LEADER 05349nam 2200673 450 001 9910144281703321 005 20170810191455.0 010 $a1-281-84251-6 010 $a9786611842512 010 $a3-527-61400-1 010 $a3-527-61401-X 035 $a(CKB)1000000000376617 035 $a(EBL)481693 035 $a(OCoLC)291093149 035 $a(SSID)ssj0000121590 035 $a(PQKBManifestationID)11147909 035 $a(PQKBTitleCode)TC0000121590 035 $a(PQKBWorkID)10110942 035 $a(PQKB)10892339 035 $a(MiAaPQ)EBC481693 035 $a(EXLCZ)991000000000376617 100 $a20160818h19991999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aChiral auxiliaries in cycloadditions /$fKarola Ruck-Braun, Horst Kunz 210 1$aWeinheim, [Germany] :$cWiley-VCH,$d1999. 210 4$dİ1999 215 $a1 online resource (190 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29386-8 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aChiral Auxiliaries in Cycloadditions; Table of Contents; 1 [2+1] Cycloadditions (Cyclopropanations); 1.1 Simmons-Smith Reactions; 1.2 Cyclopropanations with Carbene Equivalents; 1.3 Cyclopropanations with Ylide Reagents; 1.3.1 Chiral Ylide Reagents; 1.3.2 Chiral Alkenes; 1.4 Transition Metal-Catalyzed Reactions of Diazo Compounds; 1.5 References; 2 [2+2] Cycloadditions; 2.1 Reactions of Imines with Ketenes (Staudinger Reaction); 2.1.1 Chiral Ketenes; 2.1.2 Chiral Imines; 2.2 Reactions of Keteniminium Salts with Alkenes; 2.3 Reactions of Ketenes with Electronrich Alkenes; 2.3.1 Chiral Ketenes 327 $a2.3.2 Chiral Vinylethers2.3.3 Miscellaneous Reactions; 2.4 Reactions of Isocyanates with Alkenes; 2.5 Photochemically Induced [2+2] Cycloadditions; 2.5.1 Paterno-Bu?chi Reactions; 2.5.2 Application of Chromium Carbene Complexes; 2.6 References; 3 [4+2] Cycloadditions (Diels-Alder Reactions); 3.1 Thermal Reactions; 3.1.1 Reactions of Chiral Dienophiles; 3.1.2 Reactions of Achiral Dienophiles with Chiral Dienes; 3.2 Lewis Acid-Catalyzed Reactions; 3.2.1 Reactions of Chiral Dienophiles; 3.2.2 Reactions of Achiral Dienophiles with Chiral Dienes; 3.3 Intramolecular [4+2] Cycloadditions 327 $a3.3.1 Thermal Reactions3.3.2 Lewis Acid-Catalyzed Reactions; 3.4 References; 4 Hetero [4+2] Cycloadditions; 4.1 Reactions of Hetero-Dienophiles with Dienes; 4.1.1 Reactions of Activated Carbonyl Dienophiles/Aldehydes; 4.1.1 . 1 Reactions of Chiral Carbonyl Dienophiles with Achiral Dienes; 4.1.1.2 Reactions of Achiral Carbonyl Dienophiles with Chiral Heteroatom-substituted Dienes; 4.1.2 Reactions of Imines; 4.1.2.1 Reactions of Chiral Imines with Dienes; 4.1.2.2 Reactions of Chiral Imines with Heteroatom-substituted Dienes 327 $a4.1.2.3 Reactions of Achiral Imines with Chiral Heteroatom-substituted Dienes4.1.3 Reactions of Nitroso Compounds; 4.1.3.1 Reactions of Chloronitroso Compounds; 4.1.4 Reactions of N-Acylnitroso Compounds; 4.1.4.1 Reactions of Chiral N-Acylnitroso Compounds with Dienes; 4.1.4.2 Reactions of Achiral N-Acylnitroso Compounds with Achiral Dienes; 4.1.5 Reactions of N-Sulfinyl Dienophiles; 4.1.6 Reactions of N=N Dienophiles; 4.2 Reactions of Hetero-Dienes with Dienophiles; 4.2.1 Reactions of Oxabutadienes; 4.2.1.1 Reactions of Chiral Oxabutadienes with Achiral Vinylethers 327 $a4.2.1.2 Reactions of Achiral Oxabutadienes with Chiral Vinylethers4.2.2 Reactions of Achiral Nitroso Compounds; 4.2.3 Reactions of Nitroalkenes; 4.2.4 Reactions of 1-Aza-1,3-dienes; 4.2.5 Reactions of 2-Aza-1,3-dienes; 4.2.6 Reactions of Chiral N-Acyl-Imines; 4.2.7 Reactions of Thiabutadienes; 4.2.8 Intramolecular Hetero [4+2] Cycloadditions; 4.3 References; 5 [3+2] Cycloadditions; 5.1 Chiral Dipolarophiles; 5.1.1 Reactions of Nitrile Oxides; 5.1.2 Reactions of Nitrile Imines; 5.1.3 Reactions of Nitrones; 5.1.4 Reactions of Nitronates; 5.1.5 Reactions of Azomethine Ylides 327 $a5.1.5.1 Reactions of Azomethine Ylides Derived from AIdimines 330 $aSince the days of Diels, Alder and Woodward, cycloadditions have been among the most versatile reactions for stereoselective synthesis ... All relevant information is collected in this well-structured, practical handbook. Arranged according to the cycloaddition type, the suitable auxiliaries, reactants, stereoselectivities, yields, and references for each key reaction are compiled in compact tables. Scientists interested in the theoretical background of stereoselective cycloadditions will find an excellent selection of in-depth literature references. ... with this comprehensiv 606 $aChirality 606 $aRing formation (Chemistry) 606 $aOrganic compounds$xSynthesis 608 $aElectronic books. 615 0$aChirality. 615 0$aRing formation (Chemistry) 615 0$aOrganic compounds$xSynthesis. 676 $a547.2 676 $a547.504593 700 $aRu?ck-Braun$b Karola$0998446 702 $aKunz$b Horst 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144281703321 996 $aChiral auxiliaries in cycloadditions$92290333 997 $aUNINA