnets with a Fully Interlocked Three-Dimensional Structure3.1 Introduction; 3.2 Molecular Magnetism; 3.3 Magnetic Bricks; 3.4 A Game of Bricks and Pieces of Mortar; 3.5 Structure of Molecule-Based Magnets Containing Three Spin Carriers, with a Fully Interlocked Structure; 3.6 Magnetic Properties; 3.6.1 The Temperature Dependence of Magnetic Susceptibility; 3.6.2 Field Dependencies of the Magnetization; 3.7 Some Further Considerations; 3.8 A Few Words to Conclude; References; 4 Transition Metal-Incorporating Catenanes; 4.1 Introduction 327 $a4.2 Interlocked Compounds Containing Metals4.2.1 Metal-Containing Rotaxanes; 4.2.2 Metal-Templated Synthesis of Catenanes; 4.2.3 Organometallic Catenanes and Rotaxanes; 4.2.4 Self-Assembly of a [2]Catenane Incorporating (en)Pd(II) Units; 4.2.4.1 Quantitative Self-Assembly of a Coordination Catenane; 4.2.4.2 Mechanism of the Rapid Interconversion: Mo?bius Strip Mechanism; 4.2.4.3 Irreversible Interlock of Molecular Rings; 4.2.4.4 Electronic Effects in the Self-Assembly of Pd(II)-Linked Catenanes; 4.2.5 Made-to-Order Assembling of Pd(II)-Linked Catenanes 327 $a4.2.5.1 Quantitative Formation of Catenanes from Rectangular Molecular Boxes4.2.5.2 Selective Formation of Catenanes from Three Species-Eight Components; 4.2.5.3 Scope and Limitations; 4.3 Conclusion; References; 5 Catenane and Rotaxane Motifs in Interpenetrating and Self-Penetrating Coordination Polymers; 5.1 Introduction; 5.1.1 Nets; 5.1.2 Interpenetration of Nets; 5.2 Interpenetrating 1D Polymers; 5.3 Interpenetrating 2D Networks; 5.3.1 Parallel Interpenetration of 2D Frameworks; 5.3.1.1 Interpenetratjng Pairs of Sheets; 5.3.1.2 Parallel Interpenetration of more than Two Sheets 327 $a5.3.1.3 Parallel Interpenetration of Sheets Other than (6, 3) and (4, 4)5.3.1.4 Parallel Interpenetration of 2D Nets to Give a 3D Interlocked Composite; 5.3.2 Inclined Interpenetration of 2D Frameworks; 5.3.2.1 More Than One Sheet Passing Through Any Ring; 5.4 Interpenetrating 3D Networks; 5.4.1 Interpenetrating 3-Connected 3D Nets; 5.4.1.1 Interpenetrating (10,3 )-a Nets; 5.4.1.2 Interpenetrating (10,3 )-b Nets; 5.4.1.3 Interpenetrating (8,3 )-c Nets; 5.4.2 Interpenetrating 4-Connected 3D Nets; 5.4.2.1 Interpenetrating Diamond-Like Nets; 5.4.2.2 Interpenetrating Quartz-Like Nets 327 $a5.4.2.3 Interpenetrating PtS-Like Nets 330 $aThis journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules. Nearly one hundred years of progress have passed since Willst?tter's speculative vision of a molecule consisting of two interlinked rings. But even today the synthesis of such structures are a challenge to the creativity of synthetic chemists. These molecules are not only of academic interest, since they occur naturally. 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