LEADER 05225nam 2200637 450 001 9910144281503321 005 20170816124348.0 010 $a1-281-84252-4 010 $a9786611842529 010 $a3-527-61406-0 010 $a3-527-61407-9 035 $a(CKB)1000000000376618 035 $a(EBL)481969 035 $a(OCoLC)291092539 035 $a(SSID)ssj0000201627 035 $a(PQKBManifestationID)11196343 035 $a(PQKBTitleCode)TC0000201627 035 $a(PQKBWorkID)10245717 035 $a(PQKB)11131036 035 $a(MiAaPQ)EBC481969 035 $a(EXLCZ)991000000000376618 100 $a20160820h19991999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMetal carbenes in organic synthesis /$fFlorencio Zaragoza Do?rwald 210 1$aWeinheim, [Germany] :$cWiley-VCH,$d1999. 210 4$dİ1999 215 $a1 online resource (311 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29625-5 320 $aIncludes bibliographical references and index. 327 $aMetal Carbenes in Organic Synthesis; Table of Contents; Abbreviations; Experimental Procedures; 1 The Carbon-Metal Double Bond; 1 1 Reactivity of Carbene Complexes; 1.2 Fischer-Type and Schrock-Type Carbene Complexes: Theoretical Treatment; 1.3 Olefin Metathesis and Olefin Cyclopropanation; 1.4 Characteristic NMR Data; 2 Heteroatom-Substituted Carbene Complexes; 2.1 Generation of Heteroatom-Substituted Carbene Complexes; 2.1.1 From Acyl Complexes; 2.1.1.1 From Acyl Complexes Generated from Carbonyl Complexes; 2.1.1.2 From Acyl Complexes Generated from Metallates 327 $a2.1.1.3 From Acyl Complexes Generated by Other Methods2.1.2 From Isonitrile Complexes; 2.1.3 From a-Haloiminium Salts and Metallates; 2.1.4 From Carboxamides and Metallates; 2.1.5 From Vinylidene Complexes; 2.1.5.1 From Vinylidene Complexes Generated from Alkynes; 2.1.5.2 From Vinylidene Complexes Generated from Alkynyl Complexes; 2.1.6 From Carbenes and Carbenoids; 2.1.7 From Alkyl Complexes by a-Abstraction; 2.1.8 From Carbyne Complexes; 2.1.9 Other Methods; 2.2 Synthetic Applications of Heteroatom-Substituted Carbene Complexes; 2.2.1 General Considerations 327 $a2.2.2 Demetallation and Formation of Acyclic Products2.2.3 Photochemical Transformations; 2.2.4 Cyclopropanation; 2.2.5 Thermal Benzannulations; 2.2.5.1 The Do?tz Benzannulation Reaction; 2.2.5.2 Other Thermal Benzannulations; 2.2.6 Formation of Five-Membered Rings; 2.2.6.1 Cyclization of (1,3-Butadien-1-yl)carbene Complexes; 2.2.6.2 Cyclization of Functionalized Carbene Complexes; 2.2.6.3 Rearrangement of Ammonium Ylides; 2.2.6.4 Other Methods; 2.2.7 Formation of Six-Membered. Non-Aromatic Carbocycles and Six-Membered Heterocycles; 2.2.8 Formation of Seven-Membered Rings 327 $a3 Non-Heteroatom-Substituted Carbene Complexes3.1 Generation of Non-Heteroatom-Substituted Carbene Complexes; 3.1.1 a-Abstraction of Electrophiles (Nucleophilic Abstraction); 3.1.2 a-Abstraction of Nucleophiles (Electrophilic Abstraction); 3.1.2.1 a-Abstraction of Hydride; 3.1.2.2 a-Abstraction of Oxygen-Bound Leaving Groups; 3.1.2.3 a-Abstraction of Thioethers; 3.1.2.4 a-Abstraction of Halides; 3.1.3 From Ylides; 3.1.3.1 From Diazoalkanes; 3.1.3.2 From Other Ylides; 3.1.4 From Carbyne Complexes; 3.1.4.1 Nucleophilic Additions to Carbyne Complexes 327 $a3.1.4.2 Electrophilic Additions to Carbyne Complexes3.1.5 From Alkynyl and Alkenyl Complexes; 3.1.6 From Alkyne and Cyclopropene Complexes; 3.1.7 By [2 + 2] Cycloreversion; 3.1.8 Other Methods; 3.2 Synthetic Applications of Non-Heteroatom-Substituted Carbene Complexes; 3.2.1 General Considerations; 3.2.2 Cyclopropanation; 3.2.2.1 Stoichiometric Cyclopropanations; 3.2.2.2 Catalytic Cyclopropanations with Diazoalkanes; 3.2.2.3 Catalytic Cyclopropanations with Other Carbene Precursors; 3.2.3 C-H Insertions; 3.2.3.1 C-H Insertions of Nucleophilic Carbene Complexes 327 $a3.2.3.2 C-H Insertions of Electrophilic Carbene Complexes 330 $aThere are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production.This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes 606 $aCarbenes (Methylene compounds) 606 $aOrganic compounds$xSynthesis 608 $aElectronic books. 615 0$aCarbenes (Methylene compounds) 615 0$aOrganic compounds$xSynthesis. 676 $a547.050459 676 $a547.2 700 $aDo?rwald$b Florencio Zaragoza$0875082 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144281503321 996 $aMetal carbenes in organic synthesis$92004808 997 $aUNINA